KR970006668A - 종이 제조 방법 - Google Patents

종이 제조 방법 Download PDF

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KR970006668A
KR970006668A KR1019960026619A KR19960026619A KR970006668A KR 970006668 A KR970006668 A KR 970006668A KR 1019960026619 A KR1019960026619 A KR 1019960026619A KR 19960026619 A KR19960026619 A KR 19960026619A KR 970006668 A KR970006668 A KR 970006668A
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molecular weight
polymer
cationic
high molecular
low molecular
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KR100194229B1 (ko
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미카엘 페르손
요아킴 카렌
한스 요한슨
카를로스 코도바
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자이드 스콜드
에카 케미칼스 에이비
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/04—Addition to the pulp; After-treatment of added substances in the pulp
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/24—Homopolymers or copolymers of amides or imides
    • C08L33/26—Homopolymers or copolymers of acrylamide or methacrylamide
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D21H17/28—Starch
    • D21H17/29—Starch cationic
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • D21H17/375—Poly(meth)acrylamide
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
    • D21H17/44—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups cationic
    • D21H17/45—Nitrogen-containing groups
    • D21H17/455—Nitrogen-containing groups comprising tertiary amine or being at least partially quaternised
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
    • D21H17/55—Polyamides; Polyaminoamides; Polyester-amides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
    • D21H17/56—Polyamines; Polyimines; Polyester-imides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/50—Aqueous dispersion, e.g. containing polymers with a glass transition temperature (Tg) above 20°C
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/04—Starch derivatives, e.g. crosslinked derivatives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/02—Polyamines

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Paper (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polarising Elements (AREA)

Abstract

본 발명은 섬유 및 충진재를 포함한 셀룰로오스의 현탁액으로부터 종이를 제조하는 방법에 관계하며, 저분자량의 양이온성 유기 고분자, 고분자 량의 양이온성 또느 양쪽성 고분자 및 음이온성 무기 입자가 현탁액에 첨가되며 이 현탁액은 종이 또는 망 상에 성형되고 배출되며, 저분자량의 고분자는 700,000 이하의 분자량을 가지며 고분자량의 고분자는 1,000,000 이상의 분자량을 가지며 상기 고분자들은 현탁액에 동시에 첨가된다. 본 발명은 1,000,000 이상의 분자량을 갖는 적어도 하나의 고분자 량의 양쪽성 및/또는 양이온성 아크릴아미드제 고분자와 700,000 이하의 분자량을 갖는 적어도 하나의 저분자량의 양이온성 유기 고분자와 적어도 하나의 수용성 무기염을 포함한 수분산물 형태의 고분자 혼합물에 더욱 관계하며, 상기 저분자 량의 고분자에 대한 상기 고분자량의 고분자의 중량 비는 9:1∼1:2 범위 내에 있다.

Description

종이 제조 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 저분자량의 양이온성 유기 고분자, 고분자량의 양이온성 또는 양쪽성 고분자 및 음이온성 무기입자가 현탁액에 가해지며 이 현탁액이 종이 뜨는 망 상에 성형되고 배출되는 섬유 및 충진재를 포함하는 셀룰로오스 현탁액으로부터 종이 제조방법에 있어서, 저분자량의 고분자가 700,000 이하의 분자량을 가지며 고분자량의 고분자가 1,000,000 이상의 분자량을 가지며 상기 고분자가 동시에 현탁액에 가해 짐을 특징으로 하는 종이 제조 방법.
  2. 제1항에 있어서, 저분자량의 고분자와 고분자량의 고분자가 혼합물 형태로 현탁액에 가해짐을 특징으로 하는 종이 제조 방법.
  3. 제1항에 있어서, 저분자량의 고분자와 고분자량의 고분자가 동시적이지만 별도로 현탁액에 가해짐을 특징으로 하는 종이 제조 방법.
  4. 제1항, 2항 또는 3항에 있어서, 고분자량의 고분자가 양이온성 전분, 양이온성 구아검 또는 양이온성 아크릴아미드계 고분자임을 특징으로 하는 종이 제조 방법.
  5. 제1항, 2항 또는 3항에 있어서, 저분자량의 양이온성 고분자가 개질된 전분, 폴리아민, 폴리에틸렌 이민, 폴리아미드아민/에피클로로히드린, 디메틸아민/에피클로로히드린 또는 디알릴디메틸 염화암모늄, 비닐아민, 아크릴(또는 메탈크릴)아미드, 아크릴(또는 메타크릴)데이트, 또는 이들의 혼합물에서 선택된 모노머 기초 단일이나 공중합체임을 특징으로 하는 종이 제조 방법.
  6. 앞선 청구항 중 어느 항에 있어서, 저분자량의 고분자에 대한 고분자량의 고분자의 중량비가 1:1∼1:3 범위내에 있음을 특징으로 하는 종이 제조 방법.
  7. 제1항에 있어서, 음이온성 무기 입자가 실리카계 입자임을 특징으로 하는 종이 제조 방법.
  8. 제7항에 있어서, 실리카계 입자가 콜로이드성 실리카, 콜로이드성 알루미늄으로 개질된 실리카, 콜로이드성 알루미늄 실리케이트 또는 폴리규산 임을 특징으로 하는 종이 제조 방법.
  9. 제1항에 있어서, 음이온성 무기입자가 벤토나이트임을 특징으로 하는 종이 제조 방법.
  10. 1,000,000 이상의 분자량을 갖는 적어도 하나의 고분자량의 양이온성 또는 양쪽성 아크릴아미드계 고분자와 700,000 이하의 분자량을 갖는 적어도 하나의 저분자량의 양이온성 유기고분자와 적어도 하나의 수용성 무기염을 포함하며, 상기 저분자량의 고분자에 대한 상기 고분자량의 고분자에 대한 중량비가 9:1∼1:2임을 특징으로 하는 수분산물 형태의 고분자 혼합물.
  11. 제10항에 있어서, 고분자량의 아크릴아미드계 고분자가 양이온성이며, 저분자량의 양이온성 고분자가 디알릴디메틸 염화암모늄, 아크릴(또는 베타크릴) 아미드, 아크릴(또는 메타크릴)레이트, 또는 이들의 혼합물로부터 선택된 모노머 기초 단일이나 공중합체임을 특징으로 하는 고분자 혼합물.
  12. 제10항 또는 11항에 있어서, 무기염이 황산나트륨, 황산암모늄, 황산 마그네슘 또는 황산알루미늄이고 무기물이 분산물에 대해서 5중량% 이상 존재함을 특징으로 하는 고분자 혼합물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960026619A 1995-07-07 1996-07-01 종이 제조 방법 KR100194229B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE9502522A SE9502522D0 (sv) 1995-07-07 1995-07-07 A process for the production of paper
SE9502522-7 1995-07-07

