KR970007493A - 광-가교결합성 액정 1,2-페닐렌 유도체 - Google Patents

광-가교결합성 액정 1,2-페닐렌 유도체 Download PDF

Info

Publication number
KR970007493A
KR970007493A KR1019960030809A KR19960030809A KR970007493A KR 970007493 A KR970007493 A KR 970007493A KR 1019960030809 A KR1019960030809 A KR 1019960030809A KR 19960030809 A KR19960030809 A KR 19960030809A KR 970007493 A KR970007493 A KR 970007493A
Authority
KR
South Korea
Prior art keywords
coo
cyano
ooc
halogen
independently
Prior art date
Application number
KR1019960030809A
Other languages
English (en)
Other versions
KR100391862B1 (ko
Inventor
스티븐 켈리
Original Assignee
클라우스너 프리돌린, 보러 롤란드
롤리크 아게
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 클라우스너 프리돌린, 보러 롤란드, 롤리크 아게 filed Critical 클라우스너 프리돌린, 보러 롤란드
Publication of KR970007493A publication Critical patent/KR970007493A/ko
Application granted granted Critical
Publication of KR100391862B1 publication Critical patent/KR100391862B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/28—Radicals substituted by singly-bound oxygen or sulphur atoms
    • C07D213/30—Oxygen atoms
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/54—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and etherified hydroxy groups bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/55—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and esterified hydroxy groups bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/73—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
    • C07C69/734—Ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C07C69/84—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring of monocyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of a six-membered aromatic ring
    • C07C69/92—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring of monocyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of a six-membered aromatic ring with etherified hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C07C69/94—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring of polycyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/32—One oxygen, sulfur or nitrogen atom
    • C07D239/34—One oxygen atom
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
    • C09K19/20—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers
    • C09K19/2007—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers the chain containing -COO- or -OCO- groups
    • C09K19/2014—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers the chain containing -COO- or -OCO- groups containing additionally a linking group other than -COO- or -OCO-, e.g. -CH2-CH2-, -CH=CH-, -C=C-; containing at least one additional carbon atom in the chain containing -COO- or -OCO- groups, e.g. -(CH2)m-COO-(CH2)n-
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
    • C09K19/3001—Cyclohexane rings
    • C09K19/3066—Cyclohexane rings in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers
    • C09K19/3068—Cyclohexane rings in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers chain containing -COO- or -OCO- groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/38—Polymers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K2019/0444—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group
    • C09K2019/0448—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group the end chain group being a polymerizable end group, e.g. -Sp-P or acrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
  • Liquid Crystal Substances (AREA)
  • Pyridine Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

본 발명은 하기 일반식(1)의 광 가교결합성 액정 화합물, 상기 화합물을 함유하는 액정 혼합물 및 이들을 가교결합된 상태로 광학 소자에 사용하는 용도에 관한 것이다 :
상기 식에서, 고리 A 내지 F는 각각 피리딘-2,5-디일, 피리미딘-2,5-디일, 트란스-1,4-사이클로헥실렌, 트랜스-1,3-디옥산-2,5-디일 또는 독립적으로 할로겐, 메틸 및/또는 시아노로 임의로 치환된 1,4-페닐렌이고; Z1, Z2및 Z7은 독립적으로 -CH2-(CH2)S-, -(CH2)S-O-, -O(CH2)S-, -COO-, -OOC-, -(CH2)SCOO- 또는 -(CH2)SOOC-이고; Z3, Z4및 Z8은 독립적으로 단일결합, -CH2CH2-, -CH2O-, -OCH2-, -COO-, -OOC-, -(CH2)4-, -O(CH2)3- 또는 -(CH2)3O-이고; Z5및 Z6는 -(CY2)S-, -O(CY2)S-, -(CY2)SO-, -(CY2)SCOO-, -(CY2)SOOC-, -(Si〔(CH3)2〕O)s-, -OCH2(Si〔(CH3)2〕O)SSi〔(CH3)2〕CH2O- 또는 -NHCH2(Si〔(CH3)2〕O)SSi〔(CH3)2〕CH2NH-이고; Y는 수소 또는 불소이고; m, n, q 또는 r은 독립적으로 0, 1 또는 2이고; S은 1 내지 16의 정수이고; R1및 R2는 CH2=CH-, CH2=CH-COO-, CH2=C(CH3)-COO-, CH2=C(Cl)-COO-, CH2=C(Ph)-COO-, CH2=CH-COO-Ph-, CH2=CH-CO-NH-, CH2=C(CH3)-CONH-, CH2=C(Cl)-CONH-, CH2=C(Ph)-CONH-, CH2=C(COOR′)-CH2-COO-, CH2-CH-O-, CH2=CH-OOC-, Ph-CH=CH-, CH3-C(=NR´)-, 시스, 트란스 -HOO-CR´=CR´-COO-,또는 의 구조를 갖는 가교결합성 그룹이고; Ph는 페닐이고; R´은 저급 알킬이고; R˝은 메틸, 메톡시, 시아노 또는 할로겐이나, 단 R1-Z5및 R2-Z6는 -O-O- 또는 -N-O- 그룹을 함유하지 않고; R3는 수소, 할로겐, 시아노 또는 알킬, 알콕시, 알콕시카보닐이거나. 또는 메톡시, 시아노 및/또는 할로겐으로 임의로 치환된 알카노일옥시 그룹이고; X1, X2및 X3는 독립적으로 수소, 할로겐, 시아노 또는 저급 알킬이나; 단 m이 2이고/이거나, n이 2일때 두개의 고리 B 및 D는 동일하거나 상이할 수 있다.

