KR920701280A - 아크릴 공중합체 및 그의 코팅제로서의 용도 - Google Patents

아크릴 공중합체 및 그의 코팅제로서의 용도

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Publication number
KR920701280A
KR920701280A KR1019910700961A KR910700961A KR920701280A KR 920701280 A KR920701280 A KR 920701280A KR 1019910700961 A KR1019910700961 A KR 1019910700961A KR 910700961 A KR910700961 A KR 910700961A KR 920701280 A KR920701280 A KR 920701280A
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South Korea
Prior art keywords
parts
methacrylate
copolymer according
carbon atoms
alkyl
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KR1019910700961A
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English (en)
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위게르 베르냐르
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아토샹
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Publication of KR920701280A publication Critical patent/KR920701280A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/10—Homopolymers or copolymers of methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

아크릴 공중합체 및 그의 코팅제로서의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

100중량부당, 알킬기에 1 내지 10탄소원자가 있는 하나 이상의 알킬 아크릴레이트 도는 메타크릴레이트 또는 아릴기에 6 내지 10탄소원자가 있는 아릴 아크릴레이트 또는 메타크릴레이트 약 20 내지 95부, -하나 이상의 하기 일반식의 아민화 메타크릴레이트 약 5 내지 50부:
(여기서, n은 1 내지 20사이의 정수이고, R1은 1 내지 10탄소원자를 갖는 알킬 라디칼이다).
-하나 이상의 불소화 알킬(메타) 아크릴레이트 약 0내지 65부 및-아크릴 산 5부 이하를 포함함을 특징으로 하는 아크릴 공중합체.
제1항에 있어서, 100중량부당 하나 이상의 교차 결합 단량체 3부까지를 부가적으로 포함함을 특징으로 하는 공중합체.
제1항 또는 제2항에 있어서, 불소화 알킬 메타크릴레이트가 하기식 화합물임을 특징으로 하는 공중합체:
(상기식에서 R1은 메틸 라디칼이고, R2및 R3은 동일하거나 상이하며, H, CH3, CH2, -CH3및 CF3에서 선택되며; A는 CF2및 CFH에서 선택되고; n은 1 내지 19사이이며; m은 0 내지 n이다).
제1항 내지 제3항중 어느 한 항에 있어서, 수성분산액을 존재함을 특징으로 하는 공중합체.
제4항에 있어서, 분산액의 입자크기가 0.05 내지 0.5㎛사이임을 특징으로 하는 공중합체.
제4항 또는 제5항에 있어서, 20℃에서 분산액의 브룩필드 점도가 30 내지 300mPa.s사이임을 특징으로 하는 공중합체.
수성 유탁액 중에서 단량체를 중합시키는 것으로 이루어지는 제1 내지 6항중 어느 한항에 따르는 공중합체의 제조방법에 있어서, 중합될 단량체 혼합물이 100중량부당, -알킬기에 1 내지 10탄소원자가 있는 하나 이상의 알킬 아크릴레이트 또는 메타크릴레이트 또는 아릴기에 6 내지 10탄소원자가 있는 아릴 아크릴레이트 또는 메타아크릴레이트 약 20 내지 95부, -하나 이상의 하기 일반식 (Ⅰ)의 아민화 메타크릴레이트 약 5 내지 50부,
(여기서, n은 1 내지 20사이의 정수이며, R1은 1 내지 20탄소원자를 갖는 알킬 라디칼이다).
-하나 이상의 불소화 알킬(메타) 아크릴 레이트 약 0 내지 65부, -아크릴 산 5부 이하 및 -하나 이상의 교차 결합 단량체 0내지 3부를 포함하는 것을 특징으로 하는 방법.
제7항에 있어서, 중합을 55℃ 내지 99℃온도에서 수행함을 특징으로 하는 제조방법.
제7항 또는 제8항에 있어서, 중합을 2 내지 8시간에 걸쳐 수행함을 특징으로 하는 방법.
기질이 제1항 내지 제7항중 어느 한항에 따른 공중합체의 수성분산액을 포함하는 제제로 코팅됨을 특징으로 하는 기질의 코팅 방법.
제1항 내지 7항중 어느 한 항에 따른 공중 합체의 수성분산액의 특히 건축산업용의 얼룩 방지 코팅제로서의 용도.
※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910700961A 1989-12-21 1990-12-19 아크릴 공중합체 및 그의 코팅제로서의 용도 KR920701280A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR89.16989 1989-12-21
FR8916989A FR2656316B1 (fr) 1989-12-21 1989-12-21 Nouveaux copolymeres acryliques et leur application comme revetements.
PCT/FR1990/000927 WO1991009889A1 (fr) 1989-12-21 1990-12-19 Nouveaux copolymeres acryliques et leur application comme revetements

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KR920701280A true KR920701280A (ko) 1992-08-11

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Country Status (8)

Country Link
US (1) US5225505A (ko)
EP (1) EP0460170A1 (ko)
JP (1) JPH04503690A (ko)
KR (1) KR920701280A (ko)
AU (1) AU642192B2 (ko)
CA (1) CA2046867A1 (ko)
FR (1) FR2656316B1 (ko)
WO (1) WO1991009889A1 (ko)

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JP5478553B2 (ja) 2010-09-03 2014-04-23 日東電工株式会社 連続ウェブ状光学フィルム積層体ロール及びその製造方法
JP5701679B2 (ja) 2010-09-03 2015-04-15 日東電工株式会社 矩形形状のパネルに偏光膜を有する光学フィルムを順次的に貼り付ける方法及び装置
JP5511730B2 (ja) 2010-09-03 2014-06-04 日東電工株式会社 光学的パネル組立体の連続的製造方法及び装置
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EP0460170A1 (fr) 1991-12-11
AU6975991A (en) 1991-07-24
JPH04503690A (ja) 1992-07-02
US5225505A (en) 1993-07-06
CA2046867A1 (fr) 1991-06-22
FR2656316B1 (fr) 1993-12-31
WO1991009889A1 (fr) 1991-07-11
FR2656316A1 (fr) 1991-06-28
AU642192B2 (en) 1993-10-14

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