KR880014003A - 알파, 베타-에틸렌형 불포화산과 에폭시 화합물을 중합함으로써 제조된 중합체 - Google Patents

알파, 베타-에틸렌형 불포화산과 에폭시 화합물을 중합함으로써 제조된 중합체 Download PDF

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Publication number
KR880014003A
KR880014003A KR1019880005366A KR880005366A KR880014003A KR 880014003 A KR880014003 A KR 880014003A KR 1019880005366 A KR1019880005366 A KR 1019880005366A KR 880005366 A KR880005366 A KR 880005366A KR 880014003 A KR880014003 A KR 880014003A
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KR
South Korea
Prior art keywords
beta
ethylenically unsaturated
carbon atoms
acid
alpha
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KR1019880005366A
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English (en)
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KR960014552B1 (ko
Inventor
쿠마 다스 수리아
포어터 쥬니어 새무얼
하워드 타이거 웨인
Original Assignee
헬렌 에이 패브릭
피이피이지이 인더스트리이즈 인코포레이팃드
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/26—Esters containing oxygen in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/04—Acids, Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups

Abstract

내용 없음

Description

알파, 베타-에틸렌형 불포화산과 에폭시 화합물을 중합함으로써 제조된 중합체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 자유라디칼 개시제와 임의로 연쇄 전달제의 존재하에서, 하기(A) 및 (B)의 반응성 성분을 가열하는 것을 포함하는 히드록실-함유 중합체를 제조하는 방법 : (A) 중합 가능한 알파, 베타-에틸렌형 불포화 카르복실산, 및 (B) (A) 와 중합될 수 없는 적어도 5개의 탄소 원자를 함유하는 에폭시 화합물.
    (여기에서 (A)와 (B)는 반응성 성분의 적어도 80중량%까지의 양이며, (A)내 산대 (B)내 에폭시의 당량비는 적어도 1 : 1이다.)
  2. 제 1 항에 있어서, 중합 가능한 알파, 베타-에틸렌형 불포화 카르복실산이 아크릴산, 메타크릴산, 이타콘산 또는 이들의 혼합물인 방법.
  3. 제 1 항에 있어서, 에폭시 화합물이 8 내지 30개의 탄소원자를 함유하는 카르복실산의 글리시딜 에스테르인 방법.
  4. 제 1 항에 있어서, 글리시딜 에스테르가 하기 일반 구조식의 에스테르인 방법 :
    상기식에서 R은 4 내지 26개의 탄소원자를 갖는 3차 지방족 탄화수소기이다.
  5. 제 4 항에 있어서, R이 8 내지 10개의 탄소원자를 함유하는 방법.
  6. 제 1 항 내지 제 5 항 중 어는 한 항에서 있어서, 반응성 성분이 알킬기 내에 1 내지 12개의 탄소 원자를 함유하는 알파, 베타-에틸렌형 불포화 모노카르복실산의 알킬에스테르 또는 히드록시 알킬기내에 2 내지 3개의 탄소원자를 함유하는 에틸렌형 불포화 모노카르복실산의 히드록시알킬 에스테르인 공중합가능한 알파, 베타-에틸렌형 불포화 단량체 하나 이상을 포함하는 방법.
  7. 제 6 항에 있어서, 다른 공중합가능한 알파, 베타-에틸렌형 불포화 단량체 또는 단량체들이 반응성 성분의 15중량% 미만의 양으로 존재하는 방법.
  8. 제 1 항에 있어서, 결과의 중합체가 적어도 130의 히드록실 수를 갖는 방법.
  9. 제 1 항에 있어서, 결과의 중합체가 적어도 15,000의 미만의 평균 분자량을 갖는 방법.
  10. 제 1 항, 제 8 항 및 제 9 항 중 어느 한 항에 따르는 방법에 의해 제조된 히드록실기-함유 중합체와 중합체내 히드록실기와 반응성이 있고 경화 생성물을 형성하기에 충분한 양으로 존재하는 경화제를 포함하는 경화성 코우팅 조성물.
  11. 제10항에 있어서, 경화제가 아미노플라스트인 조성물.
  12. 제10항에 있어서, 경화제가 폴리이소시아네이트인 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880005366A 1987-05-13 1988-05-07 알파,베타-에틸렌형 불포화 산과 에폭시 화합물을 중합하여 히드록실기 함유 중합체를 제조하는 방법 KR960014552B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/049,236 US4818796A (en) 1987-05-13 1987-05-13 Polymers prepared by polymerizing alpha, beta-ethylenically unsaturated acids and epoxy compounds
US049236 1987-05-13
US049,236 1987-05-13

Publications (2)

Publication Number Publication Date
KR880014003A true KR880014003A (ko) 1988-12-22
KR960014552B1 KR960014552B1 (ko) 1996-10-16

Family

ID=21958761

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019880005366A KR960014552B1 (ko) 1987-05-13 1988-05-07 알파,베타-에틸렌형 불포화 산과 에폭시 화합물을 중합하여 히드록실기 함유 중합체를 제조하는 방법

Country Status (6)