Description

광-가교결합성 액정 1,2-페닐렌 유도체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 하기 일반식(1)의 화합물:
    상기 식에서, 고리 A 내지 F는 각각 피리딘-2,5-디일, 피리미딘-2,5-디일, 트란스-1,4-사이클로헥실렌, 트랜스-1,3-디옥산-2,5-디일 또는 독립적으로 할로겐, 메틸 및/또는 시아노로 임의로 치환된 1,4-페닐렌이고; Z1, Z2및 Z7은 독립적으로 -CH2-(CH2)S-, -(CH2)SO-, -O(CH2)S-, -COO-, -OOC-, -(CH2)SCOO- 또는 -(CH2)3OOC-이고; Z3, Z4및 Z8은 독립적으로 단일결합, -CH2CH2-, -CH2O-, -OCH2-, -COO-, -OOC-, -(CH2)4-, -O(CH2)3- 또는 -(CH2)3O-이고; Z5및 Z6는 -(CY2)S-, -O(CY2)S-, -(CY|2)SO-, -(CY2)SCOO-, -(CY2)SOOC-, -(Si〔(CH3)2〕O)|S-, -OCH2(Si〔(CH3)2〕O)SSi〔(CH3)2〕CH|2O- 또는 -NHCH2(Si〔(CH3)2〕O)SSi〔(CH3)2〕CH|2NH-이고; Y는 수소 또는 불소이고; m, n, q 또는 r은 독립적으로 0, 1 또는 2이고; s은 1내지 16의 정수이고; R1및 R2는 CH2=CH-, CH2=CH-COO-, CH2=C(CH3)-COO-, CH2=C(Cl)-COO-, CH2=C(Ph)-COO-, CH2=CH-COO-Ph-, CH2=CH-CO-NH-, CH2=C(CH3)-CONH-, CH2=C(Cl)-CONH-, CH2=C(Ph)-CONH-, CH2=C(COOR′)-CH2-COO-, CH2-CH-O-, CH2=CH-OOC-, Ph-CH=CH-, CH3-C(=NR´)-, 시스, 트랜스 HOO-CR´=CR´-COO-,또는의 구조를 갖는 가교결합성 그룹이고; Ph는 페닐이고; R´은 저급 알킬이고; R˝은 메틸, 메톡시, 시아노 또는 할로겐이나, 단 R1-Z5및 R2-Z6는 -O-O- 또는 -N-O- 그룹을 함유하지 않고; R3는 수소, 할로겐, 시아노 또는 알킬, 알콕시, 알콕시카보닐이거나. 또는 메톡시, 시아노 및/또는 할로겐으로 임의로 치환된 알카노일옥시 그룹이고; X1, X2및 X3는 독립적으로 수소, 할로겐, 시아노 또는 저급 알킬이나; 단 m이 2이고/이거나, n이 2일때 두개의 고리 B 및 D는 동일하거나 상이할 수 있다.
  2. 제1항에 있어서 상기 일반식(1)에서, 고리 A 내지 F는 각각 피리딘-2,5-디일, 피리미딘-2,5-디일, 트랜스-1,4-사이클로헥실렌, 트란스-1,3-디옥산-2,5-디일 또는 독립적으로 할로겐, 메틸 및/또는 시아노로 임의로 치환된 1,4-페닐렌이고; Z1, Z2및 Z7은 독립적으로 -CH2-CH2-, -CH2-O-, -COO-, -OOC-, -(CH2)4-, 또는 -(CH2)3O-이고; Z3, Z4및 Z8은 독립적으로 단일결합, -CH2CH2-, -CH2O-, -OCH2-, -COO-, -OOC-, -(CH2)4-, -O(CH2)3- 또는 -(CH2)3O-이고; Z5및 Z6는 -(CY2)S-, -O(CY2)S-, -(CY2)SO-, -(CY2)SCOO-, -(CY2)SOOC-, -(Si〔(CH3)2〕O)S-, -OCH2(Si〔(CH3)2〕O)SSi〔(CH3)2〕CH|2O- 또는 -NHCH2(Si〔(CH3)2〕O)SSi〔(CH3)2〕CH|2NH-이고; Y는 수소 또는 불소이고; m, n, q 또는 r은 독립적으로 0 또는 1이고; s가 1 내지 16의 정수이고; R1및 R2는 CH2=CH-, CH2=CH-COO-, CH2=C(CH3)-COO-, CH2=C(Cl)-COO-, CH2=C(Ph)-COO-, CH2=CH-COO-Ph-, CH2=CH-CO-NH-, CH2=C(CH3)-CONH-, CH2=C(Cl)-CONH-, CH2=C(Ph)-CONH-, CH2=C(COOR′)-CH2-COO-, CH2-CH-O-, CH2=CH-OOC-, Ph-CH=CH-, CH3-C(=NR´)-, 시스, 트랜스 HOO-CR´=CR´-COO-,또는 의 구조를 갖는 가교결합성 그룹이고; Ph는 페닐이고; R´은 저급 알킬이고; R˝은 메틸, 메톡시, 시아노 또는 할로겐이나, 단 R1-Z5및 R2-Z6는 -O-O- 또는 -N-O- 그룹을 함유하지 않고; R3는 수소, 할로겐, 시아노 또는 알킬, 알콕시, 알콕시이거나, 또는 메톡시, 시아노 및/또는 할로겐으로 임의로 치환된 알카노일옥시 그룹이고; X1, X2및 X3는 독립적으로 수소, 할로겐, 시아노 또는 저급 알킬인 화합물.
