KR880003068A - 미세분할된 수성분산제를 재료로한 종이아교물 - Google Patents

미세분할된 수성분산제를 재료로한 종이아교물 Download PDF

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KR880003068A
KR880003068A KR1019870008990A KR870008990A KR880003068A KR 880003068 A KR880003068 A KR 880003068A KR 1019870008990 A KR1019870008990 A KR 1019870008990A KR 870008990 A KR870008990 A KR 870008990A KR 880003068 A KR880003068 A KR 880003068A
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weight
monomer
finely divided
monomer mixture
divided water
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KR1019870008990A
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KR960003432B1 (ko
Inventor
데겐 한스-위르겐
라이헬 프릿츠
리벨링 울리히
회르 로타르
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반게르트, 바르츠
바스프 악티엔게젤샤프트
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D21H17/28—Starch
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Paper (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Disintegrating Or Milling (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Polymerisation Methods In General (AREA)
  • Colloid Chemistry (AREA)

Abstract

내용 없음

Description

미세분할된 수성분산제를 재료로한 종이아교물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. 혼성 중합체의 미세분할된 수성분산제를 재료로 하는 종이아교물에 있어서, 에멀션 중합 방법에 따라 (a) 아크릴로니트릴과/또는 세타그릴로니트릴의 중량비로 20 내지 65%, (b) 모노히드릭 포화된 C3-C8-알코올의 아크릴 레이트의 중량비가 80 내지 35%, (c) 에틸렌화 불포화 혼성 중합 가능한 단량체의 중량비로 0 내지 10%의 단량체 혼합물의 10 내지 56 부분들을 0.12 내지 0.50dl/g의 점성도 n1를 가진 분해전분의 중량비로 1.5내지 25%의 수성용액의 100부분 내에서 40 내지 100℃로 개시제를 함유한 과산화물의 존재하에 혼성중합시키므로 제조되는데(a), (b) 및 (c)의 합은 항상 100으로 되게한 미세분할 된 수성분산제를 재료로 하는 종이아교물.
  2. 제1항에 있어서, (a) 아크릴로니트릴과, (b) 하나 이상의 부틸 아크릴레이트의 단량체 혼합물이 혼성중합 되게한 미세분할된 수성분산제를 재료로하는 종이아교물.
  3. 제1항 또는 제2항에 있어서, 단량체(c)로써 에틸렌화 불포화 C3-C5-카르복실산, 아황화비닐과/또는 2-아크릴아미도 프로판술폰산을 함유한 단량체 혼합물이 혼성 중합되게한 미세분할된 수성분산제를 재료로 하는 종이아교물.
  4. 제1항 또는 제2항에 있어서, 단량체(c)로서 2-C1-C3-알킬아미노-C2-C6-알킬(메타)아크릴레이트, N-비닐이미다졸린과/또는 N-비닐-2-메틸이미다졸린이거나 그들의 4가 생성물을 함유한 단량체 혼합물이 혼성중합되게 한 미세 분할된 수성분산제를 재료로 한 종이아교물.
  5. 제1항 또는 제2항에 있어서, 단량체(c)로써, 스틸렌, 아크릴아미드, 메타크릴 아미드, 아크릴레이트(b)와 다른 메타크릴레이트 아크릴 레이트를 함유한 단량체 혼합물이 혼성중합되게 한 미세 분할된 수성분산제를 재료로한 종이아교물.
  6. 혼성중합체에 있어서, (a) 아크릴로니트릴/또는 메타크릴로 니트릴의 중량비로 20 내지 65%, (b) 모노노히드릭 포화된 C3-C8-알코올의 아크릴 테이트의 중량비로 80내지 35%, (c) 에틸렌화 불포화 혼성 중합 가능한, 단량체의 중량비로 0 내지 10%로 되는 단량체 혼합물의 중량비로 10내지 56부분을 0.12내지 0.50dl/g의 점성도 n1를 가진 분해 전분의 중량비로 1.5내지 25%의 수성용액의 100부분들 내에서 40 내지 100℃로 개시제를 함유한 과산화물의 존재하에 혼성중합키셔 제조한 혼성중합체가 종이용 아교물로써 사용되게 하고, (a), (b) 및 (c)의 합이 항상 100이 되게한 혼성중합체의 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870008990A 1986-08-14 1987-08-14 미세분할된 수성 분산제를 재료로 한 종이아교물 KR960003432B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19863627594 DE3627594A1 (de) 1986-08-14 1986-08-14 Leimungsmittel fuer papier auf basis feinteiliger waessriger dispersionen
DEP3627594.8 1986-08-14

Publications (2)

Publication Number Publication Date
KR880003068A true KR880003068A (ko) 1988-05-13
KR960003432B1 KR960003432B1 (ko) 1996-03-13

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Country Link
US (1) US4855343A (ko)
EP (1) EP0257412B2 (ko)
JP (1) JP2518858B2 (ko)
KR (1) KR960003432B1 (ko)
AT (1) ATE58191T1 (ko)
AU (1) AU594492B2 (ko)
BR (1) BR8704166A (ko)
CA (1) CA1294721C (ko)
DE (2) DE3627594A1 (ko)
DK (1) DK422187A (ko)
ES (1) ES2018508T5 (ko)
FI (1) FI88928C (ko)
NZ (1) NZ221423A (ko)

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Publication number Publication date
DK422187A (da) 1988-02-15
FI88928B (fi) 1993-04-15
ES2018508B3 (es) 1991-04-16
FI873236A (fi) 1988-02-15
EP0257412B2 (de) 1993-07-07
ATE58191T1 (de) 1990-11-15
JPS6350596A (ja) 1988-03-03
AU594492B2 (en) 1990-03-08
ES2018508T5 (es) 1995-08-01
KR960003432B1 (ko) 1996-03-13
FI873236A0 (fi) 1987-07-23
DE3627594A1 (de) 1988-02-18
DK422187D0 (da) 1987-08-13
JP2518858B2 (ja) 1996-07-31
CA1294721C (en) 1992-01-21
FI88928C (fi) 1993-07-26
AU7685587A (en) 1988-02-18
US4855343A (en) 1989-08-08
NZ221423A (en) 1989-02-24
DE3766045D1 (de) 1990-12-13
EP0257412B1 (de) 1990-11-07
EP0257412A1 (de) 1988-03-02
BR8704166A (pt) 1988-04-12

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