KR970064718A - 다공성 유출 성형체 및 이의 제조방법 - Google Patents

다공성 유출 성형체 및 이의 제조방법 Download PDF

Info

Publication number
KR970064718A
KR970064718A KR1019970009908A KR19970009908A KR970064718A KR 970064718 A KR970064718 A KR 970064718A KR 1019970009908 A KR1019970009908 A KR 1019970009908A KR 19970009908 A KR19970009908 A KR 19970009908A KR 970064718 A KR970064718 A KR 970064718A
Authority
KR
South Korea
Prior art keywords
powder
molded article
calcination
silicon
binder
Prior art date
Application number
KR1019970009908A
Other languages
English (en)
Other versions
KR100484558B1 (ko
Inventor
호르스트 에르 마이어
우베 슈마허
발터 베스트
볼프강 세퍼
Original Assignee
베스트 베, 슈타인스 아
토마스 요세프 하임바호 게엠베하 앤드 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 베스트 베, 슈타인스 아, 토마스 요세프 하임바호 게엠베하 앤드 캄파니 filed Critical 베스트 베, 슈타인스 아
Publication of KR970064718A publication Critical patent/KR970064718A/ko
Application granted granted Critical
Publication of KR100484558B1 publication Critical patent/KR100484558B1/ko

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
    • B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
    • B01D46/2418—Honeycomb filters
    • B01D46/2451—Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure
    • B01D46/2455—Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure of the whole honeycomb or segments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B01D39/14—Other self-supporting filtering material ; Other filtering material
    • B01D39/20—Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
    • B01D39/2068—Other inorganic materials, e.g. ceramics
    • B01D39/2072—Other inorganic materials, e.g. ceramics the material being particulate or granular
    • B01D39/2075—Other inorganic materials, e.g. ceramics the material being particulate or granular sintered or bonded by inorganic agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
    • B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
    • B01D46/2418—Honeycomb filters
    • B01D46/2425—Honeycomb filters characterized by parameters related to the physical properties of the honeycomb structure material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
    • B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
    • B01D46/2418—Honeycomb filters
    • B01D46/2425—Honeycomb filters characterized by parameters related to the physical properties of the honeycomb structure material
    • B01D46/2429—Honeycomb filters characterized by parameters related to the physical properties of the honeycomb structure material of the honeycomb walls or cells
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
    • B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
    • B01D46/2418—Honeycomb filters
    • B01D46/2425—Honeycomb filters characterized by parameters related to the physical properties of the honeycomb structure material
    • B01D46/24491—Porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
    • B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
    • B01D46/2418—Honeycomb filters
    • B01D46/2425—Honeycomb filters characterized by parameters related to the physical properties of the honeycomb structure material
    • B01D46/24492—Pore diameter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
    • B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
    • B01D46/2418—Honeycomb filters
    • B01D46/2425—Honeycomb filters characterized by parameters related to the physical properties of the honeycomb structure material
    • B01D46/24494—Thermal expansion coefficient, heat capacity or thermal conductivity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
    • B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
    • B01D46/2418—Honeycomb filters
    • B01D46/2451—Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure
    • B01D46/2474—Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure of the walls along the length of the honeycomb
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
    • B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
    • B01D46/2418—Honeycomb filters
    • B01D46/2451—Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure
    • B01D46/2482—Thickness, height, width, length or diameter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
    • B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
    • B01D46/2418—Honeycomb filters
    • B01D46/2451—Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure
    • B01D46/2484—Cell density, area or aspect ratio
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
    • B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
    • B01D46/2418—Honeycomb filters
    • B01D46/2498—The honeycomb filter being defined by mathematical relationships
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/0006—Honeycomb structures
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/0022—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof obtained by a chemical conversion or reaction other than those relating to the setting or hardening of cement-like material or to the formation of a sol or a gel, e.g. by carbonising or pyrolysing preformed cellular materials based on polymers, organo-metallic or organo-silicon precursors
    • C04B38/0025—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof obtained by a chemical conversion or reaction other than those relating to the setting or hardening of cement-like material or to the formation of a sol or a gel, e.g. by carbonising or pyrolysing preformed cellular materials based on polymers, organo-metallic or organo-silicon precursors starting from inorganic materials only, e.g. metal foam; Lanxide type products
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/022—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
    • F01N3/0222—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous the structure being monolithic, e.g. honeycombs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2275/00—Filter media structures for filters specially adapted for separating dispersed particles from gases or vapours
    • B01D2275/30—Porosity of filtering material
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00793—Uses not provided for elsewhere in C04B2111/00 as filters or diaphragms
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0081—Uses not provided for elsewhere in C04B2111/00 as catalysts or catalyst carriers
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/90—Electrical properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S55/00—Gas separation
    • Y10S55/05—Methods of making filter
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S55/00—Gas separation
    • Y10S55/30—Exhaust treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Geometry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Geology (AREA)
  • Thermal Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Ceramic Products (AREA)
  • Processes For Solid Components From Exhaust (AREA)
  • Filtering Materials (AREA)
  • Filtering Of Dispersed Particles In Gases (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Materials For Medical Uses (AREA)
  • Seal Device For Vehicle (AREA)
  • Porous Artificial Stone Or Porous Ceramic Products (AREA)

