KR920006271A - 할로겐화 알케닐 유도체 - Google Patents

할로겐화 알케닐 유도체 Download PDF

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KR920006271A
KR920006271A KR1019910015956A KR910015956A KR920006271A KR 920006271 A KR920006271 A KR 920006271A KR 1019910015956 A KR1019910015956 A KR 1019910015956A KR 910015956 A KR910015956 A KR 910015956A KR 920006271 A KR920006271 A KR 920006271A
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alkenyl
compound
chlorine
fluorine
diyl
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부헥커 리하르트
게르만 알프레트
샤트 마르틴
빌리거 알로이스
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게르하르트 분쯔, 롤란드 보러
에프. 호프만-라 롯슈 아크티엔게젤샤프트
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Abstract

내용 없음

Description

할로겐화 알케닐 유도체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 하기 일반식(Ⅰ)의 화합물 :
    (Ⅰ)
    상기식에서, Z1은 단일 공유결합 또는 -CH2CH2-를 나타내고; A1고리는 1, 4-페닐렌, 피리미딘-2,5-디일, 피리딘-2,5-디일을 나타내거나, 또는 Z1이 -CH2CH2-를 나타낼 때는 또한 트랜스-1,4-사이클로헥실렌을 나타내며; X1은 불소 또는 염소를 나타내고; X2는 불소, 염소 또는 수소를 나타내지만, 단, X1이 염소일때, 또는 A1고리가 피리딘-2,5-디일을 나타내고 Z1이 -CH2CH2-를 나타낼 때는 수소만을 나타내며; R1은 2 내지 12개의 탄소원자를 갖는 1E-알케닐을 나타낸다.
  2. 하기 일반식(Ⅰ)의 화합물 :
    (Ⅰ)
    상기식에서, Z1은 단일 공유결합 또는 -CH2CH2-를 나타내고; A1고리는 1, 4-페닐렌, 피리미딘-2,5-디일, 피리딘-2,5-디일을 나타내거나, 또는 Z1이 -CH2CH2-를 나타낼 때는 또한 트랜스-1,4-사이클로헥실렌을 나타내며; X1은 불소 또는 염소를 나타내고; X2는 불소 또는 염소를 나타내거나, 또는 X1이 염소를 나타낼 때는 또는 또한 수소를 나타내며; R1은 2 내지 12개의 탄소원자를 갖는 1E-알케닐을 나타낸다.
  3. 제1항 또는 제2항에 있어서, 하기 일반식(Ia) 내지(Ig)을 갖는 화합물 :
    la
    lc
    le
    lg
    상기식들에서, R1은 2 내지 12개의 탄소원자를 갖는 1E-알케닐 잔기를 나타내고 ; Z1은 단일 공유결합 또는 -CH2CH2-를 나타내며 : X3는 수소, 염소 또는 불소를 나타낸다.
  4. 제3항에 있어서, Z1이 단일 공유결합을 나타내는 화합물.
  5. 제1항 또는 제2항에 있어서, 하기 일반식(Ib) 내지 (Ih)를 갖는 화합물 :
    lb
    ld
    lf
    lh
    상기식에서, R1은 2 내지 12개의 탄소원자를 갖는 1E-알케닐 잔기를 나타내고 ; Z1은 단일 공유결합 또는 -CH2CH2-를 나타내며 : X3는 불소, 염소 또는 수소를 나타내고 ; X4는 염소 또는 불소를 나타내다.
  6. 제1항에 있어서, 하기 일반식(Ie)를 갖는 화합물 :
    le
    상기식에서, R1은 2 내지 12개의 탄소원자를 갖는 1E-알케닐 잔기를 나타내고 ; Z1은 단일 공유결합 또는 -CH2CH2-를 나타내며 : X3는 염소, 불소 또는 수소를 나타낸다.
