KR970011017A - 구리 또는 구리합금용 마이크로 엣칭 조성물 - Google Patents
구리 또는 구리합금용 마이크로 엣칭 조성물 Download PDFInfo
- Publication number
- KR970011017A KR970011017A KR1019960031430A KR19960031430A KR970011017A KR 970011017 A KR970011017 A KR 970011017A KR 1019960031430 A KR1019960031430 A KR 1019960031430A KR 19960031430 A KR19960031430 A KR 19960031430A KR 970011017 A KR970011017 A KR 970011017A
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- KR
- South Korea
- Prior art keywords
- acid
- copper
- group
- composition
- chloride
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract 4
- 229910000881 Cu alloy Inorganic materials 0.000 title claims abstract 4
- 229910052802 copper Inorganic materials 0.000 title claims abstract 4
- 239000010949 copper Substances 0.000 title claims abstract 4
- 238000005530 etching Methods 0.000 title claims 2
- 150000007524 organic acids Chemical class 0.000 claims abstract 5
- 239000002253 acid Substances 0.000 claims abstract 4
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims abstract 3
- 238000010494 dissociation reaction Methods 0.000 claims abstract 3
- 230000005593 dissociations Effects 0.000 claims abstract 3
- -1 halide ion Chemical class 0.000 claims abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 6
- JOOXCMJARBKPKM-UHFFFAOYSA-N 4-oxopentanoic acid Chemical compound CC(=O)CCC(O)=O JOOXCMJARBKPKM-UHFFFAOYSA-N 0.000 claims 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims 4
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims 4
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 4
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 claims 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims 4
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims 4
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims 4
- 150000001875 compounds Chemical class 0.000 claims 3
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical class Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims 3
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims 2
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 claims 2
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 2
- RDFQSFOGKVZWKF-UHFFFAOYSA-N 3-hydroxy-2,2-dimethylpropanoic acid Chemical compound OCC(C)(C)C(O)=O RDFQSFOGKVZWKF-UHFFFAOYSA-N 0.000 claims 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims 2
- 239000005711 Benzoic acid Substances 0.000 claims 2
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 claims 2
- JJLJMEJHUUYSSY-UHFFFAOYSA-L Copper hydroxide Chemical class [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 claims 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims 2
- 235000011054 acetic acid Nutrition 0.000 claims 2
- 239000001361 adipic acid Substances 0.000 claims 2
- 235000011037 adipic acid Nutrition 0.000 claims 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims 2
- 235000010323 ascorbic acid Nutrition 0.000 claims 2
- 229960005070 ascorbic acid Drugs 0.000 claims 2
- 239000011668 ascorbic acid Substances 0.000 claims 2
- 235000010233 benzoic acid Nutrition 0.000 claims 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims 2
- 235000013985 cinnamic acid Nutrition 0.000 claims 2
- 229930016911 cinnamic acid Natural products 0.000 claims 2
- 235000015165 citric acid Nutrition 0.000 claims 2
- QTMDXZNDVAMKGV-UHFFFAOYSA-L copper(ii) bromide Chemical class [Cu+2].[Br-].[Br-] QTMDXZNDVAMKGV-UHFFFAOYSA-L 0.000 claims 2
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims 2
- 235000019253 formic acid Nutrition 0.000 claims 2
- LDHQCZJRKDOVOX-IHWYPQMZSA-N isocrotonic acid Chemical compound C\C=C/C(O)=O LDHQCZJRKDOVOX-IHWYPQMZSA-N 0.000 claims 2
- 239000004310 lactic acid Substances 0.000 claims 2
- 235000014655 lactic acid Nutrition 0.000 claims 2
- 229940040102 levulinic acid Drugs 0.000 claims 2
- 239000001630 malic acid Substances 0.000 claims 2
- 235000011090 malic acid Nutrition 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 claims 2
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims 2
- 235000001968 nicotinic acid Nutrition 0.000 claims 2
- 229960003512 nicotinic acid Drugs 0.000 claims 2
- 239000011664 nicotinic acid Substances 0.000 claims 2
- 235000006408 oxalic acid Nutrition 0.000 claims 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 claims 2
