KR970070158A - 오가노실록산 조성물 - Google Patents

오가노실록산 조성물 Download PDF

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KR970070158A
KR970070158A KR1019970013897A KR19970013897A KR970070158A KR 970070158 A KR970070158 A KR 970070158A KR 1019970013897 A KR1019970013897 A KR 1019970013897A KR 19970013897 A KR19970013897 A KR 19970013897A KR 970070158 A KR970070158 A KR 970070158A
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파트릭 림포엘
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불로우스 엠.
다우 코닝 에스. 아.
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
    • C09J183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/14—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
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    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
    • C09J183/14—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
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    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
    • C08G77/50—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms by carbon linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/28—Non-macromolecular organic substances
    • C08L2666/44—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/54—Inorganic substances
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S528/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S528/901—Room temperature curable silicon-containing polymer

Abstract

본 발명은 수분 경화성 조성물은 하이드록실 그룹 또는 가수분해되기 쉬운 그룹인, 규소에 결합된 두개 이상의 그룹을 갖는 중심체성 재료, 알콕시실란 경화제, 접착 촉진제, 및 중합체성 재료와 알콕시실란 경화제 사이의 축합 반응을 촉매하는 촉매 재료의 혼합물 및/또는 반응 생성물을 포함한다. 접착 촉진제는 화학식 RaSiO4-a/2에 따르는 단위(i) 및 화학식 RbR'SiO3-b/2〔여기서, R은 1가의 탄화수소 그룹을 나타내고, R'은 옥시알킬렌쇄 R''(C2H6O)X(C3H6O)yZ(여기서, R''은 규소 원자에 대한 탄화수소 결합을 나타내고, Z는 H 또는 카복실산 잔기를 나타낸다)를 나타낸다〕에 따르는 단위(ii)로 구성된 실리콘 유기 공중합체를 포함한다. 또한, 본 발명은 표면들 사이에 수분 경화성 조성물을 도입시키는 것을 포함하며, 두개 이상의 이러한 표면에 접착되는 엘라스토머 소재를 표면들 사이에 형성시키는 방법에 관한 것이다.

Description

오가노실록산 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. 하이드록시 그룹 및 기타 가수분해되기 쉬운 그룹으로부터 독립적으로 선택되는, 규모에 결합되는 두개 이상의 그룹을 갖는 중합체성 재료, 알콕시실란 경화제, 미분된 충전제, 및 중합체성 재료와 알콕시실란 경화제 사이의 축합반응을 촉매하는 촉매 재료의 혼합물 및/또는 반응 생성물을 포함하고, 추가로 화학식 RaSiO4-a/2에 따른 단위(i) 및 화학식 RbR'SiO3-b/2에 따르는 단위(ii)[여기서, R은 각각 동일하거나 상이하고 탄소수 20 이하인 1가 탄화수소 그룹을 나타내고, a는 각각 동일하거나 상이하고 0 내지 3의 값을 가지며, b는 각각 동일하거나 상이하고 0 내지 2의 값을 가지며, R'은 동일하거나 상이하고 옥시알킬렌 쇄 R''(C2H6O)X(C3H5O)yZ(여기서, R''은 규소 원자에 대한 탄화수소 결합을 나타내고, Z는 각각 동일하거나 상이하고 H 또는 카복실산 잔기를 나타내며,x는 각각 동일하거나 상이하고 0 내지 20의 값을 갖고, y는 각각 동일하거나 상이하고 0 내지 20의 값을 가지며, x+y는 3 내지 40의 값이다)를 나타낸다]로 구성된 실리콘 유기 공중합체를 포함하는 접착촉진제를 포함함을 특징으로 하는 수분 경화성 조성물 소재를 표면들 사이에 도입함을 포함하여, 두개 이상의 표면에 접착되는 엘라스토머 소재를 표면들 사이에 형성시키는 방법.
  2. 제1항에 있어서, 단위(ii)의 그룹 R'이 실리콘 유기 공중합체의 40중량% 이하로 제공됨을 특징으로 하는 방법.
  3. 제1항에 있어서, 중합체성 재료가 말단 그룹 SiMe2OH 또는 SiMe2R″′Si(OR5)3(여기서 R″′은 규소수 6이하의 하나 이상의 실록산 스테이서(spacer)에 의해 차단될 수 있는 2가 탄화수소 그룹이고, R5는 탄수소 6이하의 알킬 그룹, 또는 알킬 그룹이 6개 이하의 탄소원자를 갖는 옥시알킬 그룹을 나타낸다)을 갖는 적어도 실질적으로 선형인 폴리디오가노실록산임을 특징으로 하는 방법.
  4. 제1항에 있어서, 알콕시실란이 메틸 트리메톡시실란임을 특징으로 하는 방법.
  5. 제1항에 있어서, 미분된 충전제가 실리카임을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970013897A 1996-04-17 1997-04-16 오가노실록산조성물 KR100437518B1 (ko)

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GB9607897.7 1996-04-17
GBGB9607897.7A GB9607897D0 (en) 1996-04-17 1996-04-17 Organosiloxane compositions

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US (1) US5833798A (ko)
EP (1) EP0802233B1 (ko)
JP (1) JPH1036810A (ko)
KR (1) KR100437518B1 (ko)
AU (1) AU1890397A (ko)
CA (1) CA2202340A1 (ko)
DE (1) DE69727611T2 (ko)
ES (1) ES2212046T3 (ko)
GB (1) GB9607897D0 (ko)

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EP0802233A2 (en) 1997-10-22
JPH1036810A (ja) 1998-02-10
DE69727611T2 (de) 2004-12-09
EP0802233A3 (en) 1998-03-25
EP0802233B1 (en) 2004-02-18
DE69727611D1 (de) 2004-03-25
AU1890397A (en) 1997-10-23
US5833798A (en) 1998-11-10
ES2212046T3 (es) 2004-07-16
CA2202340A1 (en) 1997-10-17
GB9607897D0 (en) 1996-06-19
KR100437518B1 (ko) 2005-05-03

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