KR870005683A - 중합체 분산액의 제조방법 - Google Patents
중합체 분산액의 제조방법 Download PDFInfo
- Publication number
- KR870005683A KR870005683A KR860010687A KR860010687A KR870005683A KR 870005683 A KR870005683 A KR 870005683A KR 860010687 A KR860010687 A KR 860010687A KR 860010687 A KR860010687 A KR 860010687A KR 870005683 A KR870005683 A KR 870005683A
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- polymer dispersion
- methacrylate
- polymerization
- carried out
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (11)
- 에폭시기를 추가로 함유하는 1내지 99중량%의 카복시-작용성 중합체(A) 및 0 내지 20중량%의 음이온 또는 비이온성 유화제 또는 2가지 이상의 보호 콜로이드의 혼합물(C)의 존재하 및 필요한 경우 추가의 첨가제의 존재하에서, 1 내지 99중량%의 적어도 하나의 α,β-올레핀계 불포화 단량체(B)[상기의 양은 성분 (A) 내지 (C)의 고체 함량에 관한 것이다]를 0 내지 150℃의 수성 시스템에서 중합시킴을 특징으로 하여 수성 중합체 분산액을 제조하는 방법.
- 제1항에 있어서, 중합반응을 20 내지 100℃, 특히 40 내지 90℃의 온도에서 수행하는 방법.
- 제1항 또는 제2항에 있어서, 유화제 및/또는 보호 콜로이드를 사용하지 않는 방법.
- 제1항 내지 제3항중 어느 하나에 있어서, 중합반응을 0.02내지 5중량%, 특히 0.05 내지 3중량%의, 자유 라디칼을 생성시키는 개시제의 존재하에서 수행시키는 방법.
- 제1항 내지 제4항중 어느 하나에 있어서, 성분 (A) 및 (B)를 각각 5 내지 95중량%의 양으로 사용하는 방법.
- 제1항 내지 제5항 중 어느 하나에 있어서, 단량체(B)의 총량을 기준으로 하여 0.01 내지 20중량%의 α,β-에틸렌계 최대 3불포화 단량체를 사용하는 방법.
- 제1항 내지 제6항중 어느 하나에 있어서, 메틸 메타크릴레이트 및 n-부틸아크릴레이트로 이루어진 그룹으로부터 선택된 적어도 한 화합물 100중량%이하, 0 내지 20중량%의 히드록시에틸메타크릴레이트, 0 내지 20중량%의 글리시딜 메타크릴레이트 및 0 내지 20중량%의 아크릴 및/또는 메타크릴산(단량체의 총합은 항상 100%이다)을 성분 B로서 사용하는 방법.
- 제7항에 있어서, 15내지 80중량%의 메틸메타크릴레이트, 15 내지 50중량%의 n-부틸 아크릴레이트, 0 내지 15중량%의 히드록시에틸 메타크릴레이트, 0 내지 15중량%의 글리시딜 메타크릴레이트 및 0 내지 5중량%의 아클릴 및/또는 메타크릴산을 성분(B)로서 사용하는 방법.
- 제1항 내지 제8항 중 어느 하나에 있어서, 중합체 분산액의 고체 함량이 5 내지 75중량%, 바람직하게는 10 내지 65중량%인 방법.
- 실온 또는 승온에서 경화되는 피막 시스템을 생성하는 결합제 성분으로 제1항 내지 9항 중 어느 하나에서 수득가능한 수성 중합체 분산액의 용도.