- 235000019260 propionic acid Nutrition 0.000 claims 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims 2
- 235000002639 sodium chloride Nutrition 0.000 claims 2
- 229940005605 valeric acid Drugs 0.000 claims 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims 2
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 claims 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims 1
- 229910021590 Copper(II) bromide Inorganic materials 0.000 claims 1
- 235000019270 ammonium chloride Nutrition 0.000 claims 1
- ODWXUNBKCRECNW-UHFFFAOYSA-M bromocopper(1+) Chemical compound Br[Cu+] ODWXUNBKCRECNW-UHFFFAOYSA-M 0.000 claims 1
- 239000001110 calcium chloride Substances 0.000 claims 1
- 229910001628 calcium chloride Inorganic materials 0.000 claims 1
- 235000011148 calcium chloride Nutrition 0.000 claims 1
- 229910001431 copper ion Inorganic materials 0.000 claims 1
- 229960003280 cupric chloride Drugs 0.000 claims 1
- 229940093915 gynecological organic acid Drugs 0.000 claims 1
- 235000005985 organic acids Nutrition 0.000 claims 1
- 239000001103 potassium chloride Substances 0.000 claims 1
- 235000011164 potassium chloride Nutrition 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000011780 sodium chloride Substances 0.000 claims 1
- 239000011592 zinc chloride Substances 0.000 claims 1
- 235000005074 zinc chloride Nutrition 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
- C23F1/10—Etching compositions
- C23F1/14—Aqueous compositions
- C23F1/16—Acidic compositions
- C23F1/18—Acidic compositions for etching copper or alloys thereof
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
- C23F1/10—Etching compositions
- C23F1/14—Aqueous compositions
- C23F1/16—Acidic compositions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/10—Other heavy metals
- C23G1/103—Other heavy metals copper or alloys of copper
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/38—Improvement of the adhesion between the insulating substrate and the metal
- H05K3/382—Improvement of the adhesion between the insulating substrate and the metal by special treatment of the metal
- H05K3/383—Improvement of the adhesion between the insulating substrate and the metal by special treatment of the metal by microetching
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/12—Using specific substances
- H05K2203/125—Inorganic compounds, e.g. silver salt
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/02—Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding
- H05K3/06—Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding the conductive material being removed chemically or electrolytically, e.g. by photo-etch process
- H05K3/061—Etching masks
- H05K3/064—Photoresists
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/22—Secondary treatment of printed circuits
- H05K3/28—Applying non-metallic protective coatings
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4611—Manufacturing multilayer circuits by laminating two or more circuit boards
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- ing And Chemical Polishing (AREA)
- Manufacturing Of Printed Circuit Boards (AREA)
- Electric Connection Of Electric Components To Printed Circuits (AREA)
- Weting (AREA)
- Manufacturing Of Printed Wiring (AREA)
Abstract
(a) 제2구리 이온원, (b) 산해리정수(pKa) 5 이하의 유기산, (c) 할라이드 이온원 및 (d) 물을 함유하는 구리 또는 구리 합금용 마이크로 엣칭 조성물. 이 조성물은 프리프레그 및 레지스트와 같은 수지에 대해 우수한 부착력 및 뛰어난 납땜능을 나타내는 구리 또는 구리합금 표면을 생성할 수 있다. 이 조성물은 고집적의 정교한 라인 패턴을 갖는 인쇄회로기판의 제조에 매우 적합하다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (5)
- (a) 제2구리 이온원, (b) 산해리정수(pKa) 5 이하의 유기산, (c) 할라이드 이온원 및 (d) 물을 함유하는 구리 또는 구리 합금용 마이크로 엣칭 조성물.
- 제1항에 있어서, 제2구리 이온원 화합물이 유기산의 제2구리염, 염화 제2구리, 브롬화 제2구리 및 수산화 제2구리로 구성된 군에서 선택된 화합물인 마이크로 엣칭 조성물.
- 제2항에 있어서, 유기산이 포름산, 아세트산, 프로디온산, 부티르산, 발데르산, 카프론산, 아크릴산, 크로톤산, 이소크로톤산, 옥살산, 말론산, 숙신산, 글루타르산, 아디프산, 피멜산 말레산, 벤조산, 프탈산, 신남산, 글리콜산, 젖산, 말산, 시트로산, 술팜산, β-클로로프로피온산, 니코틴산, 아스코르브산, 히드록실 피발산 및 레블린산으로 이루어진 군에서 선택된 것이 특징인 마이크로 엣칭 조성물.
- 제1항에 있어서, 유기산이 포름산, 아세트산, 프로피온산, 부티르산, 발레르산, 카프론산, 아크릴산, 크로톤산, 이소크로톤산, 옥살산, 말론산, 숙신산, 글루타르산, 아디프산, 피멜산 말레산, 벤조산, 프탈산, 신남산, 글리콜산, 젖산, 말산, 시트로산, 술팜산, β-클로로프로피온산, 니코틴산, 아스코르브산, 히드록실 피발산 및 레블린산으로 이루어진 군에서 선택된 5 이하의 산해리정수(pKa)를 갖는 것이 특징인 마이크로 엣칭 조성물.