Abstract

본 발명은 디젤 엔진의 배출 가스로부터의 디젤 매열 입자의 제거를 위해서 특별하게 설계된 다공성 유출 성형체에 관한 것이다. 이는, 탄화규소로 이루어진 교호적으로 밀집된 벌집 형태의 본체를 포함하며, 벽 두께가 1.25±0.5mm이고 다공성이 55 내지 60%이며 평균 세공 직경이 25 내지 70㎛이고 비투과율이 20 내지 100nPm임을 특징으로 한다.
제조방법에 있어서, 출발 물질인 규소 분말, 또는 규소 분말과 탄화규소 분말 분획 및/또는 탄소 분말 분획의 혼합물을 코크스화될 수 있는 유기 결합제와 배합시켜 미가공체로 성형시킨다. 이어서, 이를 불활성 대기중에서 코크스화 하소처리하고, 이러한 방식으로 수득된 성형체를 질소 가스 또는 질소 함유 불활성 가스의 존재하에 유리 규소가 하소반응에서 탄소와 함께 전환되어 탄화규소를 형성하는 온도로 가열한다. 추가로, 재결정화 하소온도는 2000℃보다 높게 설정한다.

Description

다공성 유출 성형체 및 이의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (24)

  1. 디젤 엔진의 배출 가스로부터의 디젤 매연 입자의 제거를 위해서 특별하게 설계되고, 탄화규소로 이루어진 교호적으로 밀집된 벌집 형태의 본체를 포함하며, 벽 두께가 1.25±0.5mm이고 다공성이 55 내지 60%이며 평균 세공 직경이 25 내지 70㎛이고 비투과율이 20 내지 100nPm임을 특징으로 하는, 다공성 유출 성형체.
  2. 제1항에 있어서, 성형체의 비전기저항 r이 하기 수학식(1)에 상응하는 rmin내지 rmax로 설정됨을 특징으로 하는 성형체.
    상기 수학식에서, Pset는 소요되는 전기 열 용량이고, Imax는 최대로 허용되는 전류 강도이고, Umax는 최대로 허용되는 전압이고, Aq는 성형체의 전류 수송 단면적이고, 1은 성형체의 전류 수송 종면적이고, 이때 Pset는 Umax×Imax이하이다.
  3. 제2항에 있어서, 성형체의 비전기저항 r이 0.1 내지 3Ω×cm임을 특징으로 하는 성형체.
  4. 제1항 내지 제3항 중의 어느 한 항에 있어서, 성형체가 주기율표의 제3 및 제5주족 또는 아족의 화합물 및/또는 원소를 함유함을 특징으로 하는 성형체.
  5. 제4항에 있어서, 성형체가 붕소원자를 0.05 내지 1.0중량%의 양으로 함유함을 특징으로 하는 성형체.
  6. 출발 물질인 규소 분말, 또한 규소 분말과 탄화규소 분말 분획 및/또는 탄소 분말 분획의 혼합물을 코크스화될 수 있는 유기 결합제와 배합시켜 미가공체 압출 성형시킨 다음, 이를 불활성 가스 대기중에서 코크스화 하소처리하고, 이러한 방식으로 수득된 성형체를 질소 가스 또는 질소 함유 불활성 가스의 존재하에 유리규소가 반응 하소에서 탄소와 함께 전환되어 탄화규소를 형성하기에 충분한 온도로 가열하고, 재결정화 하소가 2000℃보다 높은 온도에서 수행됨을 특징으로 하는, 다공성 유출 성형체의 제조방법.
  7. 제6항에 있어서, 재결정화 하소가 2100 내지 2300℃에서 수행됨을 특징으로 하는 방법.
  8. 제6항 또는 제7항에 있어서, 성형체를 연속적으로 재결정화 하소 온도하에 둠을 특징으로 하는 방법.
  9. 제6항 또는 제7항에 있어서, 반응 하소를 우선 수행한 다음, 재결정화 하소를 수행함을 특징으로 하는 방법.
  10. 제9항에 있어서, 반응 하소 직후에 재결정화 하소를 수행함을 특징으로 하는 방법.
  11. 제6항 내지 제10항 중의 어느 한 항에 있어서, 반응 하소가 1400 내지 1900℃, 바람직하게는 1700 내지 1900℃에서 수행됨을 특징으로 하는 방법.
  12. 제6항 내지 제11항 중의 어느 한 항에 있어서, 출발물질인 분말에 함유된 제1탄화규소의 분율이 25중량%이하임을 특징으로 하는 방법.
  13. 제6항 내지 제12항 중의 어느 한 항에 있어서, 탄수화물족 화합물로부터의 화합물 또는 이들 화합물의 변형물이 결합제로서 사용됨을 특징으로 하는 방법.
  14. 제13항에 있어서, 변형된 전분이 결합제로서 사용됨을 특징으로 하는 방법.
  15. 제6항 내지 제14항 중의 어느 한 항에 있어서, 결합제가 분말 형태로서 출발물질인 분말에 가해짐을 특징으로 하는 방법.
  16. 제6항 내지 제11항 중의 어느 한 항에 있어서, 실온에서 액체인 결합제가 사용됨을 특징으로 하는 방법.
  17. 제6항 내지 제13항 중의 어느 한 항에 있어서, 수용성 결합제가 사용됨을 특징으로 하는 방법.
  18. 제6항 내지 제14항 중의 어느 한 항에 있어서, 사용되는 결합제의 분율이, 결합제에 함유된 탄소를 포함하는 모든 탄소가 출발 분말중의 유리 규소에 대하여 0.8 내지 1.2의 화학양론비로 존재하도록 조정됨을 특징으로 하는 방법.
  19. 제6항 내지 제15항 중의 어느 한 항에 있어서, 전기 전도율을 증가시키기 위한 첨가제가, 전기 저항이 0.1 내지 3Ω×cm이도록 하는 양으로 가해짐을 특징으로 하는 방법.
  20. 제19항에 있어서, 주기율표의 제3 및 제5주족 또는 아족으로부터의 하나 이상의 화합물 및/또는 한 원소가 첨가제로서 사용됨을 특징으로 하는 방법.
  21. 제20항에 있어서, 붕소 화합물이 첨가제로서 사용됨을 특징으로 하는 방법.
  22. 제21항에 있어서, 붕소 화합물을, 출발 혼합물 중에 붕소원소가 0.05 내지 1.0중량% 존재할 수 있는 양으로 가함을 특징으로 하는 방법.
  23. 제19항 내지 제22항 중의 어느 한 항에 있어서, 첨가제를, 입자 크기가 10㎛를 초과하지 않는 분말 형태로 가함을 특징으로 하는 방법.
  24. 제6항 내지 제23항 중의 어느 한 항에 있어서, 평균 입자 크기는 10 내지 70㎛의 범위인 유리 규소 및/또는 탄소를 사용함을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970009908A 1996-03-23 1997-03-22 다공성투과 성형체 및 이의 제조방법 KR100484558B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP96104647.1 1996-03-23
EP96104647A EP0796830B1 (de) 1996-03-23 1996-03-23 Poröser durchströmbarer Formkörper sowie Verfahren zu seiner Herstellung

Publications (2)

Publication Number Publication Date
KR970064718A true KR970064718A (ko) 1997-10-13
KR100484558B1 KR100484558B1 (ko) 2005-08-04

Family

ID=8222590

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019970009908A KR100484558B1 (ko) 1996-03-23 1997-03-22 다공성투과 성형체 및 이의 제조방법

Country Status (8)

Country Link
US (2) US5853444A (ko)
EP (1) EP0796830B1 (ko)
JP (1) JP4029175B2 (ko)
KR (1) KR100484558B1 (ko)
AT (1) ATE222576T1 (ko)
DE (1) DE59609574D1 (ko)
ES (1) ES2180668T3 (ko)
PT (1) PT796830E (ko)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19809976C2 (de) 1998-03-09 2001-09-06 Heimbach Gmbh Thomas Josef Formkörper aus einer elektrisch leitfähigen Keramikverbindung sowie Verfahren zur Herstellung des Formkörpers
JP2002530175A (ja) * 1998-11-20 2002-09-17 コーニンクレッカ フィリップス エレクトロニクス エヌ ヴィ コードレス走査ヘッドの充電器を備える超音波診断イメージングシステム
JP4642955B2 (ja) * 1999-06-23 2011-03-02 イビデン株式会社 触媒担体およびその製造方法
DE20023990U1 (de) * 1999-09-29 2008-09-18 IBIDEN CO., LTD., Ogaki-shi Keramische Filteranordnung
CA2392216A1 (en) 1999-11-16 2001-05-25 Ibiden Co., Ltd. Catalyst and method of producing the same
US6555031B2 (en) 2000-06-19 2003-04-29 Corning Incorporated Process for producing silicon carbide bodies
EP1296889A4 (en) * 2000-06-19 2007-03-07 Corning Inc PLASTICIZED MIXTURE AND METHOD OF USING THE MIXTURE
DE20016803U1 (de) 2000-09-29 2000-12-28 Heimbach Gmbh Thomas Josef Filtereinrichtung
DE20100882U1 (de) 2001-01-18 2002-05-23 Heimbach Gmbh Thomas Josef Filtereinrichtung, insbesondere als Rußfilter für Dieselmotorabgase
JP4094824B2 (ja) * 2001-04-04 2008-06-04 日本碍子株式会社 ハニカム型セラミックス質フィルター
JP5052717B2 (ja) 2001-05-02 2012-10-17 日本碍子株式会社 ハニカム構造体、及びそれを用いたハニカムフィルター、コンバーターシステム
EP1256368A3 (en) * 2001-05-11 2002-12-18 Asahi Glass Company Ltd. Method for sealing a silicon nitride filter and composition for sealing
US7431892B2 (en) * 2001-09-25 2008-10-07 Piezo Top Ltd. Apparatus for sterilizing a liquid with focused acoustic standing waves
JP4279497B2 (ja) * 2002-02-26 2009-06-17 日本碍子株式会社 ハニカムフィルタ
JP4227347B2 (ja) * 2002-03-29 2009-02-18 日本碍子株式会社 多孔質材料及びその製造方法
JP2004188303A (ja) * 2002-12-10 2004-07-08 Ngk Insulators Ltd セラミックハニカムフィルタ
US7179316B2 (en) * 2003-06-25 2007-02-20 Corning Incorporated Cordierite filters with reduced pressure drop
DE10331049B4 (de) * 2003-07-09 2010-04-08 Saint-Gobain Industriekeramik Rödental GmbH Verfahren zur Herstellung eines porösen Keramikkörpers, danach hergestellter poröser Keramikkörper und dessen Verwendung
DE102004039343B4 (de) * 2003-08-16 2013-01-17 Helsa-Automotive Gmbh & Co. Kg Mechanisch stabiler, poröser Aktivkohleformkörper mit hohem Adsorptionsvermögen, Verfahren zur Herstellung desselben und Filtersystem
US7759276B2 (en) 2004-07-23 2010-07-20 Helsa-Automotive Gmbh & Co. Kg Adsorptive formed body having an inorganic amorphous supporting structure, and process for the production thereof
US7867313B2 (en) 2005-07-05 2011-01-11 Helsa-Automotive Gmbh & Co. Kg Porous β-SiC-containing ceramic molded article comprising an aluminum oxide coating, and method for the production thereof
EP1741687B1 (de) 2005-07-05 2011-10-12 MANN+HUMMEL Innenraumfilter GmbH & Co. KG Poröser beta-SIC-haltiger keramischer Formkörper und Verfahren zu dessen Herstellung aus einem Kohlenstoff-haltigen Formkörper
EP1741685B1 (de) 2005-07-05 2014-04-30 MANN+HUMMEL Innenraumfilter GmbH & Co. KG Poröser beta-SiC-haltiger keramischer Formkörper und Verfahren zu dessen Herstellung.
FR2889184B1 (fr) * 2005-07-29 2007-10-19 Saint Gobain Ct Recherches Procede de preparation d'une structure poreuse utilisant des agents porogenes a base de silice
WO2007015550A1 (ja) * 2005-08-03 2007-02-08 Ibiden Co., Ltd. 炭化珪素質焼成用治具及び多孔質炭化珪素体の製造方法
EP1826370A1 (en) * 2006-02-23 2007-08-29 Ibiden Co., Ltd. Honeycomb structure
JPWO2007097056A1 (ja) * 2006-02-23 2009-07-09 イビデン株式会社 ハニカム構造体および排ガス浄化装置
JP5313658B2 (ja) * 2006-03-07 2013-10-09 日本碍子株式会社 セラミック構造体及びその製造方法
FR2899493B1 (fr) * 2006-04-10 2008-05-23 Saint Gobain Ct Recherches Structure de purification incorporant un systeme de catalyse electrochimique
DE102006026161A1 (de) * 2006-05-23 2007-11-29 Robert Bosch Gmbh Filtereinrichtung, insbesondere für ein Abgassystem einer Brennkraftmaschine
DE102008041530A1 (de) 2008-08-25 2010-03-04 Dirk Dombrowski Verfahren und Abgasanlage zur Reinigung SOx-haltiger Abgase, insbesondere von Schiffsbrennkraftmaschinen
CN101530716B (zh) * 2009-03-11 2012-07-04 中国科学院生态环境研究中心 一种空气净化方法
PL2597075T3 (pl) 2011-11-23 2016-09-30 Porowata wypraska zawierająca alfa-SiC o całkowicie otwartej strukturze porów
JP2016067995A (ja) * 2014-09-29 2016-05-09 イビデン株式会社 ハニカムフィルタ及びその製造方法

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2938807A (en) * 1957-08-13 1960-05-31 James C Andersen Method of making refractory bodies
US4019913A (en) * 1975-07-18 1977-04-26 Norton Company Process for fabricating silicon carbide articles
US4535589A (en) * 1981-05-26 1985-08-20 Nippon Soken, Inc. Exhaust gas cleaning device for internal combustion engine
US4505107A (en) * 1981-10-26 1985-03-19 Nippondenso Co., Ltd. Exhaust gas cleaning apparatus
DE3305529A1 (de) * 1983-02-18 1984-08-23 Kernforschungsanlage Jülich GmbH, 5170 Jülich Verfahren zur herstellung poroeser, durchstroembarer formkoerper aus siliziumkarbid
JPS60255671A (ja) * 1984-05-29 1985-12-17 イビデン株式会社 高強度多孔質炭化ケイ素焼結体とその製造方法
GB8605058D0 (en) * 1986-02-28 1986-04-09 Porous Element Heating Ltd Removal of particulate material from gas
DE3608801A1 (de) * 1986-03-15 1987-09-17 Fev Forsch Energietech Verbr Verfahren und vorrichtung zur regeneration von partikelfiltersystemen
US4744216A (en) * 1986-10-20 1988-05-17 Ford Motor Company Electrical ignition device for regeneration of a particulate trap
US4912076A (en) * 1987-10-15 1990-03-27 Swiss Aluminium Ltd. Filter for cleaning exhaust gases of diesel engines
JPH0657624B2 (ja) * 1987-11-30 1994-08-03 イビデン株式会社 炭化ケイ素質ハニカム構造体及びその製造方法
US4979364A (en) * 1988-03-11 1990-12-25 Fleck Carl M Diesel fuel exhaust gas filter
WO1989009648A1 (en) * 1988-04-08 1989-10-19 Per Stobbe A method of filtering particles from flue gas, a flue gas filter means and a vehicle
JP2728457B2 (ja) * 1988-10-01 1998-03-18 イビデン株式会社 導電性炭化ケイ素焼結多孔体の製造方法
US5087272A (en) * 1990-10-17 1992-02-11 Nixdorf Richard D Filter and means for regeneration thereof
DE4130630C2 (de) * 1991-09-14 1994-12-08 Forschungszentrum Juelich Gmbh Verfahren zur Herstellung poröser, durchströmbarer Formkörper aus Siliciumcarbid und Dieselruß-Filterelement
DK205191D0 (da) * 1991-12-20 1991-12-20 Per Stobbe Roeggasfilter
FR2705340B1 (fr) * 1993-05-13 1995-06-30 Pechiney Recherche Fabrication de mousse de carbure de silicium à partir d'une mousse de polyuréthane imprégnée de résine contenant du silicium.
US5423904A (en) * 1993-05-28 1995-06-13 Dasgupta; Sankar Exhaust gas filter
JP3431670B2 (ja) * 1993-09-14 2003-07-28 イビデン株式会社 排気ガスフィルタの製造方法
DE4413127C1 (de) * 1994-04-19 1995-10-05 Forschungszentrum Juelich Gmbh Verfahren zur Herstellung poröser, durchströmbarer Formkörper aus Siliciumcarbid und Formkörper

