KR930016444A - Catalyst for olefin polymerization, preparation method thereof and use thereof - Google Patents

Catalyst for olefin polymerization, preparation method thereof and use thereof Download PDF

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Publication number
KR930016444A
KR930016444A KR1019930000792A KR930000792A KR930016444A KR 930016444 A KR930016444 A KR 930016444A KR 1019930000792 A KR1019930000792 A KR 1019930000792A KR 930000792 A KR930000792 A KR 930000792A KR 930016444 A KR930016444 A KR 930016444A
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KR
South Korea
Prior art keywords
aluminoxane
catalyst
catalyst according
metallocene
insoluble
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KR1019930000792A
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Korean (ko)
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KR100269055B1 (en
Inventor
프리드리히 헤르만 한스
바흐만 베른트
돌레 볼커
스파렉크 발터
Original Assignee
테르가우, 발렌틴
훽스트 아크티엔게젤샤프트
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Publication of KR930016444A publication Critical patent/KR930016444A/en
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Publication of KR100269055B1 publication Critical patent/KR100269055B1/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/22—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of chromium, molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Abstract

The present invention relates to a heterogeneous catalyst for the polymerisation of olefins which comprises the product of the reaction of an aluminoxane which is insoluble in aliphatic and aromatic hydrocarbons with at least one metallocene.

Description

올레핀 중합용 촉매, 이의 제조방법 및 이의 용도Catalyst for olefin polymerization, preparation method thereof and use thereof

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (9)

지방족 및 방향족 탄화수소 속에서 불용성인 알루미녹산과 하나 이상의 메탈로센과의 반응 생성물을 포함하는 올레핀 중합용 촉매.A catalyst for olefin polymerization comprising a reaction product of an aluminoxane and at least one metallocene insoluble in aliphatic and aromatic hydrocarbons. 제1항에 있어서, 알루미녹산의 실험식이 AlOaRb(여기서, a는 0.5≤a≤1.3이고, b는 0.5≤b≤2이며, R은 동일하거나 상이하고 C1-C6-알킬, C6-C10-아릴 또는 벤질이다)인 촉매.The empirical formula of aluminoxane according to claim 1, wherein the empirical formula of Aluminoxane is AlOaRb, wherein a is 0.5 ≦ a ≦ 1.3, b is 0.5 ≦ b ≦ 2, and R is the same or different and C 1 -C 6 -alkyl, C 6- C 10 -aryl or benzyl). 제1항 또는 제2항에 있어서, 알루미녹산이 C1-C4-알킬 알루미녹산인 촉매.The catalyst according to claim 1 or 2, wherein the aluminoxane is C 1 -C 4 -alkyl aluminoxane. 제1항 내지 제3항 중의 어느 한 항에 있어서, 알루미녹산이 메틸알루미녹산인 촉매.The catalyst according to any one of claims 1 to 3, wherein the aluminoxane is methylaluminoxane. 제1항 내지 제4항 중의 어느 한 항에 있어서, 알루미녹산이 벤젠 또는 톨루엔 속에서 불용성인 촉매.The catalyst according to any one of claims 1 to 4, wherein the aluminoxane is insoluble in benzene or toluene. 제1항 내지 제5항 중의 어느 한 항에 있어서, 메탈로센을 사용하여 제조된 촉매.The catalyst according to any one of claims 1 to 5, prepared using metallocene. 제1항 내지 제6항 중의 어느 한 항에 있어서, 메탈로센이 지르코노센인 촉매.The catalyst according to any one of claims 1 to 6, wherein the metallocene is zirconocene. 지방족 및 방향족 탄화수소 중에서 불용성인 알루미녹산을 하나 이상의 메탈로센과 반응시킴을 포함하여, 제1항 내지 제7항 중의 어느 한 항에서 청구한 촉매를 제조하는 방법.A process for preparing a catalyst as claimed in claim 1 comprising reacting an insoluble aluminoxane with aliphatic and aromatic hydrocarbons with one or more metallocenes. 제1항 내지 제7항 중의 어느 한 항에서 청구한 촉매를 사용함을 포함하여, 일반식 Ra-CH=CH-Rb의 올레핀(여기서, 는 동일하거나 상이하고 수소원자 또는 탄소수 1 내지 14의 탄화수소 라디칼이거나, 또는 Ra및 Rb는 이들이 결합하고 있는 원자와 함께 환을 형성한다.)을 촉매의 존재하에 용액, 현탁액 또는 기상으로 -60 내지 200℃의 온도 및 0.5 내지 100bar의 입력하에 중합시키거나 공중합시킴으로써 올레핀 중합체를 제조하는 방법.An olefin of the general formula R a -CH = CH-R b , wherein is the same or different and has a hydrogen atom or of 1 to 14 carbon atoms, including the use of a catalyst as claimed in claim 1. Hydrocarbon radicals, or R a and R b together with the atoms to which they are attached form a ring.) In a solution, suspension or gas phase in the presence of a catalyst at a temperature of −60 to 200 ° C. and an input of 0.5 to 100 bar. To produce an olefin polymer by preforming or copolymerizing. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019930000792A 1992-01-24 1993-01-21 Olefin polymerization catalyst and process for preparing the same KR100269055B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEP4201850.10 1992-01-24
DEP4201850.1 1992-01-24
DE4201850 1992-01-24

Publications (2)

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KR930016444A true KR930016444A (en) 1993-08-26
KR100269055B1 KR100269055B1 (en) 2000-10-16

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EP (1) EP0557718B1 (en)
JP (1) JPH05339311A (en)
KR (1) KR100269055B1 (en)
AT (1) ATE129256T1 (en)
AU (1) AU656834B2 (en)
CA (1) CA2087918A1 (en)
DE (1) DE59300761D1 (en)
ES (1) ES2079213T3 (en)
TW (1) TW337527B (en)
ZA (1) ZA93480B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW298593B (en) * 1993-02-12 1997-02-21 Hoechst Ag
EP0690079B1 (en) * 1993-02-22 2002-07-03 Idemitsu Kosan Company Limited Ethylene copolymer, thermoplastic resin composition containing the same, and process for producing ethylene copolymer
FI97141C (en) * 1994-03-14 1996-10-25 Neste Oy Method for the selective hydrogenation of unsaturated polymers
JP3404906B2 (en) * 1994-08-12 2003-05-12 東ソー株式会社 Method for producing olefin copolymer
ATE159734T1 (en) * 1996-03-19 1997-11-15 Witco Gmbh METHOD FOR PRODUCING HIGHLY ACTIVE, STABLE METALLOCENE CATALYST SYSTEMS AND FORMULATIONS PRODUCED ACCORDING TO THIS METHOD
JP4972284B2 (en) 2002-10-15 2012-07-11 エクソンモービル・ケミカル・パテンツ・インク Multiple catalyst systems for olefin polymerization and polymers produced therefrom
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom

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KR920006464B1 (en) * 1988-09-14 1992-08-07 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 Olefin polymerization catalyst component olefin polymerization catalyst and process for the polymerization of olefins

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TW337527B (en) 1998-08-01
ZA93480B (en) 1993-08-23
DE59300761D1 (en) 1995-11-23
AU3194393A (en) 1993-07-29
AU656834B2 (en) 1995-02-16
EP0557718B1 (en) 1995-10-18
ES2079213T3 (en) 1996-01-01
EP0557718A1 (en) 1993-09-01
CA2087918A1 (en) 1993-07-25
ATE129256T1 (en) 1995-11-15
KR100269055B1 (en) 2000-10-16
JPH05339311A (en) 1993-12-21

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