Country Link
US (1) US4818796A (ko)
EP (1) EP0295784A3 (ko)
JP (2) JPH07103188B2 (ko)
KR (1) KR960014552B1 (ko)
CA (1) CA1335922C (ko)
MX (1) MX169111B (ko)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4818796A (en) * 1987-05-13 1989-04-04 Ppg Industries, Inc. Polymers prepared by polymerizing alpha, beta-ethylenically unsaturated acids and epoxy compounds
FR2644467B1 (fr) * 1989-03-16 1991-07-12 Hoechst Ag Polymere hydrophile a base d'acide acrylique et d'acrylate de metal alcalin, son procede de preparation et son application comme agent absorbant, en particulier comme agent absorbant pour articles d'hygiene
EP0408858B1 (en) * 1989-05-19 1993-12-15 BASF Corporation Copolymers for use in high solids, low volatile organic content coatings
US5068288A (en) * 1990-05-31 1991-11-26 Ppg Industries, Inc. Acid etch resistant clear coats
US5106651A (en) * 1991-02-21 1992-04-21 Ppg Industries, Inc. Method for improving resistance to water spotting and acid etching of coatings by exposure to UV radiation
US5773513A (en) * 1996-04-04 1998-06-30 E. I. Du Pont De Nemours And Company Hydroxy functional acrylic polymer prepared via skew feed polymerization
US6136443A (en) * 1997-07-11 2000-10-24 Ppg Industries Ohio, Inc. Acid etch resistant film-forming compositions and composite coating compositions
AU2833701A (en) * 1999-09-30 2001-05-10 Shell Internationale Research Maatschappij B.V. Adducts of glycidylesters of alpha, alpha-branched carboxylic acids and carboxylic acids and poly(ortho ester) as intermediate for their preparation
US20020156220A1 (en) * 2001-02-20 2002-10-24 Meyer Gerald Wayne High solids acrylic resin
JP3551255B2 (ja) * 2001-03-22 2004-08-04 株式会社椿本チエイン 光センサ
WO2010144787A1 (en) * 2009-06-11 2010-12-16 Pentron Clinical Technologies, Llc Epoxy-containing composition curable by multiple polymerization mechanisms
EP3786242A1 (en) * 2019-08-27 2021-03-03 Nitto Belgium N.V Pressure-sensitive adhesive sheet with improved weatherability

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3256225A (en) * 1962-01-24 1966-06-14 Staley Mfg Co A E Vicinal acryloxy hydroxy long chain fatty compounds and polymers thereof
US3549583A (en) * 1966-12-14 1970-12-22 Nippon Paint Co Ltd Polyurethane liquid containing compositions
US3719619A (en) * 1969-09-08 1973-03-06 Nippon Paint Co Ltd Quick drying coatings containing copolymers having t-aliphatic hydrocarbon groups and t-aliphatic alkyd resins
CH519532A (de) * 1969-12-18 1972-02-29 Reichhold Albert Chemie Ag Verfahren zur Herstellung von löslichen organischen Mischpolymerisaten sowie deren Verwendung als Bindemittelkomponente, insbesondere in Grundierungen und Decklacken für verzinkte Eisenbleche
GB1549059A (en) * 1975-04-10 1979-08-01 Hoechst Ag Copolymer solution of acrylic resin
DE2603259C3 (de) * 1976-01-29 1982-10-21 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung von hydroxylgruppenenthaltenden Mischpolymerisaten
DE2618809C2 (de) * 1976-04-29 1983-06-30 Hoechst Ag, 6230 Frankfurt Verfahren zur Herstellung von in organischen Lösungsmitteln löslichen Copolymerisaten und Verwendung derselben in Reaktionslacken
DE2618810C3 (de) * 1976-04-29 1978-12-07 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung von Überzügen
DE2626900C2 (de) * 1976-06-16 1978-04-13 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung von hydroxylgruppenenthaltenden Mischpolymerisaten
DE2732693C3 (de) * 1977-07-20 1980-04-17 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung von in organischen Lösungsmitteln löslichen hydroxylgruppenhaltigen Copolymerisaten
NL7708218A (nl) * 1977-07-23 1979-01-25 Akzo Nv Vloeibare bekledingssamenstelling met een hoog vaste-stofgehalte op basis van een acrylaat- copolymeer.
DE2942327A1 (de) * 1979-10-19 1981-05-14 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von oh-gruppen enthaltenden copolymerisaten
DE3019959A1 (de) * 1980-05-24 1981-12-03 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von hydroxylgruppenhaltigen copolymerisaten und deren verwendung
FR2555184B1 (fr) * 1983-11-19 1987-02-13 Nippon Paint Co Ltd Resine acrylique du type modifie, sa preparation et composition resineuse de revetement
US4818796A (en) * 1987-05-13 1989-04-04 Ppg Industries, Inc. Polymers prepared by polymerizing alpha, beta-ethylenically unsaturated acids and epoxy compounds

Also Published As

Publication number Publication date
JPS63297405A (ja) 1988-12-05
US4818796A (en) 1989-04-04
EP0295784A2 (en) 1988-12-21
JPH07103188B2 (ja) 1995-11-08
KR960014552B1 (ko) 1996-10-16
JPH0753920A (ja) 1995-02-28
CA1335922C (en) 1995-06-13
EP0295784A3 (en) 1990-06-27
MX169111B (es) 1993-06-22

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