KR860006446A - 피리미딘 유도체의 제조방법 - Google Patents
피리미딘 유도체의 제조방법 Download PDFInfo
- Publication number
- KR860006446A KR860006446A KR1019860001178A KR860001178A KR860006446A KR 860006446 A KR860006446 A KR 860006446A KR 1019860001178 A KR1019860001178 A KR 1019860001178A KR 860001178 A KR860001178 A KR 860001178A KR 860006446 A KR860006446 A KR 860006446A
- Authority
- KR
- South Korea
- Prior art keywords
- liquid crystal
- phenylene
- group
- compound
- general formula
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/26—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/34—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
- C09K19/3441—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having nitrogen as hetero atom
- C09K19/345—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having nitrogen as hetero atom the heterocyclic ring being a six-membered aromatic ring containing two nitrogen atoms
- C09K19/3458—Uncondensed pyrimidines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Liquid Crystal Substances (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (4)
- 다음 일반식(Ⅰ)의 화합물의 H 원자 대신에 하나 이상의 활원성 그룹 및/또는 추가로 C-C 결합을 함유하는 상응하는 화합물을 환원제로 처리하거나 또는 일반식(Ⅰ)의 에테르의 제조를 위해서는 상응하는 히드록시 화합물을 에테르화시키는 것을 특징으로 하는 일반식(Ⅰ)의 피리미딘 유도체의 제조방법.R1-Pyr-A1-Z1-A2[Z2-A3]m-R2(Ⅰ)상기 일반식에서R1및 R2는 각기 탄소수 1 내지 12의 알킬그룹이고, 여기에서 한개 또는 두개의 비-인접 CH2그룹은 -O-, -CO-,-O-CO-,-CO-O- 또는 -CH=CH-로 치환될 수도 있으며, R1및 R2기중 하나는 H,F,Cl,Br 또는 CN이고,Pyr은 피리미딘 -2,5- 디일이고, A1및 A3는 각기 트랜스 -1,4- 시클로헥실렌, 비치환 1,4- 페닐렌 또는 한개 또는 두개의 F 및/또는 Cl원자 및/또는 CH3및/또는 CN그룹으로 치환된 1,4-페닐렌이고,A2는 비치환 1,4- 페닐렌 또는 한개 또는 두개의 F 및 또는 Cl 원자 및/또는 CH3및/또는 CN그룹으로치환된 1,4- 페닐렌이고,Z1은 -CH2CH2-,-CH2O-, 또는 -OCH2- 이고, Z2는 -CO -O-, -O-CO-, -H2CH2-,-CH2O-,-O-CH2-또는 단일결합이고, m O 또는 1 이다.
- 제 1 항에 따른 일반식(Ⅰ)의 화합물 적어도 하나를 함유하는 것을 특징으로 하는, 적어도 두가지 액정성분으로 이루어진 액정상.
- 제 2 항에 따른 액정상을 함유하는 것을 특징으로 하는 액정표시소자.
