KR900016077A - 트랜스-3-사이클로헥실알릴옥시 그룹을 함유한 액정 성분 - Google Patents
트랜스-3-사이클로헥실알릴옥시 그룹을 함유한 액정 성분 Download PDFInfo
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- KR900016077A KR900016077A KR1019900005510A KR900005510A KR900016077A KR 900016077 A KR900016077 A KR 900016077A KR 1019900005510 A KR1019900005510 A KR 1019900005510A KR 900005510 A KR900005510 A KR 900005510A KR 900016077 A KR900016077 A KR 900016077A
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- 239000004973 liquid crystal related substance Substances 0.000 title claims 2
- 150000001875 compounds Chemical class 0.000 claims 21
- -1 methyl-substituted 1,4-phenylene Chemical group 0.000 claims 11
- 125000004093 cyano group Chemical group *C#N 0.000 claims 8
- 229910052736 halogen Inorganic materials 0.000 claims 8
- 150000002367 halogens Chemical class 0.000 claims 8
- 125000000217 alkyl group Chemical group 0.000 claims 7
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims 7
- 125000003342 alkenyl group Chemical group 0.000 claims 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 4
- 125000005407 trans-1,4-cyclohexylene group Chemical group [H]C1([H])C([H])([H])[C@]([H])([*:2])C([H])([H])C([H])([H])[C@@]1([H])[*:1] 0.000 claims 4
- ZVQOOHYFBIDMTQ-UHFFFAOYSA-N [methyl(oxido){1-[6-(trifluoromethyl)pyridin-3-yl]ethyl}-lambda(6)-sulfanylidene]cyanamide Chemical compound N#CN=S(C)(=O)C(C)C1=CC=C(C(F)(F)F)N=C1 ZVQOOHYFBIDMTQ-UHFFFAOYSA-N 0.000 claims 3
- 125000003302 alkenyloxy group Chemical group 0.000 claims 3
- 125000003545 alkoxy group Chemical group 0.000 claims 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 2
- 125000004423 acyloxy group Chemical group 0.000 claims 2
- 125000005092 alkenyloxycarbonyl group Chemical group 0.000 claims 2
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 150000002431 hydrogen Chemical class 0.000 claims 2
- 229910052757 nitrogen Inorganic materials 0.000 claims 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 239000001301 oxygen Substances 0.000 claims 2
- 229910052717 sulfur Inorganic materials 0.000 claims 2
- 239000011593 sulfur Substances 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 230000007547 defect Effects 0.000 claims 1
- 230000001747 exhibiting effect Effects 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 125000005757 tetralin-2,6-ylene group Chemical group [H]C1=C([*:2])C([H])=C2C(=C1[H])C([H])([H])C([H])([*:1])C([H])([H])C2([H])[H] 0.000 claims 1
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/14—Unsaturated ethers
- C07C43/164—Unsaturated ethers containing six-membered aromatic rings
- C07C43/168—Unsaturated ethers containing six-membered aromatic rings containing six-membered aromatic rings and other rings
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- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
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- C07D213/64—One oxygen atom attached in position 2 or 6
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- C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