  3. 제1항 또는 제2항에 있어서, 상기 가교결합성 잔기 R1및 R2가 서로 독립적으로 CH2=CH-COO-, CH2=C(CH3)-COO-, CH2=CH-O- 또는인 화합물.
  4. 제1항 내지 제3항 중 어느 한 항에 있어서, X1, X2및 X3가 수소, 불소, 염소, 시아노 및 메틸인 화합물.
  5. 제1항 내지 제4항 중 어느 한 항에 있어서, 하기 화학식 1-A인 화합물:
    상기 식에서, A1, B1및 E1은 독립적으로 불소, 피리딘-2,5-디일 또는 트랜스-1,4-사이클로헥실렌으로 임의로 치환된 1,4-페닐렌이고; Z11은 -CH2CH2-, -CH2O-, -COO-, -OOC-, -(CH2)4- 또는 -(CH2)3O-이고; Z31는 단일결합, -CH2O-, -COO- 또는 -OOC-이고; Z51은 -(CH2)S-, -(CH2)SO-, -(CH|2)sCOO- 또는 -(CH2)sOOC-이고; Z71은 -CH2O- 또는 -COO-이고; S′는 3 내지 12의 정수이고; R11은 CH2=CH-COO-, CH2=C(CH3)-COO-, CH2=CH-O- 또는이 R31은 할로겐, 시아노, 저급 알킬 또는 알콕시카보닐이고; q는 0 또는 1이고; X1, X2및 X3는 제1항에서 정의된 바와 같다.
  6. 제5항에 있어서, 하기 화학식 1-a 내지 화학식 1-c인 화합물;
    상기 식에서, R32는 시아노 또는 알콕시카보닐이고; X1, X2및 X3가 수소이고; S′는 제5항에서 정의한 바와 같다.
  7. 제1항 내지 제4항 중 어느 한 항에 있어서, 하기 일반식 1-B의 화합물:
    상기 식에서, A2, B2, B3및 E2은 독립적으로 불소, 트랜스-1,4-사이클로헥실렌으로 임의로 치환된 1,4-페닐렌이고; Z12는 -(CH2)2COO-, 또는 -(CH2)SCOO- 또는 -(CH2)sO이고; Z52는 -(CH2)s-, -(CH2)|sO-, -(CH2)sCOO- 또는 -(CH2)sOOC-이고; Z72은 -CH2O- 또는 -COO-이고; S′는 3 내지 12의 정수이고; R12은 CH2=CH-COO-, CH2=C(CH3)-COO-, CH2=CH-O- 또는이고, R33은 할로겐, 시아노 또는 알콕시카보닐이고; q는 0 또는 1이고; X1, X2및 X3는 제1항에서 정의된 바와 같다.
  8. 제7항에 있어서, 하기 화학식 1-d 내지 화학식 1-g의 화합물;
    상기 식에서, R34는 시아노 또는 알콜시카보닐이고; X1, X2및 X3는 수소이고; s′는 제7항에서 정의된 바와 같다.
  9. 하나 이상의 성분이 제1항에서 정의한 화학식(1)의 화합물인, 2개 이상의 성분을 포함하는 가교결합성 액정 혼합물.
  10. 제9항에 있어서, 하나 이상의 화학식(1)의 화합물뿐아니라 하기 화학식(2) 내지 화학식(9)의 화합물 중의 하나 이상의 화합물을 포함하는 가교결합성 액정 혼합물:
    상기 식에서, X는 수소, 불소, 염소, 브롬 또는 메틸이고; s′은 3 내지 12의 정수이고; t는 2 내지 12의 정수이고 Z는 -OCH2- 또는 -OOC-이고; A는 1,4-페닐렌 또는 2- 또는 3-플루오로-1,4-페닐렌이고; S는 -(CH2)s- 또는 -(CH2)|sO-이고; R은 CH2=CH-COO-, CH2=C(CH3)-COO-, CH2=CH-O- 또는이다.
  11. 가교결합된 상태의 제1항 내지 제8항 중 임의의 한 항에 따른 화합물의 광학 성분을 위한 용도.
  12. 가교결합된 상태의 제9항 내지 제10항에 따른 가교결합성 액정 혼합물의 화학성분을 위한 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960030809A 1995-07-28 1996-07-27 광-가교결합성액정1,2-페닐렌유도체 KR100391862B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CH222195 1995-07-28
CH2221/95 1995-07-28
CH95-2221 1995-07-28
EP96107341.8 1996-05-09
EP96107341 1996-05-09