- 제 3 항에 있어서, 제 2 항에 따른 액정상을 함유하는 것을 특징으로 하는 전기-광학적 표시소자.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3506446.3 | 1985-02-23 | ||
DE19853506446 DE3506446A1 (de) | 1985-02-23 | 1985-02-23 | Pyrimidinderivate |
Publications (1)
Publication Number | Publication Date |
---|---|
KR860006446A true KR860006446A (ko) | 1986-09-11 |
Family
ID=6263416
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019860001178A KR860006446A (ko) | 1985-02-23 | 1986-02-20 | 피리미딘 유도체의 제조방법 |
Country Status (6)
Country | Link |
---|---|
US (1) | US4776973A (ko) |
EP (1) | EP0199004B1 (ko) |
JP (1) | JPS61210074A (ko) |
KR (1) | KR860006446A (ko) |
DD (1) | DD243290A5 (ko) |
DE (2) | DE3506446A1 (ko) |
Families Citing this family (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3404116A1 (de) * | 1984-02-07 | 1985-08-08 | Merck Patent Gmbh, 6100 Darmstadt | Stickstoffhaltige heterocyclen |
DE3510432A1 (de) * | 1985-03-22 | 1986-09-25 | Merck Patent Gmbh, 6100 Darmstadt | Cyclohexanderivate |
US5279762A (en) * | 1985-04-27 | 1994-01-18 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Smectic liquid crystal phases |
DE3515373A1 (de) * | 1985-04-27 | 1986-11-06 | Merck Patent Gmbh, 6100 Darmstadt | Stickstoffhaltige heterocyclen |
DE3515374C2 (de) * | 1985-04-27 | 1998-02-26 | Hoechst Ag | Chirale getilte smektische flüssigkristalline Phasen und deren Verwendung in elektrooptischen Anzeigeelementen |
DE3515633A1 (de) * | 1985-05-02 | 1986-11-06 | Merck Patent Gmbh, 6100 Darmstadt | Benzonitrile |
DE3518734A1 (de) * | 1985-05-24 | 1986-11-27 | Merck Patent Gmbh, 6100 Darmstadt | Smektische fluessigkristalline phasen |
DE3533333A1 (de) * | 1985-09-18 | 1987-03-26 | Merck Patent Gmbh | Smektische fluessigkristalline phasen |
DE3650014D1 (de) * | 1985-09-18 | 1994-09-08 | Merck Patent Gmbh | Smektische flüssigkristalline phasen. |
DE3600052A1 (de) * | 1986-01-03 | 1987-07-09 | Merck Patent Gmbh | Heterocyclische verbindungen |
DE3606153A1 (de) * | 1986-02-26 | 1987-08-27 | Merck Patent Gmbh | Fluessigkristallanzeigeelement |
DE3787253D1 (de) * | 1986-11-20 | 1993-10-07 | Hoffmann La Roche | Ferroelektrische Flüssigkristalle. |
JPH0832673B2 (ja) * | 1987-03-20 | 1996-03-29 | チッソ株式会社 | オルト−シアノ−ベンゼン骨格を含む光学活性液晶化合物 |
DE3709549A1 (de) * | 1987-03-24 | 1988-10-06 | Hoechst Ag | Verwendung von 5-phenyl-pyrimidinderivaten als komponenten in smektischen fluessigkristallmischungen |
DE3709618A1 (de) * | 1987-03-24 | 1988-10-06 | Hoechst Ag | Neue fluessigkristalline 5-phenylpyrimidin-derivate mit s(pfeil abwaerts)c(pfeil abwaerts)-oder s(pfeil abwaerts)c(pfeil abwaerts) -phase und verfahren zu ihrer herstellung |
JP2660551B2 (ja) * | 1987-07-28 | 1997-10-08 | キヤノン株式会社 | 光学活性化合物及びそれを含む液晶組成物、液晶素子 |
DE3807862A1 (de) * | 1988-03-10 | 1989-09-21 | Merck Patent Gmbh | Smektische fluessigkristallphase |
DE3731639A1 (de) * | 1987-09-19 | 1989-03-30 | Hoechst Ag | Fluessigkristalline phenylpyrimidin-cyclohexancarbonsaeureester, verfahren zu ihrer herstellung und ihre verwendung in fluessigkristallmischungen |