- C07C255/54—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and etherified hydroxy groups bound to the carbon skeleton
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
- C07C255/55—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and esterified hydroxy groups bound to the carbon skeleton
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- C07C43/18—Ethers having an ether-oxygen atom bound to a carbon atom of a ring other than a six-membered aromatic ring
- C07C43/188—Unsaturated ethers
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- C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
- C07C43/215—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring having unsaturation outside the six-membered aromatic rings
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- C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
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- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/26—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
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- C07D319/06—1,3-Dioxanes; Hydrogenated 1,3-dioxanes not condensed with other rings
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- C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
- C09K19/3001—Cyclohexane rings
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- Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
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Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (15)
- 하기 일반식(I)화합물 :상기식에서, R1은 R3또는 R3-A4-Z3-그룹을 나타내고: R2는 R4또는 -Z4-A5-R4그룹을 나타내고 : m 및 n은 각각 개별적으로 0 또는 1을 나타내고: A1,A2,A3,A4및A5는각각 서로 무관하게 치환되지 않거나 또는 할로겐-. 시아노- 및/또는 메틸-치환된 1,4-페닐렌(여기에서, CH그룹 1개 또는 2개는 임의로 질소에 의해 치환된다). 2개의 인접하지 않은 메틸렌 그룹이 임의로 산소 및/또는 황에 의해 치환된 트랜스-1, 4-사이클로헥실렌, 1-시아노-트랜스-1, 4-사이클로헥실렌, 비사이클로(2,2,2)옥탄-1. 4-디일, 나프탈렌-2. 6-디일, 테트랄린-2, 6-디일 또는 트랜스데칼린-2. 6-디일을 나타내고: Z1,Z2,Z3, 및 Z4는 각각 서로 무관하게 단일공유결합 -COO-, -OOC-, -CH2O-, -OCH2-, -CH2CH2-, -C=C-, -(CH2)3-.1-(CH2)3- 또는 -CH=CH-CH2O- 또는 -OCH2-CH=CH-의 트랜스형을 나타내고; R3및 R1는 각각 서로 무관하게 할로겐, 시아노, -NCS. -CH3, -OCH3또는 알킬(여기에서. 1개의 >CH-CH<는 임의로>C=C<에 의해 치환되고/ 되거나 1개의 메틸렌 그룹 또는 2개의 인접하지 않은 메틸렌 그룹은 임의로 -0-, -COO- 및 /또는 -OOC-에 의해 치환되고/되거나 1개의 메틸렌 그룹은 임의로 -CHX-에 의해 치환된다)을 나타내고: X는 할로겐, 시아노 또는 메틸을 나타낸다.
- 제1항에 있어서, A1이 치환되지 않거나 또는 할로겐-, 시아노- 및/또는 메틸-치환된 1,4-페닐렌 또는 트랜스-1,4-사이클로헥실렌을 나타내는 화합물.
- 제1항에 있어서, 상기 일반식(I-1)의 화합물 :상기식에서, X1및 X2는 각각 서로 무관하게 수소, 할로겐, 시아노 또는 메틸을 나타내고, A2, A3, R1, R2, Z1, Z2, m 및 n은 제1항에서 정의한 바와 같다.
- 제1항 내지 제3항중 어느 한 항에 있어서, A3가 트랜스-1,4-사이클로헥실렌을 나타내고, Z2가 단일 공유 결합 또는 -CH2CH2-를 나타내고, n이 0 또는 1을 나타내는 화합물.
- 제1항 내지 제4항중 어느 한 항에 있어서, Z1,Z2,Z3및 Z4그룹중 각각 단일 공유 결함을 나타내거나, 또는 Z1,Z2,Z3및 Z4그룹중 하나가 또한 -COO-, -OOC-, -CH2O-, -OCH2-, -CH2CH2-, -C≡C-, -(CH2)3O-, -O(CH2)3-, 또는 -CH=CH-CH2O- 또는 -OCH2-CH=CH-의 트랜스형을 나타내는 화합물.
- 제1항에 있어서, 하기 일반식(I -3)의 화합물 :상기 식에서, Z5및 Z6는 각각 서로 무관하게 단일 공유결합 또는 -CH2CH2-를 나타태고, R1, R2, m 및 n은 제1항에서 정의한 바와같다.
- 제1항 내지 제6항중 어느 한 항에 있어서, R1이 R3그룹을 나타내고, R2이 R4그룹을 나타내고, m 및 n이 0을 나타내거나, 또는 m이 1을 나타내고 n이 0을 나타내거나, 또는 m이 0을 나타내고 n이 1을 나타내는 화합물.
