KR930016444A - 올레핀 중합용 촉매, 이의 제조방법 및 이의 용도 - Google Patents

올레핀 중합용 촉매, 이의 제조방법 및 이의 용도 Download PDF

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Publication number
KR930016444A
KR930016444A KR1019930000792A KR930000792A KR930016444A KR 930016444 A KR930016444 A KR 930016444A KR 1019930000792 A KR1019930000792 A KR 1019930000792A KR 930000792 A KR930000792 A KR 930000792A KR 930016444 A KR930016444 A KR 930016444A
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South Korea
Prior art keywords
aluminoxane
catalyst
catalyst according
metallocene
insoluble
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KR1019930000792A
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English (en)
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KR100269055B1 (ko
Inventor
프리드리히 헤르만 한스
바흐만 베른트
돌레 볼커
스파렉크 발터
Original Assignee
테르가우, 발렌틴
훽스트 아크티엔게젤샤프트
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Publication of KR930016444A publication Critical patent/KR930016444A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/22—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of chromium, molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Abstract

본 발명은 지방족 및 방향족 탄화수소 속에서 불용성인 알루미녹산과 하나 이상의 메탈로센의 반응 생성물을 포함하는 올레핀 중합용 불균일 촉매에 관한 것이다.

Description

올레핀 중합용 촉매, 이의 제조방법 및 이의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 지방족 및 방향족 탄화수소 속에서 불용성인 알루미녹산과 하나 이상의 메탈로센과의 반응 생성물을 포함하는 올레핀 중합용 촉매.
  2. 제1항에 있어서, 알루미녹산의 실험식이 AlOaRb(여기서, a는 0.5≤a≤1.3이고, b는 0.5≤b≤2이며, R은 동일하거나 상이하고 C1-C6-알킬, C6-C10-아릴 또는 벤질이다)인 촉매.
  3. 제1항 또는 제2항에 있어서, 알루미녹산이 C1-C4-알킬 알루미녹산인 촉매.
  4. 제1항 내지 제3항 중의 어느 한 항에 있어서, 알루미녹산이 메틸알루미녹산인 촉매.
  5. 제1항 내지 제4항 중의 어느 한 항에 있어서, 알루미녹산이 벤젠 또는 톨루엔 속에서 불용성인 촉매.
  6. 제1항 내지 제5항 중의 어느 한 항에 있어서, 메탈로센을 사용하여 제조된 촉매.
  7. 제1항 내지 제6항 중의 어느 한 항에 있어서, 메탈로센이 지르코노센인 촉매.
  8. 지방족 및 방향족 탄화수소 중에서 불용성인 알루미녹산을 하나 이상의 메탈로센과 반응시킴을 포함하여, 제1항 내지 제7항 중의 어느 한 항에서 청구한 촉매를 제조하는 방법.
  9. 제1항 내지 제7항 중의 어느 한 항에서 청구한 촉매를 사용함을 포함하여, 일반식 Ra-CH=CH-Rb의 올레핀(여기서, 는 동일하거나 상이하고 수소원자 또는 탄소수 1 내지 14의 탄화수소 라디칼이거나, 또는 Ra및 Rb는 이들이 결합하고 있는 원자와 함께 환을 형성한다.)을 촉매의 존재하에 용액, 현탁액 또는 기상으로 -60 내지 200℃의 온도 및 0.5 내지 100bar의 입력하에 중합시키거나 공중합시킴으로써 올레핀 중합체를 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930000792A 1992-01-24 1993-01-21 올레핀중합용촉매및이의제조방법 KR100269055B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEP4201850.1 1992-01-24
DE4201850 1992-01-24
DEP4201850.10 1992-01-24

Publications (2)

Publication Number Publication Date
KR930016444A true KR930016444A (ko) 1993-08-26
KR100269055B1 KR100269055B1 (ko) 2000-10-16

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KR1019930000792A KR100269055B1 (ko) 1992-01-24 1993-01-21 올레핀중합용촉매및이의제조방법

Country Status (10)

Country Link
EP (1) EP0557718B1 (ko)
JP (1) JPH05339311A (ko)
KR (1) KR100269055B1 (ko)
AT (1) ATE129256T1 (ko)
AU (1) AU656834B2 (ko)
CA (1) CA2087918A1 (ko)
DE (1) DE59300761D1 (ko)
ES (1) ES2079213T3 (ko)
TW (1) TW337527B (ko)
ZA (1) ZA93480B (ko)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW298593B (ko) * 1993-02-12 1997-02-21 Hoechst Ag
WO1994019381A1 (en) * 1993-02-22 1994-09-01 Idemitsu Kosan Co., Ltd. Ethylene copolymer, thermoplastic resin composition containing the same, and process for producing ethylene copolymer
FI97141C (fi) * 1994-03-14 1996-10-25 Neste Oy Menetelmä tyydyttämättömien polymeerien selektiiviseksi hydrogenoimiseksi
JP3404906B2 (ja) * 1994-08-12 2003-05-12 東ソー株式会社 オレフィン系共重合体の製造方法
DE59600039D1 (de) * 1996-03-19 1997-12-11 Witco Gmbh Verfahren zur Herstellung von hochaktiven, stabilen Metallocen-Katalysatorsystemen und gemäss diesem Verfahren hergestellte Formulierungen
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
AU2003302033A1 (en) 2002-10-15 2004-06-15 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR920006464B1 (ko) * 1988-09-14 1992-08-07 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 올레핀중합용 촉매성분, 올레핀중합용 촉매 및 이 올레핀중합용 촉매를 사용한 올레핀의 중합방법

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Publication number Publication date
KR100269055B1 (ko) 2000-10-16
EP0557718B1 (de) 1995-10-18
JPH05339311A (ja) 1993-12-21
ES2079213T3 (es) 1996-01-01
AU656834B2 (en) 1995-02-16
CA2087918A1 (en) 1993-07-25
ATE129256T1 (de) 1995-11-15
ZA93480B (en) 1993-08-23
DE59300761D1 (de) 1995-11-23
TW337527B (en) 1998-08-01
EP0557718A1 (de) 1993-09-01
AU3194393A (en) 1993-07-29

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