- 제1항에 있어서, 할라이드 이온원의 염산, 브롬화수소산, 염화나트륨, 염화칼슘, 염화칼륨, 염화암모늄, 브롬화칼륨, 염화구리, 브롬화구리, 염화아연, 염화철 및 브롬화주석으로 이루어진 군에서 선택된 화합물인 것이 특징인 마이크로 엣칭 조성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP196637/1995 | 1995-08-01 | ||
JP7196637A JP2923524B2 (ja) | 1995-08-01 | 1995-08-01 | 銅および銅合金のマイクロエッチング剤並びにマイクロエッチング方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR970011017A true KR970011017A (ko) | 1997-03-27 |
KR100409189B1 KR100409189B1 (ko) | 2004-06-04 |
Family
ID=16361086
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019960031430A KR100409189B1 (ko) | 1995-08-01 | 1996-07-30 | 구리또는구리합금용마이크로엣칭조성물 |
Country Status (7)
Country | Link |
---|---|
US (1) | US5807493A (ko) |
EP (1) | EP0757118B1 (ko) |
JP (1) | JP2923524B2 (ko) |
KR (1) | KR100409189B1 (ko) |
CN (1) | CN1090686C (ko) |
DE (1) | DE69612336T2 (ko) |
TW (1) | TW366368B (ko) |
Families Citing this family (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW374802B (en) * | 1996-07-29 | 1999-11-21 | Ebara Densan Ltd | Etching composition, method for roughening copper surface and method for producing printed wiring board |
US6146701A (en) * | 1997-06-12 | 2000-11-14 | Macdermid, Incorporated | Process for improving the adhension of polymeric materials to metal surfaces |
US6162503A (en) * | 1997-06-12 | 2000-12-19 | Macdermid, Incorporated | Process for improving the adhesion of polymeric materials to metal surfaces |
US5869130A (en) * | 1997-06-12 | 1999-02-09 | Mac Dermid, Incorporated | Process for improving the adhesion of polymeric materials to metal surfaces |
JPH1187928A (ja) * | 1997-07-08 | 1999-03-30 | Ibiden Co Ltd | 多層プリント配線板 |
US6141870A (en) | 1997-08-04 | 2000-11-07 | Peter K. Trzyna | Method for making electrical device |
US6284309B1 (en) * | 1997-12-19 | 2001-09-04 | Atotech Deutschland Gmbh | Method of producing copper surfaces for improved bonding, compositions used therein and articles made therefrom |
US6331490B1 (en) * | 1998-03-13 | 2001-12-18 | Semitool, Inc. | Process for etching thin-film layers of a workpiece used to form microelectric circuits or components |
TW367415B (en) * | 1998-06-18 | 1999-08-21 | United Microelectronics Corp | Test method for ball grid array integrated circuit |
CN1316175A (zh) * | 1998-07-08 | 2001-10-03 | 伊比登株式会社 | 印刷电路板及其制造方法 |
JP4063475B2 (ja) * | 1999-11-10 | 2008-03-19 | メック株式会社 | 銅または銅合金のエッチング剤 |
US6383272B1 (en) | 2000-06-08 | 2002-05-07 | Donald Ferrier | Process for improving the adhesion of polymeric materials to metal surfaces |
US6419784B1 (en) | 2000-06-21 | 2002-07-16 | Donald Ferrier | Process for improving the adhesion of polymeric materials to metal surfaces |
DE10066028C2 (de) * | 2000-07-07 | 2003-04-24 | Atotech Deutschland Gmbh | Kupfersubstrat mit aufgerauhten Oberflächen |
US6506314B1 (en) * | 2000-07-27 | 2003-01-14 | Atotech Deutschland Gmbh | Adhesion of polymeric materials to metal surfaces |
US6554948B1 (en) | 2000-08-22 | 2003-04-29 | Donald Ferrier | Process for improving the adhesion of polymeric materials to metal surfaces |
KR100379824B1 (ko) * | 2000-12-20 | 2003-04-11 | 엘지.필립스 엘시디 주식회사 | 식각용액 및 식각용액으로 패턴된 구리배선을 가지는전자기기용 어레이기판 |
JP4309602B2 (ja) | 2001-04-25 | 2009-08-05 | メック株式会社 | 銅または銅合金と樹脂との接着性を向上させる方法、ならびに積層体 |
