KR980002074A - 화학적 화합물 - Google Patents

화학적 화합물 Download PDF

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KR980002074A
KR980002074A KR1019970022784A KR19970022784A KR980002074A KR 980002074 A KR980002074 A KR 980002074A KR 1019970022784 A KR1019970022784 A KR 1019970022784A KR 19970022784 A KR19970022784 A KR 19970022784A KR 980002074 A KR980002074 A KR 980002074A
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코르넬리아 프리체
프랑크 퀴버
한스 보넨
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아울미히, 쿤켈
훽스트 아크티엔게젤샤프트
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Abstract

본 발명은 다음 화학식(1)의 화학적 화합물에 관한 것이다.
상기식에서, R은 서로 독립적으로 동일하거나 상이한 할로겐 원자 또는 C1-C40그룹이고, X은 서로 독립적이로 동일하거나 상이하며 각가가 C1-C40그룹이고, M은 서로 독립적으로 동일하거나 상이하며 각각 원소 주기율표의 Ⅱa족, Ⅲa족, Ⅳa족 또는 Ⅴa족 원소이고, a, b 및 c는 각각 정수 0 내지 10이며, a=b·c이고, d, e 및 f는 각각 0 또는 1이며, g, h 및 k는 각각 정수 0 내지 10이고, i는 정수 0 내지 1000이며, j는 정수 1 내지 6이고, A는 원소 주기율표의 Ⅰa족, Ⅱa족 및 Ⅲa족의 양이온, 카베늄, 옥소늄 또는 설포늄 양이온 또는 4급 암모늄 화합물이다. 당해 화합물은 올레핀 중합 반응용 촉매 성분으로 적합하다.

Description

화학적 화합물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 본 발명은 다음 화학식(1)의 화합물.
    상기식에서, R은 서로 독립적으로 동일하거나 상이한 할로겐 원자 또는 C1-C40그룹이고, X은 서로 독립적이로 동일하거나 상이하며 각가가 C1-C40그룹이고, M은 서로 독립적으로 동일하거나 상이하며 각각 원소 주기율표의 Ⅱa족, Ⅲa족, Ⅳa족 또는 Ⅴa족 원소이고, a, b 및 c는 각각 정수 0 내지 10이며, a=b·c이고, d, e 및 f는 각각 0 또는 1이며, g, h 및 k는 각각 정수 0 내지 10이고, i는 정수 0 내지 1000이며, j는 정수 1 내지 6이고, A는 원소 주기율표의 Ⅰa족, Ⅱa족 및 Ⅲa족의 양이온, 카베늄, 옥소늄 또는 설포늄 양이온 또는 4급 암모늄 화합물이다.
  2. 제1항에 있어서, R이 서로 독립적으로 동일하거나 상이하며 각각 C1-C40-알킬, C1-C40-할로알킬, C6-C40- 아릴, C6-C40- 할로아릴, C7-C40- 아릴아킬 또는 C7-C40-할로아릴알킬 그룹이고,X가 독립적으로 동일하거나 상이하며 각각 C1-C40- 알킬렌, C1-C40-할로알킬렌, C6-C40- 아릴렌, C6-C40- 할로아릴렌, C7-C40-아릴아킬렌, C7-C40-할로아릴아킬렌, C2-C40- 알키닐렌, C2-C40-할로알키닐렌,C2-C40-알케닐렌 또는 C2-C40-할로알케닐렌 그룹인 화학식(1)의 화합물.
  3. 제1항 또는 제2항에 있어서, R이 각각 할로겐화 C1-C30-알킬 그룹 또는 그C6-C30-아릴 그룹, 할로겐화되지 않거나 할로겐화된 C6-C30-아릴렌 그룹, C|2-C30-알켈닐렌 그룹 또는 C2-C30-알키닐렌 그룹이고, M이 원소 주기율표의 Ⅲa족 원소이며 a, b 및 c가 각각 0,1 또는 2이고, g, h 및 k 가 각각 정수 0 또는 1이며, j가 3 또는 4이고, i는 0 또는 1이며 A가 카베늄 이온 또는 4급 암모늄 이온인 화학식(1)의 화합물.
  4. 화학식 YXY의 화합물을 염기의 존재하에서 화학식 MRjY 및 RY의 화합물과 반응시키는 단계 및 이러한 반응생성물을 화학식 AY의 화합물과 반응시키는 단계를 포함하는(여기서, Y는 이탈 그룹이고, X, M, R, j및 A는 제1항에서 정의한 바와 같다). 제1항 내지 제3항 중의 어느 한 항에 따른 화학식(1)의 화합물의 제조 방법.
  5. a)하나 이상의, 제1항 내지 제3항 중의 어느 한 항에 따른 화학식(1)의 화합물 및 b) 하나 이상의 메탈로센을 포함하는 촉매 시스템.
  6. 제5항에 있어서, 지지체를 추가로 포함하는 촉매 시스템.
  7. 제5항 또는 제6항에 따르는 촉매 시스템을 제조하기 위한, 제1항 내지 제3항 중의 어느 한 항에 따른 화학식(1)의 화합물의 용도.
  8. 제5항 또는 제6항에 따르는 촉매의 시스템을 제조하기 위한, 제1항 내지 제3항 중의 어느 한 항에 따른 화학식(1)의 화합물의 용도.
  9. 올레핀 중합체를 제조하기 위한, 제1항 내지 제3항 중의 어느 한 항에 따른 화학식(1)의 화합물의 용도.
  10. 제8항에 따른 방법에 의해 제조될 수 있는 폴리올레핀.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970022784A 1996-06-03 1997-06-03 올레핀 중합용촉매성분으로서적합한중성또는이온성화합물및이의제조방법 KR100479253B1 (ko)

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DE19622207A DE19622207A1 (de) 1996-06-03 1996-06-03 Chemische Verbindung
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DE19622207A1 (de) * 1996-06-03 1997-12-04 Hoechst Ag Chemische Verbindung
ATE202365T1 (de) † 1996-08-13 2001-07-15 Basell Polyolefine Gmbh Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen
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ZA974827B (en) 1997-12-03
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ATE368043T1 (de) 2007-08-15
DE59712862D1 (de) 2007-09-06
EP0811627A2 (de) 1997-12-10
AU731668B2 (en) 2001-04-05
US6410665B1 (en) 2002-06-25
JP2008303219A (ja) 2008-12-18
EP0811627B1 (de) 2007-07-25
RU2147585C1 (ru) 2000-04-20
NO972507D0 (no) 1997-06-02
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US6255531B1 (en) 2001-07-03
DE19622207A1 (de) 1997-12-04

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