KR960706540A - 함불소계 중합체 수성 분산액[aqueous fluoropolymer dispersion] - Google Patents

함불소계 중합체 수성 분산액[aqueous fluoropolymer dispersion]

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Publication number
KR960706540A
KR960706540A KR1019960703128A KR19960703128A KR960706540A KR 960706540 A KR960706540 A KR 960706540A KR 1019960703128 A KR1019960703128 A KR 1019960703128A KR 19960703128 A KR19960703128 A KR 19960703128A KR 960706540 A KR960706540 A KR 960706540A
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South Korea
Prior art keywords
fluorine
containing polymer
aqueous
group
organosilicon compound
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KR1019960703128A
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English (en)
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KR100494864B1 (ko
Inventor
노부히꼬 쓰다
야스시 요네이
류우지 이와끼리
가쯔히꼬 이모또
Original Assignee
이노우에 노리유끼
다이낑고오교 가부시끼가이샤
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Publication of KR960706540A publication Critical patent/KR960706540A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
    • C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Graft Or Block Polymers (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

함불소계 중합체 수성 분산체의 고형분 100중량부에 대하여 유기규소 화합물의 고형분 1∼20중량부가 배합되어 있는 함불소계 중합체 수성분산액으로서 각종 기재에의 밀착성, 성막성, 내후성, 내오염성이 뛰어난 도막을 형성할 수 있는 도료에 유용한 함불수계 중합체 수성분산액을 제공한다.

Description

함불소계 중합체 수성 분산액[AQUEOUS FLUOROPOLYMER DISPERSION]
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 함불소계 중합체 수성 분산체의 고형분 100중량부에 대하여 유기규소 화합물 1∼20중량부가 배합되어 있는 함불소계 중합체 수성 분산액.
  2. 제1항에 있어서, 상기 함불소계 중합체 수성분산체중의 함불소계 중합체가 플루오로올레핀을 중합하여 얻어지는 함불소 중합체 또는 플루오로올레핀과의 공중합이 가능한 단량체와 플루오로올레핀을 공중합하여 얻어지는 함불소 중합체이며, 이러한 중합 또는 공중합 후 유기규소 화합물이 배합되어 있는 함불소계 중합체 수성분산액.
  3. 제1항에 있어서, 상기 함불소계 중합체 수성분산체중의 함불소계 중합체가 플루오로올레핀을 중합하여 얻어지는 함불소 중합체의 입자 또는 플루오로올레핀과의 공중합이 가능한 단량체와 플루오로올레핀을 공중합하여 얻어지는 함불소 중합체의 입자의 존재하에 반응성 α, β- 불포화기를 갖는 단량체를 시이드 중합하여 얻어지는 함불소 시이드 중합체이며, 이 시이드 중합 후, 유기규소 화합물이 배합되어 있는 함불소계 중합체 수성 분산액.
  4. 제3항에 있어서, 상기 반응성 α, β- 불포화기를 갖는 단량체가 아크릴산 에스테르 및/ 또는 메타크릴산 에스테르인 함불소계 중합체 수성분산액.
  5. 제3항 또는 제4항에 있어서, 상기 반응성 α, β- 불포화기를 갖는 단량체의 일부가 반응성 α,β- 불포화기를 갖는 유기규소 화합물로서, 이 반응성 α,β- 불포화기를 갖는 단량체 중 0.1∼50중량%를 차지하는 함불소계 중합체 수성분산액.
  6. 제2항 내지 제5항 중 어느 한 항에 있어서, 상기 함불소 중합체가 비닐리덴 플루오라이드 70∼95몰% 및 클로로트리플루오로에틸렌 5∼30몰%를 함유하고 있는 함불소계 중합체 수성분산액.
  7. 제1항에 있어서, 상기 함불소계 중합체 수성분산체 중의 함불소계 중합체가 비닐리덴 플루오라이드 70∼90몰% 및 클로로트리플루오로에틸렌 5∼30몰%를 함유하고 있는 단량체를 공중합하여 얻어지는 함불소 중합체의 입자의 존재하에 아크릴산에스테르 및/또는 메티크릴산에스테르를 시이드 중합하여 얻어지는 함불소 시이드 중합체이며, 이러한 공중합 또는 시이드 중합후 유기규소 화합물이 배합되어 있는 함불소계 중합체 수성분산액.
  8. 제1항에 있어서, 상기 유기규소 화합물이 일반시(Ⅰ) :
    R1 aSi(OR2)4-a(Ⅱ)
    (식중 R1은 비가수분해성기 또는 수소원자를 나타내고, R2는 알킬기, 아릴기, 알케닐기 또는 수소원자를 나타내고, a는 0,1 또는 2이다)로 표시되는 유기규소 단량체인 함불소계 중합체 수성분산액.
  9. 제1항에 있어서, 상기 유기규소 화합물이 일반식(Ⅲ) :
    (식중, R1은 비가수분해성기 또는 수소원자를 나타내고, R2는 알킬기, 아릴기, 알케닐기 또는 수소원자를 나타내고, c는 2∼50의 정수이다)로 표시되는 유기규소올리고머인 함불소계 중합체 수성분산액.
  10. 제1항에 있어서, 상기 유기규소 화합물이 일반식(Ⅴ) :
    (식중, R1은 비가수분해성기 또는 수소원자를 나타내고, R2는 알킬기, 아릴기, 알케닐기 또는 수소원자를 나타내고, B는 계면활성기, e는 2∼50의 정수이다)로 표시되는 유기규소 올리고머인 함불소계 중합체 수성분산액.
    ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
KR1019960703128A 1994-10-24 1995-10-19 함불소계중합체수성분산액 KR100494864B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP94-258173 1994-10-24
JP25817394A JP3239645B2 (ja) 1994-10-24 1994-10-24 含フッ素系重合体水性分散液
PCT/JP1995/002152 WO1996012773A1 (fr) 1994-10-24 1995-10-19 Dispersion fluoropolymere aqueuse

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KR960706540A true KR960706540A (ko) 1996-12-09
KR100494864B1 KR100494864B1 (ko) 2005-12-26

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Country Link
US (1) US5712335A (ko)
EP (1) EP0736583A4 (ko)
JP (1) JP3239645B2 (ko)
KR (1) KR100494864B1 (ko)
WO (1) WO1996012773A1 (ko)

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Publication number Publication date
EP0736583A4 (en) 1998-10-14
EP0736583A1 (en) 1996-10-09
US5712335A (en) 1998-01-27
JPH08120211A (ja) 1996-05-14
WO1996012773A1 (fr) 1996-05-02
KR100494864B1 (ko) 2005-12-26
JP3239645B2 (ja) 2001-12-17

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