- 제1항에 있어서, 하기 일반식(Ⅰ-4), (Ⅰ-5), (Ⅰ-6), (Ⅰ-7), (Ⅰ-8) 및 (Ⅰ-9)의 화합물 :상기 식에서, n은 0또는 1을 나타내며; X1, X2, X3및 X4는 각각 서로 무관하게 수소, 할로겐, 시아노 또는 메틸을 나타내며: A6은 1,4-페닐렌, 피리딘-2,5-디일, 피리미딘-2,5-디일, 피라진-2,5-디일, 트랜스-1,4-사이클로헥실렌. 트랜스-1,3-디옥산-2,5-디일 또는 트랜스-데칼린-2,5-디일을 나타내며: Z7은 단일 공유결합, -COO- 또는 -OOC-를 나타내며: Z8은 단일 공유결합, -OOC-, -OCH2-, -C≡C-, -O(CH2)3-, 또는 -OCH2-CH=CH-의 트랜스형을 나타내며: R3및 R4는 제1항에서 정의한 바와같다.
- 제1항 내지 제8항중 어느 한 항에 있어서, R3및 R4가 각각의 경우에 탄소수 리고 18개를 가지며, 잔기 R3및 R4중 최고 어느 하나가 할로겐, 시아노, -NCS, -CF3또는 -OCF3을 나타내는 화합물.
- 제1항 내지 제9항중 어느 한 항에 있어서, R3이 알킬, 알케닐, 알콕시, 알케닐옥시, 알콕시카보닐, 알케닐옥시카보닐, 알카노일옥시 또는 알케노일옥시, 바람직하게는 알킬 또는 알케닐을 나타내는 화합물.
- 제1항 내지 제10항중 어느 한 항에 있어서, R4가 알킬, 알케닐, 알콕시, 알케닐옥시, 알콕시카보닐, 알케닐옥시카보닐, 알카노일옥시, 알케노일옥시, 할로겐, 시아노, -NCS, -CF3또는 -OCF3바람직하게는 알킬, 알케닐, 알콕시, 알케닐옥시, 불소 염소 시아노 -NCS, -CF3또는 -OCF3을 나타내는 화합물.
- 최소한 하나의 성분이 제1항에서 정의한 일반식 (Ⅰ) 화합물인, 최소한 두개의 성분을 갖는 액정 혼합물.
- 전광 용도를 위한 제1항에서 정의한 일반식 (Ⅰ) 화합물의 용도.
- 하기 일반식 (Ⅴ)의 화합물 :상기식에서, R1은 R3또는 R3-A4-Z3- 그룹을 나타내고: n은 1을 나타내거나, 또는 R1이 R3-A4-Z3- 그룹을 나타낸다면 또한 0을 나타내고: A3및 A4는 각각 서로 무관하게 치환되지 않거나 또는 할로겐-, 시아노-및/또는 메틸-치환된 1,4-페닐렌(여기에서 CH 그룹 1개 또는 2개는 임의로 질소에 의해 치환된다). 2개의 인접하지 않은 메틸렌 그룹이 임의로 산소 및/또는 황에 의해 치환된 트랜스-1.4-사이클로헥실렌, 1-시아노-트랜스-1,4-사이코로헥실렌, 비사이클로[2,2,2]옥탄-1,4-디일, 나프탈렌-2,6-디일, 테트랄린-2.6-디일 또는 트랜스-데칼린-2.6-디일을 나타내고: Z2및 Z3은 각각 서로 무관하게 단인 공유결합, -COO-, -OOC-, -CH2O-, -OCH2-, -CH2CH2-, -C≡C-, -(CH2)3O-, -O(CH2)3-, 또는 -CH=CH-CH2O- 또는 -OCH2-CH=CH-의 트랜스형을 나타내고: R3은 할로겐. 시아노. -NCS. -CF3. -OCF3또는 알킬(여기에서, 1개의)CH-CH(는 임의로)C=C(에 의해 치환되며/되거나 메틸렌 그룹 1개 또는 2개의 인접하지 않은 메틸렌 그룹은 임의로 -0-, -COO- 및/또는 -OOC-에 의해 치환되며/되거나 1개의 메틸렌 그룹은 임의로 -CHX-에 의해 치환된다)을 나타내고: X는 할로겐, 시아노 또는 메틸을 나타내고: R5는 알킬을 나타낸다.