- 제10항에 있어서, 피막 시스템이 금속성 초벌칠, 금속이 없는 (단일) 초벌칠, 재마감 페인트 또는 전기 피막인 용도.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP3544337.5 | 1985-12-14 | ||
DE19853544337 DE3544337A1 (de) | 1985-12-14 | 1985-12-14 | Polymerisatdispersionen, verfahren zu ihrer herstellung, sowie deren anwendung als bindemittel |
Publications (2)
Publication Number | Publication Date |
---|---|
KR870005683A true KR870005683A (ko) | 1987-07-06 |
KR940010968B1 KR940010968B1 (ko) | 1994-11-21 |
Family
ID=6288490
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019860010687A KR940010968B1 (ko) | 1985-12-14 | 1986-12-13 | 중합체 분산액의 제조방법 |
Country Status (15)
Country | Link |
---|---|
US (1) | US4981885A (ko) |
EP (1) | EP0226171B1 (ko) |
JP (1) | JPH0813869B2 (ko) |
KR (1) | KR940010968B1 (ko) |
AR (1) | AR245169A1 (ko) |
AT (1) | ATE76414T1 (ko) |
AU (1) | AU590369B2 (ko) |
BR (1) | BR8606156A (ko) |
CA (1) | CA1297606C (ko) |
DE (2) | DE3544337A1 (ko) |
ES (1) | ES2042490T3 (ko) |
FI (1) | FI90555C (ko) |
MX (1) | MX164417B (ko) |
PT (1) | PT83925B (ko) |
ZA (1) | ZA869372B (ko) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0623238B2 (ja) * | 1986-04-08 | 1994-03-30 | 日本ゼオン株式会社 | アクリレ−ト系エラストマ−加硫性組成物 |
DE3628124A1 (de) * | 1986-08-19 | 1988-03-03 | Herberts Gmbh | Waessriges ueberzugsmittel, verfahren zu seiner herstellung und dessen verwendung |
US5120889A (en) * | 1989-12-14 | 1992-06-09 | National Starch And Chemical Investment Holding Corporation | Method for manufacturing binder for lead storage battery glass (fiber) mats |
CA2065100A1 (en) * | 1991-04-05 | 1992-10-06 | Masami Uemae | Aqueous dispersion of acrylic polymer |
EP0561343B1 (en) * | 1992-03-16 | 1997-01-08 | Kawasaki Steel Corporation | Binder system for use in the injection molding of sinterable powders and molding compound containing the binder system |
US5286415A (en) * | 1992-12-28 | 1994-02-15 | Advanced Products, Inc. | Water-based polymer thick film conductive ink |
JPH06346020A (ja) * | 1993-06-03 | 1994-12-20 | Mitsui Saitetsuku Kk | 缶外面水性樹脂組成物 |
AT400440B (de) * | 1993-12-06 | 1995-12-27 | Vianova Kunstharz Ag | Verfahren zur herstellung von wasserverdünnbaren lackbindemitteln und deren verwendung |
JPH09505631A (ja) * | 1994-04-30 | 1997-06-03 | ワッカー−ケミー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | 水性コーティング組成物及び観察される色が視角に依存する多層塗り塗装系の製造方法 |
JP3644080B2 (ja) * | 1994-08-17 | 2005-04-27 | 大同特殊鋼株式会社 | モータ用部品及びその塗装方法 |
DE19504015C2 (de) * | 1995-02-07 | 1998-08-13 | Bollig & Kemper | Mikrogel |
DE19644176A1 (de) * | 1996-10-24 | 1998-04-30 | Belland Ag | Packung, enthaltend einen trockenen alkalischen Feststoff |
US6187374B1 (en) | 1998-09-02 | 2001-02-13 | Xim Products, Inc. | Coatings with increased adhesion |
US6409814B1 (en) | 2000-04-19 | 2002-06-25 | E. I. Du Pont De Nemours And Company | Pigment preparations and water-borne effect base coats prepared therewith |
US6528582B2 (en) | 2000-05-16 | 2003-03-04 | Neste Resins Canada | Method of preparing co-polymer particles |
US6245853B1 (en) * | 2000-05-16 | 2001-06-12 | Neste Resins Canada | Method of preparing co-polymer particles |
CN1846030A (zh) * | 2003-09-04 | 2006-10-11 | 皇家飞利浦电子股份有限公司 | 道路标志系统 |
CN102390590B (zh) | 2004-10-20 | 2016-02-10 | 威士伯采购公司 | 用于罐的涂料组合物和涂覆方法 |
US8299163B2 (en) * | 2007-03-22 | 2012-10-30 | Kansai Paint Co., Ltd. | Water-based paint compositions and multilayer coating film-forming method |
JP5424184B2 (ja) * | 2007-10-11 | 2014-02-26 | 関西ペイント株式会社 | 水性塗料組成物 |
BR112015032814B1 (pt) | 2013-07-02 | 2021-12-14 | Swimc Llc | Artigo, e, métodos para fazer uma composição de revestimento e para formar um revestimento curado |
WO2015002958A1 (en) | 2013-07-02 | 2015-01-08 | Valspar Sourcing, Inc. | Coating compositions for packaging articles such as food and beverage containers |