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KR970006668A true KR970006668A (ko) 1997-02-21
KR100194229B1 KR100194229B1 (ko) 1999-06-15

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US (2) US5858174A (ko)
EP (1) EP0752496B1 (ko)
JP (1) JP4053620B2 (ko)
KR (1) KR100194229B1 (ko)
CN (1) CN1087370C (ko)
AT (1) ATE207989T1 (ko)
AU (1) AU691428B2 (ko)
BR (1) BR9602943A (ko)
CA (1) CA2180404C (ko)
CZ (1) CZ293559B6 (ko)
DE (1) DE69616439T2 (ko)
DK (1) DK0752496T3 (ko)
ES (1) ES2166424T3 (ko)
NO (1) NO323050B1 (ko)
NZ (1) NZ286923A (ko)
PL (1) PL190930B1 (ko)
PT (1) PT752496E (ko)
RU (1) RU2121538C1 (ko)
SE (1) SE9502522D0 (ko)
TW (1) TW308618B (ko)
ZA (1) ZA965610B (ko)

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Publication number Priority date Publication date Assignee Title
KR100449000B1 (ko) * 2001-12-31 2004-09-16 한국조폐공사 습강지의 제조방법
KR100514349B1 (ko) * 2002-07-08 2005-09-13 경상대학교산학협력단 항균 포장지 제조방법
KR100681327B1 (ko) * 2002-10-31 2007-02-15 주식회사 오병 콜로이달 실리카를 함유하는 고농축 벤토나이트 액상슬러리 및 그 제조방법

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US6238521B1 (en) 1996-05-01 2001-05-29 Nalco Chemical Company Use of diallyldimethylammonium chloride acrylamide dispersion copolymer in a papermaking process
US5744003A (en) * 1996-07-30 1998-04-28 Ashland Inc. Process for controlling the deposition of pitch with a blend of derivatized cationic guar and styrene maleic anhydride copolymer
US6664326B1 (en) * 1996-10-03 2003-12-16 Cytec Technology Corp. Aqueous dispersions
US6608124B1 (en) 1996-10-03 2003-08-19 Cytec Technology Corp. Aqueous dispersions
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US5989392A (en) * 1997-09-10 1999-11-23 Nalco Chemical Company Method of using polyammonium quaternary for controlling anionic trash and pitch deposition in pulp containing broke
CO5070714A1 (es) * 1998-03-06 2001-08-28 Nalco Chemical Co Proceso para la preparacion de silice coloidal estable
US7306700B1 (en) 1998-04-27 2007-12-11 Akzo Nobel Nv Process for the production of paper
KR100403839B1 (ko) * 1998-04-27 2003-11-01 악조 노벨 엔.브이. 제지 방법
EP0953680A1 (en) * 1998-04-27 1999-11-03 Akzo Nobel N.V. A process for the production of paper
US6132625A (en) 1998-05-28 2000-10-17 E. I. Du Pont De Nemours And Company Method for treatment of aqueous streams comprising biosolids
FI107174B (fi) * 1998-07-10 2001-06-15 Raisio Chem Oy Paperinvalmistuksen lisäainekoostumus
US6716313B2 (en) * 1998-07-10 2004-04-06 Raisio Chemicals, Ltd. Additive for paper making
WO2000047819A1 (en) * 1999-02-15 2000-08-17 Akzo Nobel N.V. Sizing dispersion
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