Publications (2)

Publication Number Publication Date
KR970007493A true KR970007493A (ko) 1997-02-21
KR100391862B1 KR100391862B1 (ko) 2004-06-18

Family

ID=25689833

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019960030809A KR100391862B1 (ko) 1995-07-28 1996-07-27 광-가교결합성액정1,2-페닐렌유도체

Country Status (8)

Country Link
US (1) US5800733A (ko)
EP (1) EP0755918B1 (ko)
JP (1) JP4023852B2 (ko)
KR (1) KR100391862B1 (ko)
CN (1) CN1065265C (ko)
DE (1) DE59605843D1 (ko)
HK (1) HK1011014A1 (ko)
SG (1) SG64395A1 (ko)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002521354A (ja) 1998-07-24 2002-07-16 ロリク アーゲー 架橋性液晶化合物
GB9817272D0 (en) * 1998-08-07 1998-10-07 Rolic Ag Liquid crystalline compounds
GB9908934D0 (en) * 1999-04-19 1999-06-16 Rolic Ag Liquid crystalline compounds
EP1070731A1 (en) * 1999-07-23 2001-01-24 Rolic AG Compound
JP3985399B2 (ja) * 1999-09-10 2007-10-03 株式会社日立製作所 液晶表示装置
CN1230411C (zh) * 2000-01-21 2005-12-07 大日本油墨化学工业株式会社 显示液晶相的聚合性组合物及使用其的光学各向异性体
DE10016524A1 (de) * 2000-04-03 2001-10-04 Basf Ag Polymerisierbare Flüssigkristalle
JP5295471B2 (ja) 2000-11-13 2013-09-18 Ｄｉｃ株式会社 重合性液晶化合物、該化合物を含有する重合性液晶組成物及びその重合体
JP4810750B2 (ja) * 2001-04-11 2011-11-09 Ｄｉｃ株式会社 重合性液晶化合物、該化合物を含有する重合性液晶組成物及びその重合体
JP4721721B2 (ja) * 2004-02-18 2011-07-13 株式会社Ａｄｅｋａ 重合性化合物及び該化合物を含有する重合性液晶組成物
ATE509006T1 (de) 2004-11-04 2011-05-15 Adeka Corp Polymerisierbare verbindung und zusammensetzung, die die polymerisierbare verbindung enthält
JP5209181B2 (ja) * 2005-03-15 2013-06-12 富士フイルム株式会社 化合物、組成物、位相差板、楕円偏光板および液晶表示装置
JP4720634B2 (ja) * 2006-06-13 2011-07-13 ソニー株式会社 重合性液晶組成物、光学素子、光学素子の製造方法、および液晶表示装置
JO3598B1 (ar) * 2006-10-10 2020-07-05 Infinity Discovery Inc الاحماض والاسترات البورونية كمثبطات اميد هيدروليز الحامض الدهني
TW200946649A (en) * 2007-12-19 2009-11-16 Zeon Corp Polymerizable liquid crystal compound, polymerizable liquid crystal composition, liquid crystalline polymer, and optical isomer
EP2222815B1 (en) 2007-12-21 2019-05-29 ROLIC Technologies AG Photoalignment composition
TW201000107A (en) * 2008-04-09 2010-01-01 Infinity Pharmaceuticals Inc Inhibitors of fatty acid amide hydrolase
US8173045B2 (en) 2008-05-28 2012-05-08 University Of Washington Diels-Alder crosslinkable dendritic nonlinear optic chromophores and polymer composites
US7910020B2 (en) * 2008-06-27 2011-03-22 Transitions Optical, Inc. Liquid crystal compositions comprising mesogen containing compounds
US8628685B2 (en) * 2008-06-27 2014-01-14 Transitions Optical, Inc Mesogen-containing compounds
US8431039B2 (en) 2008-06-27 2013-04-30 Transitions Optical, Inc. Mesogenic stabilizers
US8623238B2 (en) 2008-06-27 2014-01-07 Transitions Optical, Inc. Mesogenic stabilizers
US7910019B2 (en) * 2008-06-27 2011-03-22 Transitions Optical, Inc. Mesogen containing compounds
US8613868B2 (en) 2008-06-27 2013-12-24 Transitions Optical, Inc Mesogenic stabilizers
US8349210B2 (en) 2008-06-27 2013-01-08 Transitions Optical, Inc. Mesogenic stabilizers
DE102009026819A1 (de) * 2008-09-08 2010-03-11 Evonik Röhm Gmbh Monomermischung, Polymer, Beschichtungsmittel und Verfahren zur Herstellung einer Beschichtung
ES2493916T3 (es) 2009-04-07 2014-09-12 Infinity Pharmaceuticals, Inc. Inhibidores de hidrolasa de amida de ácidos grasos
US8541581B2 (en) 2009-04-07 2013-09-24 Infinity Pharmaceuticals, Inc. Inhibitors of fatty acid amide hydrolase
BR112012019120A2 (pt) * 2010-02-03 2016-06-28 Infinity Pharmaceuticais Inc forma sólida, composição farmacêutica, método de preparação do composto 1, método de tratamento de uma condição mediada por faah
JP5747942B2 (ja) * 2013-05-09 2015-07-15 Dic株式会社 重合性液晶化合物、該化合物を含有する重合性液晶組成物及びその重合体
WO2015133872A1 (ko) * 2014-03-07 2015-09-11 금오공과대학교 산학협력단 비대칭성 이관능기를 갖는 굽은핵 반응성 메소젠 및 이의 제조방법
ES2893100T3 (es) 2015-10-12 2022-02-08 Advanced Cell Diagnostics Inc Detección in situ de variantes de nucleótidos en muestras con un elevado nivel de ruido, y composiciones y métodos relacionados con ésta
JP7472606B2 (ja) * 2020-04-01 2024-04-23 Dic株式会社 液晶組成物及び液晶表示素子
CN111718724B (zh) * 2020-05-27 2022-04-05 国科广化(南雄)新材料研究院有限公司 一种反应型偶氮苯主侧链液晶化合物及其制备方法与应用

