KR830002811A - 수지 제조 방법 - Google Patents
수지 제조 방법Info
- Publication number
- KR830002811A KR830002811A KR1019800001929A KR800001929A KR830002811A KR 830002811 A KR830002811 A KR 830002811A KR 1019800001929 A KR1019800001929 A KR 1019800001929A KR 800001929 A KR800001929 A KR 800001929A KR 830002811 A KR830002811 A KR 830002811A
- Authority
- KR
- South Korea
- Prior art keywords
- acrylate
- weight
- initiator
- methacrylate
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims 2
- 239000011347 resin Substances 0.000 title claims 2
- 229920005989 resin Polymers 0.000 title claims 2
- 239000003999 initiator Substances 0.000 claims 4
- 238000006243 chemical reaction Methods 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- 239000000178 monomer Substances 0.000 claims 3
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 claims 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims 2
- 150000001993 dienes Chemical class 0.000 claims 2
- 230000001737 promoting effect Effects 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims 1
- JUCOAQCRUJCBPL-BTJKTKAUSA-N (z)-but-2-enedioic acid;2-methylidenebutanedioic acid Chemical compound OC(=O)\C=C/C(O)=O.OC(=O)CC(=C)C(O)=O JUCOAQCRUJCBPL-BTJKTKAUSA-N 0.000 claims 1
- UKDKWYQGLUUPBF-UHFFFAOYSA-N 1-ethenoxyhexadecane Chemical class CCCCCCCCCCCCCCCCOC=C UKDKWYQGLUUPBF-UHFFFAOYSA-N 0.000 claims 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 claims 1
- COCLLEMEIJQBAG-UHFFFAOYSA-N 8-methylnonyl 2-methylprop-2-enoate Chemical compound CC(C)CCCCCCCOC(=O)C(C)=C COCLLEMEIJQBAG-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims 1
- 239000012736 aqueous medium Substances 0.000 claims 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 239000001530 fumaric acid Substances 0.000 claims 1
- 230000002209 hydrophobic effect Effects 0.000 claims 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 150000007524 organic acids Chemical class 0.000 claims 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 claims 1
- 239000007870 radical polymerization initiator Substances 0.000 claims 1
- 238000010526 radical polymerization reaction Methods 0.000 claims 1
- 239000000376 reactant Substances 0.000 claims 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
Claims (4)
- 약 2내지 약 7의 pH범위를 갖는 수용성 매질에서 혼합물 조성이 개시제와 단위체의 100중량%를 기준하여
- (A) 약 0.1내지 약 2중량%의 적어도 1개의 유리기 중합개시제, 아크릴로니트릴, 비닐톨루엔, 메틸 메타크릴레이트, 염화비닐과 비닐리덴 클로라이드로 부터 선정한 적어도 1개의 경화편 (Hard Segment)소수성 촉진 단위체,
- (C) 약 0내지 약 35%의 메틸 아크릴레이트, 에틸아크릴레이트, 부틸아크릴레이트, 2-에틸헥실아크릴레이트, 라우릴아크릴레이트, 이소데실메타크릴레이트, 부틸메타크릴레이트, 이소부틸메타크릴레이트, 하이드록시에틸아크릴레이트, 하이드록시에틸메타크릴레이트로 부터 선정된 적어도 1개의 아크릴레이트 아니면 에틸, 부틸, 옥틸, 데실 및 세틸 비닐에테르로부터 선정한 적어도 1개의 비닐에테르 아니면 1,3-부타디엔, 이소프렌 및 2,3-디메틸부타디엔으로부터 선정한 적어도 1개의 디엔중에서 선정한, 적어도 1개의 연성편(Soft Segment)소수성 촉진단위체 [단(C)단위체중의 디엔류와 (B)단위체중의 염화비닐 및 비닐리덴 클로라이드가 함께 혼합되거나 공중합되지 않는다]와 (D)약 0.25내지 5.0중량%의 아크릴산, 메타크릴산, 푸마르산, 이타콘산 말레산으로 부터 선정된 적어도 1개의 친수성 촉진 유기산등으로 구성된 혼합물을 유리기 중합시키는 제법으로서, 이때 (1) 반응 용기에 약 50내지 약 200중량부의 물과 약 40내지 약 60%의 개시제를 충진한 후 동 반응물을 약 75℃내지 약 95℃의 온도로 조정하고 (2)여기에 천천히, 거의 동시에 100중량부의 단위체 (B,C 와 D),잔유 개시제와 이 개시제의 전달체로서의 미량의 물을 가하고 또 반응온도를 약 75℃ 내지 약 95℃로 유지시키는 일련의 반응 단계를 특징으로 하여 약 100℃ 범위의 연화점을 갖는 수지를 제조하는 방법.
- ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US4038979A | 1979-05-18 | 1979-05-18 | |
| US40,389 | 1979-05-18 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR830002811A true KR830002811A (ko) | 1983-05-30 |
| KR840000213B1 KR840000213B1 (ko) | 1984-02-29 |
Family
ID=21910720
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019800001929A Expired KR840000213B1 (ko) | 1979-05-18 | 1980-05-16 | 수지의 제조방법 |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS55155006A (ko) |
| KR (1) | KR840000213B1 (ko) |
| BR (1) | BR8002914A (ko) |
| CA (1) | CA1138596A (ko) |
| DE (1) | DE3018558A1 (ko) |
| FR (1) | FR2456750A1 (ko) |
| GB (1) | GB2049712B (ko) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100427706B1 (ko) * | 1995-12-30 | 2004-07-16 | 고려화학 주식회사 | 아크릴수지의제조방법,이로부터얻어진아크릴수지및이를주재로한자동차상도용도료 |
| KR100489993B1 (ko) * | 2001-11-26 | 2005-05-17 | 건설화학공업주식회사 | 거푸집용 수용성 아크릴수지 도료의 조성 및 그 제조 방법 |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2127919A1 (en) * | 1993-09-03 | 1995-03-04 | Jessie Alvin Binkley | Process for producing ultrafine sized latexes |
| DE4446539A1 (de) * | 1994-12-24 | 1996-06-27 | Hoechst Ag | Verfahren zur Herstellung von Kunststoffdispersionen |
| DE19911623A1 (de) * | 1999-03-16 | 2000-09-28 | Polymar Gmbh | Verfahren zur Herstellung bei Raumtemperatur fester Konzentrate und Konzentrat für wäßrige Dispersionslacke, -farben oder Coatings sowie Verfahren zur Herstellung wäßriger Dispersionslacke, -farben oder Coatings aus dem Konzentrat |
| DE19928933A1 (de) | 1999-06-24 | 2000-12-28 | Wacker Polymer Systems Gmbh | Verfahren zur Herstellung von Polyvinylalkohol-stabilisierten Polymerisaten |
| US7178227B2 (en) | 2002-09-24 | 2007-02-20 | Ford Motor Company | Workpiece presenter for a flexible manufacturing system |
| US6899377B2 (en) | 2002-09-24 | 2005-05-31 | Ford Motor Company | Vehicle body |
| US8046895B2 (en) | 2008-01-21 | 2011-11-01 | Ford Motor Company | System and method for assembling a vehicle body structure |
| CN103864981B (zh) * | 2014-02-26 | 2016-01-13 | 佛山市功能高分子材料与精细化学品专业中心 | 一种高分子陶瓷添加剂及其制备方法和应用 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50115294A (ko) * | 1974-02-27 | 1975-09-09 |
-
1980
- 1980-03-26 CA CA000348409A patent/CA1138596A/en not_active Expired
- 1980-04-29 GB GB8014008A patent/GB2049712B/en not_active Expired
- 1980-05-12 BR BR8002914A patent/BR8002914A/pt not_active IP Right Cessation
- 1980-05-14 DE DE19803018558 patent/DE3018558A1/de active Granted
- 1980-05-16 KR KR1019800001929A patent/KR840000213B1/ko not_active Expired
- 1980-05-19 FR FR8011092A patent/FR2456750A1/fr active Granted
- 1980-05-19 JP JP6634380A patent/JPS55155006A/ja active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100427706B1 (ko) * | 1995-12-30 | 2004-07-16 | 고려화학 주식회사 | 아크릴수지의제조방법,이로부터얻어진아크릴수지및이를주재로한자동차상도용도료 |
| KR100489993B1 (ko) * | 2001-11-26 | 2005-05-17 | 건설화학공업주식회사 | 거푸집용 수용성 아크릴수지 도료의 조성 및 그 제조 방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2456750B1 (ko) | 1983-06-10 |
| FR2456750A1 (fr) | 1980-12-12 |
| BR8002914A (pt) | 1980-12-23 |
| KR840000213B1 (ko) | 1984-02-29 |
| DE3018558C2 (ko) | 1989-06-08 |
| CA1138596A (en) | 1982-12-28 |
| DE3018558A1 (de) | 1980-11-27 |
| JPS6318602B2 (ko) | 1988-04-19 |
| GB2049712A (en) | 1980-12-31 |
| GB2049712B (en) | 1983-08-03 |
| JPS55155006A (en) | 1980-12-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0109 | Patent application |
Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19800516 |
|
| PG1501 | Laying open of application | ||
| PG1605 | Publication of application before grant of patent |
Comment text: Decision on Publication of Application Patent event code: PG16051S01I Patent event date: 19840207 |
|
| PE0701 | Decision of registration |
Patent event code: PE07011S01D Comment text: Decision to Grant Registration Patent event date: 19840514 |
|
| PR0701 | Registration of establishment |
Comment text: Registration of Establishment Patent event date: 19840604 Patent event code: PR07011E01D |
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| PR1002 | Payment of registration fee |
Payment date: 19840604 End annual number: 3 Start annual number: 1 |
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| PR1001 | Payment of annual fee |
Payment date: 19870108 Start annual number: 4 End annual number: 4 |
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| PR1001 | Payment of annual fee |
Payment date: 19871229 Start annual number: 5 End annual number: 5 |
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| PR1001 | Payment of annual fee |
Payment date: 19890116 Start annual number: 6 End annual number: 6 |
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| PR1001 | Payment of annual fee |
Payment date: 19900111 Start annual number: 7 End annual number: 7 |
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| PR1001 | Payment of annual fee |
Payment date: 19910116 Start annual number: 8 End annual number: 8 |
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| PR1001 | Payment of annual fee |
Payment date: 19920122 Start annual number: 9 End annual number: 9 |
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| PR1001 | Payment of annual fee |
Payment date: 19930111 Start annual number: 10 End annual number: 10 |
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| PR1001 | Payment of annual fee |
Payment date: 19940113 Start annual number: 11 End annual number: 11 |
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| PR1001 | Payment of annual fee |
Payment date: 19941231 Start annual number: 12 End annual number: 12 |
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| PC1801 | Expiration of term |