- 제14항에 있어서, 하기 일반식 (V-1)의 화합물 :상기 식에서, n은 0 또는 1을 나타내고: Z5및 Z6은 각각 서로 무관하게 단일 공유결합 또는 -CH2CH2-를 나타내고: R3및 R5는 제14항에서 정의한 바와 같다.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH154789 | 1989-04-20 | ||
| CH1547/89 | 1989-04-20 |
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| KR900016077A true KR900016077A (ko) | 1990-11-12 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019900005510A KR900016077A (ko) | 1989-04-20 | 1990-04-19 | 트랜스-3-사이클로헥실알릴옥시 그룹을 함유한 액정 성분 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5032312A (ko) |
| EP (1) | EP0393501B1 (ko) |
| JP (1) | JPH0327340A (ko) |
| KR (1) | KR900016077A (ko) |
| DE (1) | DE59001831D1 (ko) |
| HK (1) | HK54196A (ko) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5238600A (en) * | 1988-06-01 | 1993-08-24 | Hoffmann-La Roche Inc. | Ibimethylenoxy containing liquid crystal compounds |
| JP2750436B2 (ja) * | 1988-09-19 | 1998-05-13 | チッソ株式会社 | アルケニルエーテル化合物及びそれを含む液晶組成物 |
| DE4019595A1 (de) * | 1989-12-19 | 1991-06-27 | Merck Patent Gmbh | Fluorphenylpyridine |
| JP3134473B2 (ja) * | 1992-04-03 | 2001-02-13 | チッソ株式会社 | シス−１，４−置換２−ブテン誘導体 |
| JP2004256791A (ja) * | 2003-02-03 | 2004-09-16 | Chisso Corp | 液晶組成物および液晶表示素子 |
| CN114262615B (zh) * | 2021-12-27 | 2023-11-10 | 重庆汉朗精工科技有限公司 | 一种高介电常数液晶组合物及其应用 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5511671B2 (ko) * | 1971-08-26 | 1980-03-26 | ||
| GB1551043A (en) * | 1975-04-22 | 1979-08-22 | Secr Defence | Biphenyl compounds containing a cyano group and liquid crystal materials and devices containing such compounds |
| US4052423A (en) * | 1976-01-19 | 1977-10-04 | Iowa State University Research Foundation, Inc. | Synthesis of α,β-unsaturated carboxylic acids and esters |
| DE3225290A1 (de) * | 1982-07-07 | 1984-01-12 | Merck Patent Gmbh | Ringverbindungen |
| DE3509170C2 (de) * | 1985-03-14 | 1995-01-05 | Merck Patent Gmbh | trans-Ethenylenverbindungen |
| DE3601452A1 (de) * | 1986-01-20 | 1987-07-23 | Merck Patent Gmbh | Vinylen-verbindungen |
| US4891491A (en) * | 1987-01-30 | 1990-01-02 | Duley Walter W | Means of enhancing laser processing efficiency of metals |
-
1990
- 1990-03-02 US US07/487,096 patent/US5032312A/en not_active Expired - Fee Related
- 1990-04-11 DE DE9090106991T patent/DE59001831D1/de not_active Expired - Fee Related
- 1990-04-11 EP EP90106991A patent/EP0393501B1/de not_active Expired - Lifetime
- 1990-04-19 KR KR1019900005510A patent/KR900016077A/ko not_active Application Discontinuation
- 1990-04-20 JP JP2105126A patent/JPH0327340A/ja active Pending
-
1996
- 1996-03-28 HK HK54196A patent/HK54196A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| HK54196A (en) | 1996-04-03 |
| EP0393501A1 (de) | 1990-10-24 |
| DE59001831D1 (de) | 1993-07-29 |
| EP0393501B1 (de) | 1993-06-23 |
| JPH0327340A (ja) | 1991-02-05 |
| US5032312A (en) | 1991-07-16 |
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| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
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