KR101549791B1 (ko) * | 2013-09-30 | 2015-09-02 | 주식회사 엘지화학 | 아크릴계 광학 필름, 이를 포함하는 편광판 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3386939A (en) * | 1964-11-27 | 1968-06-04 | Du Pont | Acrylic dispersions for wire enamels |
BE823039A (fr) * | 1973-12-06 | 1975-04-01 | Peintures en poudre contenant des particules metalliques | |
DE2408298C3 (de) * | 1974-02-21 | 1980-08-21 | Basf Ag, 6700 Ludwigshafen | Verfahren zur flächenhaften Beschichtung von festen Substraten und seine Anwendung |
US3953644A (en) * | 1974-12-20 | 1976-04-27 | Ford Motor Company | Powa--method for coating and product |
JPS5922722B2 (ja) * | 1975-09-12 | 1984-05-29 | 関西ペイント株式会社 | エマルジヨン組成物 |
JPS595350B2 (ja) * | 1976-01-30 | 1984-02-03 | 三井東圧化学株式会社 | メタリック調塗膜の形成方法 |
JPS52108488A (en) * | 1976-03-08 | 1977-09-10 | Kao Corp | Preparation of liquid resin dispersions |
SE441599B (sv) * | 1976-05-11 | 1985-10-21 | Scm Corp | Ymppolymerkomposition av ett epoxidharts och etenisk omettad additionspolymeriserbar monomer och forfarande for framstellning derav |
DE2851962A1 (de) * | 1978-03-18 | 1980-06-19 | Hoechst Ag | Verwendung eines wasserloeslichen reaktiven bindemittels fuer klebstoffe |
DE2811913A1 (de) * | 1978-03-18 | 1980-02-21 | Hoechst Ag | Wasserloesliche reaktive polymerenmischung |
DE3128062A1 (de) * | 1981-07-16 | 1983-02-03 | Hoechst Ag, 6000 Frankfurt | Waessrige copolymerisat-dispersionen, verfahren zu ihrer herstellung und verwendung der dispersionen |
US4444923A (en) * | 1982-12-30 | 1984-04-24 | Mobil Oil Corporation | Process for preparing aqueous coatings comprising dispersible epoxy resin-acid polymer ester |
US4564648A (en) * | 1984-09-21 | 1986-01-14 | E. I. Du Pont De Nemours And Company | Epoxy graft acrylic water-based primer surfaces |
US4579887A (en) * | 1985-02-26 | 1986-04-01 | The Dow Chemical Company | Non-aqueous dispersions of relatively high molecular weight epoxy resins |
-
1985
- 1985-12-14 DE DE19853544337 patent/DE3544337A1/de not_active Withdrawn
-
1986
- 1986-12-09 ES ES86117167T patent/ES2042490T3/es not_active Expired - Lifetime
- 1986-12-09 AT AT86117167T patent/ATE76414T1/de not_active IP Right Cessation
- 1986-12-09 EP EP86117167A patent/EP0226171B1/de not_active Expired - Lifetime
- 1986-12-09 DE DE8686117167T patent/DE3685415D1/de not_active Expired - Fee Related
- 1986-12-11 FI FI865060A patent/FI90555C/fi not_active IP Right Cessation
- 1986-12-11 BR BR8606156A patent/BR8606156A/pt not_active IP Right Cessation
- 1986-12-11 AR AR86306149A patent/AR245169A1/es active
- 1986-12-12 ZA ZA869372A patent/ZA869372B/xx unknown
- 1986-12-12 CA CA000525165A patent/CA1297606C/en not_active Expired - Fee Related
- 1986-12-12 AU AU66481/86A patent/AU590369B2/en not_active Ceased
- 1986-12-12 MX MX4646A patent/MX164417B/es unknown
- 1986-12-12 PT PT83925A patent/PT83925B/pt not_active IP Right Cessation
- 1986-12-13 JP JP61295775A patent/JPH0813869B2/ja not_active Expired - Lifetime
- 1986-12-13 KR KR1019860010687A patent/KR940010968B1/ko not_active IP Right Cessation
-
1989
- 1989-08-23 US US07/397,770 patent/US4981885A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
FI90555B (fi) | 1993-11-15 |
ES2042490T3 (es) | 1993-12-16 |
CA1297606C (en) | 1992-03-17 |
MX164417B (es) | 1992-08-12 |
EP0226171A2 (de) | 1987-06-24 |
US4981885A (en) | 1991-01-01 |
ATE76414T1 (de) | 1992-06-15 |
JPS62141013A (ja) | 1987-06-24 |
EP0226171B1 (de) | 1992-05-20 |
AR245169A1 (es) | 1993-12-30 |
FI865060A (fi) | 1987-06-15 |
FI865060A0 (fi) | 1986-12-11 |
ZA869372B (en) | 1987-08-26 |
PT83925B (pt) | 1989-06-30 |
PT83925A (de) | 1987-01-01 |
AU6648186A (en) | 1987-06-18 |
JPH0813869B2 (ja) | 1996-02-14 |
BR8606156A (pt) | 1987-09-22 |
DE3685415D1 (de) | 1992-06-25 |
KR940010968B1 (ko) | 1994-11-21 |
EP0226171A3 (en) | 1989-08-16 |
AU590369B2 (en) | 1989-11-02 |
DE3544337A1 (de) | 1987-06-19 |
FI90555C (fi) | 1994-02-25 |
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