US4913532A (en) * | 1987-10-19 | 1990-04-03 | Casio Computer Co., Ltd. | Liquid crystal composition and liquid crystal display device using the same |
DE3887084D1 (de) * | 1987-11-06 | 1994-02-24 | Hoffmann La Roche | Halogenierte Benzolderivate. |
JP2594583B2 (ja) * | 1987-11-10 | 1997-03-26 | シャープ株式会社 | 液晶表示装置 |
US4933955A (en) * | 1988-02-26 | 1990-06-12 | Silicon General, Inc. | Timing generator |
US4925590A (en) * | 1988-03-10 | 1990-05-15 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Derivatives of 4-cyano-2,3-difluorophenol |
DE3807863A1 (de) * | 1988-03-10 | 1989-09-21 | Merck Patent Gmbh | 2,3-difluorbenzolderivate |
DE3807871A1 (de) * | 1988-03-10 | 1989-09-21 | Merck Patent Gmbh | Heterocyclische derivate des 1,2-difluorbenzols |
US5273680A (en) * | 1988-03-10 | 1993-12-28 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Fluorinated oligophenyls and their use in liquid crystal materials |
DE3835803A1 (de) * | 1988-03-10 | 1990-04-26 | Merck Patent Gmbh | Supertwist-fluessigkristallanzeigeelement und fluessigkristallmischung |
US5211878A (en) * | 1988-03-10 | 1993-05-18 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Difluorobenzonitrile derivatives |
US5279764A (en) * | 1988-03-10 | 1994-01-18 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Dihalogenobenzene derivatives |
US5248447A (en) * | 1988-03-10 | 1993-09-28 | Merck Patent Gesellschaft Mit Beschrankter Haftung | 2,3-difluorohydroquinone derivatives |
DE3807861A1 (de) * | 1988-03-10 | 1989-09-21 | Merck Patent Gmbh | 2,3-difluorbiphenyle |
DE3807802A1 (de) * | 1988-03-10 | 1989-09-21 | Merck Patent Gmbh | Chirale derivate des 1,2-difluorbenzols |
JPH02503431A (ja) * | 1988-03-10 | 1990-10-18 | メルク・パテント・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング | 2,3‐ジフルオロ安息香酸誘導体 |
ES2040936T3 (es) * | 1988-07-13 | 1993-11-01 | Canon Kabushiki Kaisha | Composicion de cristal liquido ferroelectrico quiral esmetico y un dispositivo de cristal liquido que utiliza la composicion de cristal liquido. |
US5186858A (en) * | 1988-07-13 | 1993-02-16 | Canon Kabushiki Kaisha | Ferroelectric chiral smectic liquid crystal composition and liquid crystal device using same |
DE68912836T2 (de) * | 1988-07-13 | 1994-06-01 | Canon Kk | Ferroelektrische, chirale, smektische Flüssigkristallzusammensetzung und deren Verwendung in einer Flüssigkristallanordnung. |
DE68921260T2 (de) * | 1988-07-14 | 1995-07-06 | Canon Kk | Ferroelektrische, chirale, smektische Flüssigkristall-Zusammensetzung und Vorrichtung zu deren Anwendung. |
DE4002609A1 (de) * | 1989-09-07 | 1991-03-21 | Merck Patent Gmbh | Difluorbenzonitrile und fluessigkristallines medium |
JP2796753B2 (ja) * | 1990-05-09 | 1998-09-10 | キヤノン株式会社 | カイラルスメクチック液晶組成物およびそれを使用した液晶素子 |
US5128061A (en) * | 1990-08-14 | 1992-07-07 | Optical Shields, Inc. | Phenyl-pyrimidine liquid crystal materials |
JP2952141B2 (ja) * | 1993-01-08 | 1999-09-20 | キヤノン株式会社 | 液晶性化合物、それを含む液晶組成物、及びこれを用いた液晶素子 |
Family Cites Families (19)