  7. 제1항 내지 제5항중 어느 한 항에 있어서, R1이 직쇄 잔기를 나타내는 화합물.
  8. 제1항 내지 제6항중 어느 한 항에 있어서, R1이 2 내지 7개, 바람직하게는 2 내지 5개의 탄소원자를 갖는 화합물.
  9. 적어도 하나의 성분이 제1항에서 정의한 일반식(Ⅰ)의 화합물인, 적어도 2개의 성분을 갖는 액정 혼합물.
  10. 제9항에 있어서, 상기 일반식(Ⅰ)화합물의 함량이 1 내지 50중량%, 바람직하게는 5내지 30중량%인 액정 혼합물.
  11. 제9항 또는 제10항에 있어서, 일반식(Ⅰ)의 하나 이상의 화합물 및 하기 일반식(Ⅶ) 내지 ( X X V)의 화합물 그룹으로부터의 하나 이상의 화합물을 함유 하는 액정 혼합물:
    Ⅶ
    Ⅷ
    Ⅸ
    Ⅹ
    XI
    XⅡ
    XⅢ
    XⅣ
    XⅤ
    XⅥ
    XⅦ
    XⅧ
    XⅨ
    XX
    XXⅠ
    XXⅡ
    XXⅢ
    XXⅣ
    XXⅤ
    상기식들에서, n은 0 또는 1을 나타내고; R3및 R6는 각각 독립적으로 알킬, 3E-알케닐, 4-알케닐, 알콕시알킬을 나타내거나, 또는 포화된 고리상에서는 또한 1E-알케닐을 나타내며; A2고리는 1,4-페닐렌, 트랜스-1,4-사이클로헥실렌, 피리딘-2,5-디일, 피리미딘-2,5-디일 또는 트랜스-1,3-디옥산-2,5-디일을 나타내고; R4는 시아노, -NCS, 불소, 알킬, 3E-알케닐, 4-알케닐, 알콕시, 2E-알케닐톡시, 3-알케닐톡시 또는 알케닐,4-알케닐을 나타내거나, 또는 사이클로헥산 고리상에서는 또한 1E-알케닐을 나타내거나, 또는 벤젠알케닐, 3E-알케닐 또는 4-알케닐을 나타내고; Z2및 Z3는 각각 독립적으로 단일 공유결합 또는 -CH2CH2-를 나타내고, 단 2개의 방향족 고리는 항상 단일 공유결합에 의해 연결되어 있으며; R8은 시아노, 알킬, 3E-알케닐, 4-알케닐, 알콕시, 2E-알케닐톡시, 3-알케닐톡시, 알콕시메틸, (2E-알케닐)톡시메틸을 나타내거나, 또는 사이클로헥산 고리상에서는 또한 1E-알케닐을 나타내고; X5는 수소; 염소 또는 불소를 나타내며; X7은 수소 또는 불소를 나타낸다.
  12. 전광 목적에 사용하기 위한 제1항에 정의된 일반식(Ⅰ) 화합물의 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910015956A 1990-09-14 1991-09-13 할로겐화 알케닐 유도체 KR100221093B1 (ko)

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CH299290 1990-09-14
CH143491 1991-05-14
CH1434/91 1991-05-14

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DE3887084D1 (de) * 1987-11-06 1994-02-24 Hoffmann La Roche Halogenierte Benzolderivate.
DE4025550B4 (de) 1989-08-16 2007-05-03 Merck Patent Gmbh Phenylcyclohexane und flüssigkristallines Medium
DE59308576D1 (de) * 1992-10-30 1998-06-25 Merck Patent Gmbh Cyclohexyl-alkenoate als Komponente flüssigkristalliner Gemische
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KR100221093B1 (ko) 1999-09-15
EP0475273A1 (de) 1992-03-18
DE59109119D1 (de) 1999-05-12
JP3035392B2 (ja) 2000-04-24
US5292452A (en) 1994-03-08
EP0475273B1 (de) 1999-04-07

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