US6627546B2 (en) * | 2001-06-29 | 2003-09-30 | Ashland Inc. | Process for removing contaminant from a surface and composition useful therefor |
US6746547B2 (en) | 2002-03-05 | 2004-06-08 | Rd Chemical Company | Methods and compositions for oxide production on copper |
US7232478B2 (en) | 2003-07-14 | 2007-06-19 | Enthone Inc. | Adhesion promotion in printed circuit boards |
US20050067378A1 (en) * | 2003-09-30 | 2005-03-31 | Harry Fuerhaupter | Method for micro-roughening treatment of copper and mixed-metal circuitry |
JP2005150554A (ja) * | 2003-11-18 | 2005-06-09 | Ngk Spark Plug Co Ltd | 配線基板の製造方法 |
US7393461B2 (en) * | 2005-08-23 | 2008-07-01 | Kesheng Feng | Microetching solution |
EP1780309B8 (en) * | 2005-10-25 | 2010-12-15 | ATOTECH Deutschland GmbH | Composition and method for improved adhesion of polymeric materials to copper or copper alloy surfaces |
US7875558B2 (en) | 2005-12-21 | 2011-01-25 | Kesheng Feng | Microetching composition and method of using the same |
US7456114B2 (en) * | 2005-12-21 | 2008-11-25 | Kesheng Feng | Microetching composition and method of using the same |
US8518281B2 (en) * | 2008-06-03 | 2013-08-27 | Kesheng Feng | Acid-resistance promoting composition |
EP2241653B1 (en) | 2009-04-15 | 2017-09-06 | ATOTECH Deutschland GmbH | Composition and method for micro etching of copper and copper alloys |
US8758634B2 (en) | 2010-05-26 | 2014-06-24 | Atotech Deutschland Gmbh | Composition and method for micro etching of copper and copper alloys |
CN102985596B (zh) * | 2010-06-18 | 2016-08-10 | 三菱瓦斯化学株式会社 | 用于包含铜层和钼层的多层结构膜的蚀刻液 |
US9763336B2 (en) | 2010-07-06 | 2017-09-12 | Atotech Deutschland Gmbh | Methods of treating metal surfaces and devices formed thereby |
US9345149B2 (en) | 2010-07-06 | 2016-05-17 | Esionic Corp. | Methods of treating copper surfaces for enhancing adhesion to organic substrates for use in printed circuit boards |
CN102181865A (zh) * | 2011-04-29 | 2011-09-14 | 广州市天承化工有限公司 | 可循环再用铜和铜合金表面微蚀刻处理剂及处理系统 |
JP5219008B1 (ja) | 2012-07-24 | 2013-06-26 | メック株式会社 | 銅のマイクロエッチング剤及びその補給液、並びに配線基板の製造方法 |
SG11201408660QA (en) | 2012-09-28 | 2015-01-29 | Mec Co Ltd | Microetching agent for copper, supplementary liquid for same, and manufacturing method for circuit board |
CN104694909B (zh) * | 2014-07-03 | 2017-01-25 | 广东丹邦科技有限公司 | 一种铜表面粗化剂 |
EP3034654B1 (en) | 2014-12-19 | 2017-10-25 | ATOTECH Deutschland GmbH | Composition and method for micro etching of copper and copper alloys |
WO2017141799A1 (ja) | 2016-02-19 | 2017-08-24 | メック株式会社 | 銅のマイクロエッチング剤および配線基板の製造方法 |
JP6218000B2 (ja) | 2016-02-19 | 2017-10-25 | メック株式会社 | 銅のマイクロエッチング剤および配線基板の製造方法 |
KR102663554B1 (ko) * | 2016-06-10 | 2024-05-08 | 삼성디스플레이 주식회사 | 식각액 조성물 및 이를 이용한 박막 트랜지스터 표시판의 제조 방법 |
CN108930038B (zh) * | 2017-05-22 | 2021-03-16 | 东友精细化工有限公司 | 银薄膜蚀刻液组合物、蚀刻方法和金属图案的形成方法 |
JP6338232B1 (ja) | 2017-09-22 | 2018-06-06 | メック株式会社 | 銅表面の粗化方法および配線基板の製造方法 |
CN110408932A (zh) * | 2018-04-27 | 2019-11-05 | 惠州市鸿宇泰科技有限公司 | 用于线路板夹具除铜的除铜剂 |
CN109267127B (zh) * | 2018-08-30 | 2023-09-05 | 扬州虹扬科技发展有限公司 | 一种铜基材处理液及预处理工艺 |
CN113170585B (zh) | 2020-06-02 | 2023-04-04 | Mec股份有限公司 | 微蚀刻剂和配线基板的制造方法 |
CN113881993A (zh) * | 2021-09-29 | 2022-01-04 | 新阳硅密(上海)半导体技术有限公司 | 一种可优化电镀填孔能力的工艺方法 |
CN115110085A (zh) * | 2021-10-23 | 2022-09-27 | 赵晓峰 | 一种铜及合金过氧化氢化学抛光体系中改进脱膜工序的新方法 |
CN114457335B (zh) * | 2022-02-15 | 2023-10-27 | 江西省科学院应用物理研究所 | 一种铜铁碳合金金相浸蚀剂及其使用方法 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3458371A (en) * | 1965-11-12 | 1969-07-29 | Photo Engravers Research Inst | Composition and process for powderless etching |
US3458372A (en) * | 1965-11-12 | 1969-07-29 | Photo Engravers Research Inst | Powderless etching |
DE1621516B1 (de) * | 1967-10-11 | 1971-10-07 | Siemens Ag | Verfahren zur Verbesserung der Loetbarkeit von Leiterplatten aus Kupfer oder Kupferlegierungen durch AEtzen |
US3650958A (en) * | 1970-07-24 | 1972-03-21 | Shipley Co | Etchant for cupreous metals |
GB1294804A (en) * | 1970-07-24 | 1972-11-01 | Shipley Co | Etchant for cupreous metals |
JPS4894502A (ko) * | 1972-03-18 | 1973-12-05 | ||
JPS5144532A (ja) * | 1974-10-15 | 1976-04-16 | Hodogaya Chemical Co Ltd | Donokokushokueki |
SU558037A1 (ru) * | 1975-10-30 | 1977-05-15 | Украинский Научно-Исследовательский Институт Полиграфической Промышленности | Водный раствор дл травлени меди и ее сплавов |
JPS52110235A (en) * | 1976-03-03 | 1977-09-16 | Nippon Paint Co Ltd | Industrial process for forming patina |
JPS5330435A (en) * | 1976-09-02 | 1978-03-22 | Sumitomo Metal Mining Co | Etching liquid |
EP0364132A1 (en) * | 1988-09-29 | 1990-04-18 | Shikoku Chemicals Corporation | Method for forming conversion coating on surface of copper or copper alloy |
JP2666470B2 (ja) * | 1989-05-09 | 1997-10-22 | 日立化成工業株式会社 | 無電解めっき法 |
JPH0375386A (ja) * | 1989-08-18 | 1991-03-29 | Metsuku Kk | 錫又は錫‐鉛合金の剥離方法 |
EP0428383A1 (en) * | 1989-11-13 | 1991-05-22 | Shikoku Chemicals Corporation | Process for surface treatment of copper and copper alloy |
US5037482A (en) * | 1990-02-16 | 1991-08-06 | Macdermid, Incorporated | Composition and method for improving adhesion of coatings to copper surfaces |
DE4118764A1 (de) * | 1991-06-07 | 1992-12-10 | Chema Technologien Gmbh | Verfahren zum aetzen von kupfer |
TW217426B (ko) * | 1992-01-08 | 1993-12-11 | Mekku Kk | |
JPH06287774A (ja) * | 1993-04-05 | 1994-10-11 | Metsuku Kk | 銅および銅合金の表面処理剤 |
TW270944B (ko) * | 1993-05-10 | 1996-02-21 | Shikoku Kakoki Co Ltd | |
TW263534B (ko) * | 1993-08-11 | 1995-11-21 | Makkusu Kk | |
JP2781954B2 (ja) * | 1994-03-04 | 1998-07-30 | メック株式会社 | 銅および銅合金の表面処理剤 |
-
1995
- 1995-08-01 JP JP7196637A patent/JP2923524B2/ja not_active Expired - Lifetime
-
1996
- 1996-07-04 TW TW085108076A patent/TW366368B/zh active
- 1996-07-10 CN CN96110803A patent/CN1090686C/zh not_active Expired - Lifetime
- 1996-07-22 DE DE69612336T patent/DE69612336T2/de not_active Expired - Lifetime
- 1996-07-22 EP EP96111792A patent/EP0757118B1/en not_active Expired - Lifetime
- 1996-07-24 US US08/686,068 patent/US5807493A/en not_active Expired - Lifetime
- 1996-07-30 KR KR1019960031430A patent/KR100409189B1/ko active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
KR100409189B1 (ko) | 2004-06-04 |
DE69612336T2 (de) | 2001-09-20 |
JP2923524B2 (ja) | 1999-07-26 |
US5807493A (en) | 1998-09-15 |
CN1147025A (zh) | 1997-04-09 |
TW366368B (en) | 1999-08-11 |
EP0757118A1 (en) | 1997-02-05 |
CN1090686C (zh) | 2002-09-11 |
EP0757118B1 (en) | 2001-04-04 |
JPH0941163A (ja) | 1997-02-10 |
DE69612336D1 (de) | 2001-05-10 |
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