ES471977A1 - Un procedimiento para la preparacion de un copolimero de acrilato - Google Patents
Un procedimiento para la preparacion de un copolimero de acrilatoInfo
- Publication number
- ES471977A1 ES471977A1 ES471977A ES471977A ES471977A1 ES 471977 A1 ES471977 A1 ES 471977A1 ES 471977 A ES471977 A ES 471977A ES 471977 A ES471977 A ES 471977A ES 471977 A1 ES471977 A1 ES 471977A1
- Authority
- ES
- Spain
- Prior art keywords
- acrylate copolymer
- mole
- acid
- preparation
- coating composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/12—Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/14—Esterification
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/30—Chemical modification of a polymer leading to the formation or introduction of aliphatic or alicyclic unsaturated groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
Abstract
Un procedimiento para la preparación de un copolímero de acrilato, por polimerización de una mezcla monómera que consiste en 35-60% en moles de estireno y/o alfa-metil- estireno, 20-60% en moles de ácido acrílico y/o ácido metacrílico y 0-30% en moles de lo más compuestos monovinílicos distintos, a una temperatura de 60º a 200ºC en presencia de un iniciador de radicales, después de lo cual el producto de reacción resultante se hace reaccionar resultante se hace reaccionar con un éster glicidílico de un ácido carboxílico de la fórmula general: **Fórmula** en la que R representa un grupo alcohilo que tiene 4 a 10 átomos de carbono, caracterizado porque la polimerización de los compuestos monómeros se lleva a cabo en presencia de un ácido mercaptomonocarboxílico y/o ácido mercaptodicarboxílico que contienen 2 a 8 átomos de carbono, en calidad de regulador de la longitud de la cadena, en una cantidad de 0,02 a 0,25 moles por cada mol de los compuestos monómeros.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL7708218A NL7708218A (nl) | 1977-07-23 | 1977-07-23 | Vloeibare bekledingssamenstelling met een hoog vaste-stofgehalte op basis van een acrylaat- copolymeer. |
Publications (1)
Publication Number | Publication Date |
---|---|
ES471977A1 true ES471977A1 (es) | 1979-04-01 |
Family
ID=19828927
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES471977A Expired ES471977A1 (es) | 1977-07-23 | 1978-07-22 | Un procedimiento para la preparacion de un copolimero de acrilato |
Country Status (8)
Country | Link |
---|---|
US (1) | US4245074A (es) |
EP (1) | EP0000601B1 (es) |
JP (1) | JPS5423697A (es) |
BR (1) | BR7804713A (es) |
DE (1) | DE2860978D1 (es) |
ES (1) | ES471977A1 (es) |
IT (1) | IT1099019B (es) |
NL (1) | NL7708218A (es) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4414370A (en) * | 1981-01-09 | 1983-11-08 | S. C. Johnson & Son, Inc. | Process for continuous bulk copolymerization of vinyl monomers |
GB2097409B (en) * | 1981-04-28 | 1984-08-15 | Ici Plc | Coating compositions |
US4529787A (en) * | 1982-06-15 | 1985-07-16 | S. C. Johnson & Son, Inc. | Bulk polymerization process for preparing high solids and uniform copolymers |
US4818796A (en) * | 1987-05-13 | 1989-04-04 | Ppg Industries, Inc. | Polymers prepared by polymerizing alpha, beta-ethylenically unsaturated acids and epoxy compounds |
US4988766A (en) * | 1987-05-13 | 1991-01-29 | Ppg Industries, Inc. | Polymers prepared by polymerizing alpha, beta-ethylenically unsaturated acids and epoxy compounds and crosslinked products therefrom |
ATE98663T1 (de) * | 1989-05-19 | 1994-01-15 | Basf Corp | Copolymere zur verwendung fuer beschichtungen mit gering fluechtigen organischen anteilen und hohen feststoffgehalten. |
ATE116343T1 (de) * | 1990-03-06 | 1995-01-15 | Akzo Nobel Nv | Wässrige hybridpolymerdispersion und beschichtungszusammensetzung. |
FR2732620B1 (fr) * | 1995-04-10 | 1997-05-09 | Coatex Sa | Copolymeres utilises comme dispersant ameliorant la resistance a l'eau des films de compositions aqueuses chargees et/ou pigmentees ainsi que les compositions les contenant |
US6136443A (en) | 1997-07-11 | 2000-10-24 | Ppg Industries Ohio, Inc. | Acid etch resistant film-forming compositions and composite coating compositions |
US20020156221A1 (en) * | 2001-02-20 | 2002-10-24 | Meyer Gerald Wayne | High solids acrylic resin |
EP1526145A1 (en) * | 2003-10-24 | 2005-04-27 | Resolution Research Belgium S.A. | Process for the preparation of hydroxy functional polymer and its use in coating compositions |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2878237A (en) * | 1955-06-15 | 1959-03-17 | American Cyanamid Co | Mercapto dibasic acids as regulators for the polymerization of acrylic acids, amidesand salts |
NL260655A (es) * | 1960-02-01 | |||
US3218302A (en) * | 1960-06-08 | 1965-11-16 | Rohm & Haas | Suspension polymerization |
US3312741A (en) | 1963-04-29 | 1967-04-04 | Eastman Kodak Co | 2, 2-dialkyl-3-alkoxy cyclobutanone derivatives |
US3330814A (en) * | 1963-05-27 | 1967-07-11 | Du Pont | Hydroxyl-containing copolymers |
CH519532A (de) * | 1969-12-18 | 1972-02-29 | Reichhold Albert Chemie Ag | Verfahren zur Herstellung von löslichen organischen Mischpolymerisaten sowie deren Verwendung als Bindemittelkomponente, insbesondere in Grundierungen und Decklacken für verzinkte Eisenbleche |
US3960824A (en) * | 1971-07-09 | 1976-06-01 | Celanese Coatings & Specialties Company | Mercaptan initiated polymerization process carried out in the presence of oxygen |
JPS5132466B2 (es) * | 1971-08-09 | 1976-09-13 | ||
US4082818A (en) * | 1976-05-17 | 1978-04-04 | The Standard Oil Company | Mercaptan activation by acid in the copolymerization of acrylonitrile |
-
1977
- 1977-07-23 NL NL7708218A patent/NL7708218A/xx not_active Application Discontinuation
-
1978
- 1978-07-13 EP EP78200096A patent/EP0000601B1/en not_active Expired
- 1978-07-13 DE DE7878200096T patent/DE2860978D1/de not_active Expired
- 1978-07-21 BR BR7804713A patent/BR7804713A/pt unknown
- 1978-07-21 IT IT25994/78A patent/IT1099019B/it active
- 1978-07-21 US US05/926,616 patent/US4245074A/en not_active Expired - Lifetime
- 1978-07-22 ES ES471977A patent/ES471977A1/es not_active Expired
- 1978-07-24 JP JP8951078A patent/JPS5423697A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS5757082B2 (es) | 1982-12-02 |
IT7825994A0 (it) | 1978-07-21 |
US4245074A (en) | 1981-01-13 |
JPS5423697A (en) | 1979-02-22 |
DE2860978D1 (en) | 1981-11-19 |
IT1099019B (it) | 1985-09-18 |
BR7804713A (pt) | 1979-04-03 |
EP0000601A1 (en) | 1979-02-07 |
EP0000601B1 (en) | 1981-08-26 |
NL7708218A (nl) | 1979-01-25 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 19971103 |