Also Published As

Publication number Publication date
KR100484558B1 (ko) 2005-08-04
US6017473A (en) 2000-01-25
PT796830E (pt) 2003-01-31
ES2180668T3 (es) 2003-02-16
EP0796830A1 (de) 1997-09-24
JPH1015323A (ja) 1998-01-20
US5853444A (en) 1998-12-29
JP4029175B2 (ja) 2008-01-09
EP0796830B1 (de) 2002-08-21
DE59609574D1 (de) 2002-09-26
ATE222576T1 (de) 2002-09-15

Similar Documents

Publication Publication Date Title
KR970064718A (ko) 다공성 유출 성형체 및 이의 제조방법
US7951324B2 (en) Method for manufacturing honeycomb structure
US20080284067A1 (en) Method for manufacturing material for silicon carbide fired body and method for manufacturing honeycomb structure
EP1905752A2 (en) Method for manufacturing honeycomb structured body and material composition for honeycomb fired body
CA2189516A1 (en) Sintering alpha silicon carbide powder with multiple sintering aids
DE3672207D1 (de) Katalysatortraeger mit hoher widerstandskraft und mit grosser spezifischer oberflaeche und verfahren zur herstellung derselben.
JPH05138043A (ja) 特に排気ガスの後燃焼用の触媒系及び該触媒系の製造方法
KR101679883B1 (ko) 다공성 바늘형 뮬라이트체의 제조 방법
KR20070004930A (ko) 낮은 열팽창성 제품
WO2002070433A1 (fr) Structure en nid d'abeilles
KR100227970B1 (ko) 탄화규소로된 다공성, 관류성 성형체의 제조방법 및 디이젤 매연-필터소자
JP2002201082A (ja) ハニカム構造体及びその製造方法
US20150225302A1 (en) Improved porous bodies comprised of mullite and methods of forming them
JPH02282442A (ja) アルミナイド構造
KR101777676B1 (ko) 콜타르피치와 물유리를 이용한 흡착 담체 및 그 제조방법
JP2612878B2 (ja) 炭化ケイ素質ハニカム構造体の製造方法
JPS61191575A (ja) 多孔質炭化珪素焼結体とその製造方法
JP3496251B2 (ja) 多孔質セラミックスの製造方法
JP4468541B2 (ja) 再結晶ＳｉＣの製造方法
JP5120793B2 (ja) 炭化ケイ素多孔体の製造方法
JPH01192765A (ja) 炭化ケイ素質ハニカム構造体の製造方法
JPS6117472A (ja) 多孔質炭化けい素焼結体の製造方法
JPS6046981A (ja) セラミツク多孔体
CN115466132A (zh) 一种制备氮化硅蜂窝陶瓷的方法
SU1728195A1 (ru) Огнеупорна масса

Legal Events

Date Code Title Description
N231 Notification of change of applicant
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20080408

Year of fee payment: 4

LAPS Lapse due to unpaid annual fee