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EP0025119B1 (de) * | 1979-08-20 | 1983-05-25 | VEB Werk Für Fernsehelektronik im VEB Kombinat Mikroelektronik | Nematische kristallin-flüssige 5-Alkyl-2-(4-acyloxyphenyl)-pyrimidine für optoelektronische Anordnungen und Verfahren zu ihrer Herstellung |
CH645664A5 (de) * | 1980-12-16 | 1984-10-15 | Merck Patent Gmbh | Fluessigkristallmischung. |
DE3163424D1 (en) * | 1981-01-19 | 1984-06-07 | Merck Patent Gmbh | Liquid crystal mixture |
DE3268611D1 (en) * | 1981-02-25 | 1986-03-06 | Hitachi Ltd | Colorless liquid crystalline compounds |
US4528114A (en) * | 1981-12-18 | 1985-07-09 | Hoffmann-La Roche Inc. | Acetylenes |
DE3270906D1 (en) * | 1982-01-14 | 1986-06-05 | Merck Patent Gmbh | Liquid crystal mixtures |
US4512636A (en) * | 1982-06-15 | 1985-04-23 | The Secretary Of State For Defence In Her Britannic Majesty's Government Of The United Kingdon Of Great Britian And Northern Ireland Of Whitehall | Liquid crystal compounds |
JPS5939876A (ja) * | 1982-08-26 | 1984-03-05 | Chisso Corp | ピリミジン誘導体 |
EP0122389B1 (de) * | 1983-03-16 | 1987-08-05 | F. HOFFMANN-LA ROCHE & CO. Aktiengesellschaft | Flüssigkristallkomponenten mit einer Alkenylseitenkette |
DE3332692A1 (de) * | 1983-09-10 | 1985-03-28 | Merck Patent Gmbh, 6100 Darmstadt | Anisotrope verbindungen und fluessigkristallmischungen |
US4623477A (en) * | 1983-10-07 | 1986-11-18 | Chisso Corporation | Ester compounds having a pyrimidine ring |
GB8400665D0 (en) * | 1984-01-11 | 1984-02-15 | Secr Defence | Disubstituted ethanes |
DE3401321A1 (de) * | 1984-01-17 | 1985-07-25 | Merck Patent Gmbh, 6100 Darmstadt | Stickstoffhaltige heterocyclen |
DE3401320A1 (de) * | 1984-01-17 | 1985-07-25 | Merck Patent Gmbh, 6100 Darmstadt | Ethanderivate |
DE3404116A1 (de) * | 1984-02-07 | 1985-08-08 | Merck Patent Gmbh, 6100 Darmstadt | Stickstoffhaltige heterocyclen |
DE3411571A1 (de) * | 1984-03-29 | 1985-10-10 | Merck Patent Gmbh, 6100 Darmstadt | Pyrimidine |
GB8415039D0 (en) * | 1984-06-13 | 1984-07-18 | Secr Defence | Pyrimidines |
DE3575158D1 (de) * | 1984-07-12 | 1990-02-08 | Hoffmann La Roche | Fluessigkristalline gemische enthaltend komponenten mit einer 4-alkenyl- oder 2z-alkenyl-seitenkette. |
DE3500909A1 (de) * | 1985-01-12 | 1986-07-17 | Merck Patent Gmbh, 6100 Darmstadt | Pyrimidine |
-
1985
- 1985-02-23 DE DE19853506446 patent/DE3506446A1/de not_active Withdrawn
-
1986
- 1986-02-08 EP EP86101637A patent/EP0199004B1/de not_active Expired
- 1986-02-08 DE DE8686101637T patent/DE3665456D1/de not_active Expired
- 1986-02-20 KR KR1019860001178A patent/KR860006446A/ko not_active Application Discontinuation
- 1986-02-21 DD DD86287242A patent/DD243290A5/de not_active IP Right Cessation
- 1986-02-21 JP JP61035432A patent/JPS61210074A/ja active Pending
- 1986-02-24 US US06/832,120 patent/US4776973A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DD243290A5 (de) | 1987-02-25 |
US4776973A (en) | 1988-10-11 |
DE3506446A1 (de) | 1986-08-28 |
DE3665456D1 (en) | 1989-10-12 |
JPS61210074A (ja) | 1986-09-18 |
EP0199004A1 (de) | 1986-10-29 |
EP0199004B1 (de) | 1989-09-06 |
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WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |