KR910021362A - (4e-사이클로헥실-3-부테닐)아릴 유도체 - Google Patents

(4e-사이클로헥실-3-부테닐)아릴 유도체 Download PDF

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KR910021362A
KR910021362A KR1019910001666A KR910001666A KR910021362A KR 910021362 A KR910021362 A KR 910021362A KR 1019910001666 A KR1019910001666 A KR 1019910001666A KR 910001666 A KR910001666 A KR 910001666A KR 910021362 A KR910021362 A KR 910021362A
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halogen
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켈리 스티븐
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쟝-자크 오게이,롤란드 보러
에프. 호프만-라 롯슈 아크티엔게젤샤프트
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Abstract

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Description

(4E-사이클로헥실-3-부테닐)아릴 유도체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. 하기 일반식(Ⅰ)의 화합물 ;
    상기식에서, n은 0또는 1을 나타내고 ; R1은 R3또는 R3-A3-Z2-그룹을 나타내고 ; R2는 R4또는 -R4-A4-Z3-그룹을 나타내고 ; A1고리는 치환되지 않거나 또는 할로겐-, 시아노-및/또는 메틸 치환된1, 4-페닐렌(여기에서, CH 그룹 1개 또는 2개는 임의로 질소에 의해 치환된다)이고 ; A2, A3및 A4고리는 각각 서로 무관하게 치환되지 않거나 또는 할로겐-, 시아노-및/또는 메틸 치환된1, 4-페닐렌(여기에서 CH그룹 1개 또는 2개는 임의로 질소에 의해 치환된다), 또는 트랜스-1, 4-사이클로헥실렌, 트랜스-1, 3-디옥산-2, 5-디일, 1-시아노-트랜스-1, 4-사이클로헥실렌, 비사이클로〔2,2,2〕옥탄-1, 4-디일, 나프탈렌-2, 6-디일, 테트랄린-2, 6-디일 또는 트랜스-데칼린-2, 6-디일을 나타내고 ; Z1, Z2및 Z3는 각각 서로 무관하게 단일 공유결합, -COO-, -OOC-, -CH2O-, -OCH2-, -CH2CH2-, -C＝C-, - (CH2)3O-, -O(CH2)3-, -(CH2)4-, 또는 -CH＝CH-CH2-CH2-, -CH2CH2-CH＝CH-, CH＝CH-CH2O-, 또는 -OCH2-CH＝CH의 트랜스형을 나타내고 R3및 R4는 각각 서로무관하게 할로겐, 시아노, -NCS-, -CF3, -OCF3또는 알킬(여기에서, 1개의 )CH-CH〈는 임의로〉C＝C〈에 의해 치환되고 /되거나 1개의 메틸렌 그룹 또는 2개의 인접하지 않은 메틸렌그룹은 임의로 -O-, -COO-및/또는 -OOC-에 의해 치환되고 /되거나 1개의 메틸렌 그룹은 임의로-CHX-에 의해 치환된다〉을 나타내고; X는 할로겐, 시아노 또는 메틸을 나타낸다.
  2. 제1항에 있어서, 하기 일반식(Ⅰ-1)을 갖는 화합물.
    상기식에서 n, R1, R2, Z1및 A2고리는 제1항에서 정의한의미를 가지며 ; X1및 X2는 각각 독립적으로 수소, 할로겐, 시아노, 또는 메틸을 나타낸다.
  3. 제1항 또는 제2항에 있어서, A3및 A4가 각각 독립적으로 트랜스-1,4-사이클로헥실렌 또는 치환되지 않거나 할로겐-, 시아노-및/또는 치환된1,4-페닐렌을 나타내는 화합물.
  4. 제1항 내지 제3항중 어느 한항에 있어서, Ａ2고리가 치환되지 않은 , 1,4-페닐렌을 나타내거나또는 할로겐, 시아노 및/또는 메틸로일 치환되는 2, 3-이치환된1,4-페닐렌, 트랜스-1, 4-사이클로헥실렌, 트랜스-1, 3-디옥산-2, 5-디일, 1-시아노, 트랜스-1, 4-사이클로헥실렌, 비사이클로［2, 2, 2］옥탄-1, 4-디일, 나프탈렌-2, 6-디일, 테트랄린-2, 6-디일, 트랜스-데칼린-2, 6-디일, 피리딘-2, 5-디일, 피라미딘-2, 5-디일 또는 파라진-2,5-디일을 나타내는 화합물.
  5. 제1항에 내지 제4항중 어느 한항에 있어서, Ｚ1, Ｚ2및 Ｚ3가 각각 단일공유결합을 나타내거나 또는 Ｚ1, Ｚ2, 및 Ｚ3그룹 중하나가 또한 -COO-, -OOC-, -CH2O-, -OCH2-, -CH2CH2-, -C＝C-, -(CH2)3O-, -O(CH2)3-, -(CH2)4- 또는 -CH＝CH-CH2-CH2-, CH2CH2-CH＝CH, CH＝CH-CH2O 또는 -OCH2-CH＝CH-의 트랜스형태를 나타내는 화합물.
  6. 제1항 내지 제5항중 어느 한 항에 있어서, 하기 일반식(Ⅰ-7), (Ⅰ-8), (Ⅰ-9), (Ⅰ-10), (Ⅰ-11) 및 (Ⅰ-12)을 갖는 화합물.
    상기 식에서 R3및 R4는 제1항에 나타낸 의미를 갖고 ; X1, X2, X3및 X4는 각각독립적으로 수소, 할로겐, 시아노 또는 메틸을 나타내고 ; Z4는 단일공유결합, -COO-, -OOC-, -C＝C-, 를나타내고 ; Z5는 단일공유결합, -OOC-, -OCH2-, -CH2CH2-, -C＝C-, -O(CH2)3-, -(CH2)4-, 또는 -CH2CH2-CH＝CH- 또는 -OCH2-CH＝CH-의 트랜스형을 나타내고 ; A5고리는 피리딘-2, 5-디일, 피리미딘-2, 5-디일, 파라진-2, 5-디일 , 트랜스-1, 3-디옥산-2, 5-디일, 비사이클로［2, 2, 2］옥탄-1,4-디일, 나프탈렌-2, 6-디일, 테트랄린-2,6-디일 또는 트랜스-데칼린-2,6-디일을 나타낸다.
  7. 제2항 또는 제6항에 있어서, X1, X2, X3및 X4가 각각 독립적으로 수소 또는 불소를 나타내는 화합물.
  8. 제1항 내지 제7항중 어느 한항에 있어서, R3및 R4가 각각 독립적으로 하나의〉CH-CH〈가 임의로〉C＝C〈로 치환되고 /되거나 하나의 메틸렌 그룹 또는 2개의 비인접 메틸렌그룹이 임의로-O-, -COO- 및/또는 -OOC- 에 의해 치환되고/되거나 하나의 메틸렌그룹이 임의로 -CHX-로 치환된 알킬을 나타내거나 또는 R4가 또한 할로겐, 시아노, -NCS-, CF3또는 -OCF3를 나타내는 화합물.
  9. 제1항 내지 제8항중 어느 한항에 있어서, R3및 R4가 각각 탄소수 최고 18개, 바람직하게는 최고 12개를 갖는 화합물.
  10. 제1항 내지 제9항중 어느 한항에 있어서, R3가 알길, 알케닐, 알콕시, 알케닐옥시, 알콕시카보닐, 알케닐옥시카보닐, 알카노일옥시 또는 알케노일옥시, 바람직하게는 알킬 또는 알케닐을 나타내는 화합물.
  11. 제1항 내지 제10항중 어느 한항에 있어서, R4가 알킬, 알케닐, 알콕시, 알케닐옥시, 알콕시카보닐, 알케닐옥시카보닐, 알카노일옥시, 아케노일옥시, 할로겐, 시아노,-NCS-, -CF3또는 -OCF3를 나타내는 화합물.
  12. 적어도 하나의 성분이 제1항에 정의된 일반식(Ⅰ)의 화합물인, 적어도 2개의 성분을 갖는 액정 혼합물.
  13. 전광 목적에 사용하기 위한 제1항에 정의된 일반식(Ⅰ) 화합물용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
KR1019910001666A 1990-02-01 1991-01-31 (4e-사이클로헥실-3-부테닐)아릴 유도체 KR910021362A (ko)