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL8802832A (nl) * 1988-02-29 1989-09-18 Philips Nv Methode voor het vervaardigen van een gelaagd element en het aldus verkregen element.
DE4226994A1 (de) * 1992-08-14 1994-02-17 Siemens Ag Anisotrope Polymere
DE59403063D1 (de) * 1993-02-17 1997-07-17 Hoffmann La Roche Optisches Bauelement
DE4342280A1 (de) * 1993-12-11 1995-06-14 Basf Ag Polymerisierbare chirale Verbindungen und deren Verwendung
DE4408170A1 (de) * 1994-03-11 1995-09-14 Basf Ag Neue polymerisierbare flüssigkristalline Verbindungen
US5593617A (en) * 1994-09-12 1997-01-14 Hoffmann-Laroche Inc. Photochemically polymerizable liquid crystals

Also Published As

Publication number Publication date
HK1011014A1 (en) 1999-07-02
US5800733A (en) 1998-09-01
CN1154368A (zh) 1997-07-16
CN1065265C (zh) 2001-05-02
DE59605843D1 (de) 2000-10-12
KR100391862B1 (ko) 2004-06-18
SG64395A1 (en) 1999-04-27
JPH0940585A (ja) 1997-02-10
EP0755918A3 (de) 1998-08-05
EP0755918A2 (de) 1997-01-29
EP0755918B1 (de) 2000-09-06
JP4023852B2 (ja) 2007-12-19

Similar Documents

Publication Publication Date Title
KR970007493A (ko) 광-가교결합성 액정 1,2-페닐렌 유도체
KR970007492A (ko) 광 가교결합성 광학 활성 화합물
KR950032067A (ko) 광-가교결합성 액정
LU92209I2 (fr) Clevidipine sous toutes les formes procurant une protection à partir du brevet de base
KR970007491A (ko) 광 가교결합성 액정 1,4-디옥산-2,3-디일 유도체
ES2171109A1 (es) Derivados de 4-fenil-piridina.
EP2287282A3 (en) Compositions containing fluorine substituted olefins
KR970001509A (ko) 광 가교 결합성 액정 염료
KR960007732A (ko) 광학 활성의 스멕틱 광-교차 결합가능한 액정
CA2252907A1 (en) Novel 2,3 disubstituted-4(3h)-quinazolinones
CA2402751A1 (en) Decahydro-isoquinolines
JP2002537280A5 (ko)
KR960034161A (ko) 광 가교결합성 나프탈렌 유도체
KR910021362A (ko) (4e-사이클로헥실-3-부테닐)아릴 유도체
KR950032578A (ko) 액정 조성물
EP1096000A3 (en) Liquid crystal composition
KR950003418A (ko) 사이클릭 탄화수소 유도체 및 이를 함유하는 액정 조성물
KR950701904A (ko) 치환된(아릴알콕시벤질)아미노프로판아미드 유도체, 이의 제조방법 및 항간질제, 신경보호제 및 항우울증제로서의 이의 용도[Substituted(arylalkoxybenzyl) aminopropanamide derivatives, their preparation and use as anti-epileptic neuroprotective and antidepressant agents]
EP0902018A3 (en) 2-(Arylphenyl)amino-imidazoline derivatives
KR940011413A (ko) 플루오르 치환된 톨란 유도체
KR910015559A (ko) 키랄 디옥솔란
WO1993004160A1 (en) Solvent composition comprising mixture of polyfluoroalkane and lower alcohol
IE45556L (en) 2-[n-(cycloalkylmethyl)-n-(phenyl)-amino]-2- imidazoline¹derivatives
CA2282840A1 (en) S-2'-(2-(1-methyl-2-piperidyl) ethyl) cinnamanilide as a 5-ht2 receptor antagonist
KR960001088A (ko) 액정 조성물 및 액정 표시 장치

Legal Events

Date Code Title Description
A201 Request for examination
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20070619

Year of fee payment: 5

LAPS Lapse due to unpaid annual fee