KR890002243A - 올레핀계 또는 스티렌계 중합체의 제조방법 - Google Patents

올레핀계 또는 스티렌계 중합체의 제조방법 Download PDF

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KR890002243A
KR890002243A KR1019880008788A KR880008788A KR890002243A KR 890002243 A KR890002243 A KR 890002243A KR 1019880008788 A KR1019880008788 A KR 1019880008788A KR 880008788 A KR880008788 A KR 880008788A KR 890002243 A KR890002243 A KR 890002243A
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South Korea
Prior art keywords
aluminoxane
styrene
producing
polymer
olefin
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KR1019880008788A
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KR910005679B1 (ko
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히로시 마에자와
마사히꼬 쿠라모또
미찌타께 우오이
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이데미쓰 쇼스께
이데미쓰 고산 가부시끼가이샤
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

내용 없음

Description

올레핀계 또는 스티렌계 중합체의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (4)

  1. (A) 천이 금속 화합물 및 (B) 알루미녹산으로 이루어지는 촉매의 존재하에, 올레핀류 또는 스티렌 혹은 스티렌 유도체를 중합시켜 올레핀계 또는 스티렌계 중합체를 제조함에 있어서, 알루미녹산(B)으로서, 부분적으로 가교된 구조를 갖는 알루미녹산을 사용하는 것을 특징으로하는 올레핀계 또는 스티렌계 중합체의 제조방법.
  2. 제1항에 있어서, 알루미녹산이, 일반식
    로 표시되는 반복 단위 및 일반식
    (식중에서, R1은 탄소수 1-8의 알킬기이고, m과 n은 각각 1이상의 정수이며, m+n은 4-60의 정수이다.)로 표시되는 반복 단위의 2개의 반복 단위를 갖고 있으며, 부분적으로 가교점을 갖고 있는 알루미녹산인 올레핀계 또는 스티렌계 중합체의 제조방법.
  3. 제1항에 있어서, 알루미녹산이, 일반식
    (식중에서, R2은 탄소수 1-8의 알킬기이다.)로 표시되는 트리알킬 알루미늄과 물을 반응시키는 것에 의해 얻어지는 알루미녹산인 올레핀계 또는 스티렌계 중합체의 제조방법.
  4. 제3항에 있어서, 알루미녹산이, 생성된 알칸의 양이 트리알킬 알루미늄 1몰에 대하여 2.05-2.50몰로된 시점에서 반응을 정지시키는 것에 의하여 얻어지는 알루미녹산인 올레핀계 또는 스티렌계 중합체의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880008788A 1987-07-13 1988-07-13 올레핀계 또는 스티렌계 중합체의 제조방법 KR910005679B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP?62-173007 1987-07-13
JP62173007A JP2566889B2 (ja) 1987-07-13 1987-07-13 オレフィン系重合体またはスチレン系重合体の製造方法
JP173007 1988-07-12

Publications (2)

Publication Number Publication Date
KR890002243A true KR890002243A (ko) 1989-04-10
KR910005679B1 KR910005679B1 (ko) 1991-08-01

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Family Applications (1)

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KR1019880008788A KR910005679B1 (ko) 1987-07-13 1988-07-13 올레핀계 또는 스티렌계 중합체의 제조방법

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Country Link
EP (1) EP0299391B1 (ko)
JP (1) JP2566889B2 (ko)
KR (1) KR910005679B1 (ko)
CA (1) CA1308853C (ko)
DE (1) DE3880568T2 (ko)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2840605B2 (ja) * 1989-03-20 1998-12-24 出光興産株式会社 スチレン系共重合体及びその製造方法
JP2810098B2 (ja) * 1989-03-31 1998-10-15 出光興産株式会社 スチレン系共重合体とその製造法
JP2744282B2 (ja) * 1989-03-31 1998-04-28 出光興産株式会社 スチレン系共重合体及びその製造方法
JP2746410B2 (ja) * 1989-03-31 1998-05-06 出光興産株式会社 スチレン系共重合体及びその製造方法
JP2746409B2 (ja) * 1989-03-31 1998-05-06 出光興産株式会社 スチレン系共重合体及びその製造方法
CA2029878C (en) * 1989-04-11 1998-06-09 Tadashi Asanuma Preparation process of syndiotactic polypropylene
JP3048591B2 (ja) * 1989-04-11 2000-06-05 三井化学株式会社 シンジオタクチックポリオレフィンの製造方法
US5043408A (en) * 1989-06-26 1991-08-27 Sumitomo Chemical Company, Limited Ethylene-aromatic vinyl compound alternating copolymer and process for the production thereof
DE69427095T2 (de) 1993-09-17 2001-11-15 Exxonmobil Chem Patents Inc Polymerisations katalysator systeme, ihre herstellung und verwendung
DE59503827D1 (de) * 1994-06-03 1998-11-12 Pcd Polymere Ag Katalysatorträger, geträgerte Metallocenkatalysatoren und deren Verwendung für die Herstellung von Polyolefinen
EP0757995A1 (en) * 1995-07-08 1997-02-12 PCD-Polymere Gesellschaft m.b.H. Supported polymerization-catalyst and its use for olefine polymerization
EP0754706B1 (en) * 1995-07-08 1998-08-05 PCD-Polymere Gesellschaft m.b.H. Supported polymerization-catalyst and its use for olefin polymerization
JP4090100B2 (ja) * 1998-02-27 2008-05-28 出光興産株式会社 アルミニウム化合物およびその製造方法、オレフィン重合体製造用触媒並びにオレフィン重合体の製造方法
JP5652688B2 (ja) * 2007-06-13 2015-01-14 出光興産株式会社 オレフィンと芳香族ビニル化合物からなる共重合体の製造方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1352996A (fr) * 1960-11-30 1964-02-21 Union Carbide Corp Nouveau procédé de polymérisation d'alpha-oléfines
DE3240383A1 (de) * 1982-11-02 1984-05-03 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von oligomeren aluminoxanen
US4665208A (en) * 1985-07-11 1987-05-12 Exxon Chemical Patents Inc. Process for the preparation of alumoxanes
CA1276748C (en) * 1985-07-29 1990-11-20 Michitake Uoi Styrene polymers
JPS62187708A (ja) * 1985-11-11 1987-08-17 Idemitsu Kosan Co Ltd スチレン系重合体の製造法
JPH0662641B2 (ja) * 1985-12-24 1994-08-17 三井石油化学工業株式会社 アルミノオキサン類の製造方法
JPH082925B2 (ja) * 1986-11-10 1996-01-17 出光興産株式会社 スチレン系重合体の製造方法

Also Published As

Publication number Publication date
EP0299391B1 (en) 1993-04-28
EP0299391A1 (en) 1989-01-18
JPS6416803A (en) 1989-01-20
CA1308853C (en) 1992-10-13
KR910005679B1 (ko) 1991-08-01
JP2566889B2 (ja) 1996-12-25
DE3880568D1 (de) 1993-06-03
DE3880568T2 (de) 1993-10-07

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