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EP0727406B1 (de) * 1995-02-16 2001-09-05 MERCK PATENT GmbH Vinylenverbindungen und flüssigkristallines Medium
EP0834490A4 (en) * 1995-06-15 2001-09-26 Chisso Corp CONNECTIONS WITH AN ALKYL-SUBSTITUTED ALKENYLENE UNIT AND LIQUID CRYSTAL PREPARATIONS.
EP0885875A4 (en) * 1996-02-23 1999-10-13 Chisso Corp VINYLENE CONNECTIONS AND LIQUID CRYSTAL PREPARATIONS
KR20020054611A (ko) * 2000-12-28 2002-07-08 구본준, 론 위라하디락사 액정 표시 장치
JP2004256791A (ja) * 2003-02-03 2004-09-16 Chisso Corp 液晶組成物および液晶表示素子
JP5680381B2 (ja) * 2010-11-19 2015-03-04 Ａｇｃセイミケミカル株式会社 液晶化合物、その製造方法、液晶組成物および液晶電気光学素子
JP5680380B2 (ja) * 2010-11-19 2015-03-04 Ａｇｃセイミケミカル株式会社 液晶化合物、その製造方法、液晶組成物および液晶電気光学素子
JP5849664B2 (ja) 2011-01-31 2016-02-03 Jnc株式会社 液晶性化合物、液晶組成物および液晶表示素子
WO2015184624A1 (en) * 2014-06-05 2015-12-10 East China University Of Science And Technology Photo-tunable liquid crystal compositions and methods for their fabrication and use
JP6467807B2 (ja) * 2014-08-08 2019-02-13 Jnc株式会社 ブテン結合基を有する液晶性化合物、液晶組成物および液晶表示素子
JP6690114B2 (ja) * 2014-09-25 2020-04-28 Jnc株式会社 液晶組成物および液晶表示素子
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US10980777B2 (en) 2017-08-18 2021-04-20 Istituto Europeo Di Oncologia S.R.L. Indole derivatives as histone demethylase inhibitors
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DE59105136D1 (de) 1995-05-18
JPH04330019A (ja) 1992-11-18
EP0442306B1 (de) 1995-04-12
EP0442306A2 (de) 1991-08-21
EP0442306A3 (en) 1992-08-19

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