KR950704413A - 실란 중합체로 개질된 무수물-에폭시 피복 조성물(an anhydride-epoxy coating composition modified with a silane polymer) - Google Patents

실란 중합체로 개질된 무수물-에폭시 피복 조성물(an anhydride-epoxy coating composition modified with a silane polymer)

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KR950704413A
KR950704413A KR1019950701953A KR19950701953A KR950704413A KR 950704413 A KR950704413 A KR 950704413A KR 1019950701953 A KR1019950701953 A KR 1019950701953A KR 19950701953 A KR19950701953 A KR 19950701953A KR 950704413 A KR950704413 A KR 950704413A
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coating composition
anhydride
alkyl
weight
acid
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KR100235424B1 (ko
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로버트 제이. 바소티
제퍼리 더블유. 존슨
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미리암 디. 메코나헤이
이. 아이. 듀퐁 드 네모아 앤드 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/01—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
    • C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C09D133/064—Copolymers with monomers not covered by C09D133/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/062—Copolymers with monomers not covered by C08L33/06
    • C08L33/064—Copolymers with monomers not covered by C08L33/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/062—Copolymers with monomers not covered by C08L33/06
    • C08L33/068—Copolymers with monomers not covered by C08L33/06 containing glycidyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L43/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Compositions of derivatives of such polymers
    • C08L43/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)

Abstract

필름 형성 결합제가 2개 이상의 반응성 무수물 그룹을 가진 아크릴산 중합체, 에폭시 함유 가교결합체, 및 에폭시-실란 개질제를 포함하는 피복 조성물은 자동차 및 트럭용 표면 처리막으로 유용하다.
상기 조성물은 적당한 수명을 가진 1-패키쥐 시스템으로서 사용할 수 있다. 상기 조성물은 환경 저항성이 개선됨을 특징으로 한다.

Description

실란 중합체로 개질된 무수물-에폭시 피복 조성물(AN ANHYDRIDE-EPOXY COATING COMPOSITION MODIFIED WITH A SILANE POLYMER)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

  1. 20 내지 80중량%의 반응성 결합제 성분 및 80 내지 20중량%의 유기 액체 담체를 포함하고; 이때, 상기 결합제가 그의 중량을 기준으로, (a) 2개 이상의 반응성 무수물 그룹을 가지며, 에틸렌형 불포화 무수물 또는 무수물로 전환되는 에틸렌형 불포화 디카복실산의 중합된 단량체 및 알킬 메타크릴레이트, 알킬 아크릴레이트 및 이들의 혼합물(이때, 상기 알킬 그룹은 1 내지 8개의 탄소 원자를 갖는다)로 이루어진 그룹중에서 선택된 중합된 단량체를 포함하는, 약 2000 내지 50,000의 중량 평균 분자량을 갖는 아크릴산 공중합체 25 내지 90 중량%; (b) 2개 이상의 반응성 글리시딜 그룹을 가진 글리시딜 성분 5 내지 30중량%; (c) 실란 그룹을 가진 중합체 5 내지 30중량%; 및 (d) 효과량의 경화 촉매를 포함하는, 상기 성분 (a), (b) 및 (c)가 상이한 성분인 피복 조성물.
  2. 제1항에 있어서, 상기 글리시딜 성분이 폴리올의 디-또는 폴리글리시딜 에스테르 또는 카복실산의 디- 또는 폴리글리시딜 에스테르를 포함하는 피복 조성물.
  3. 제1항에 있어서, 상기 글리시딜 성분이 저분자량 폴리올의 폴리글리시딜 에스테르, 에피클로로히드린 및 비스페놀 A의 에폭시 수지, 폴리산의 폴리글리시딜 에스테르, 이소시아누레이트외 폴리글리시딜 에테르, 글리시딜 메타크릴레이트 또는 글리시딜 아크릴레이트 함유 아코릴산 중합체 및 상기중 임의의 상용가능한 혼합물로 이루어진 그룹중에서 선택된 피복 조성물.
  4. 제1항에 있어서, 폴리에스테르 우레탄 폴리올을 또한 포함하는 피복 조성물.
  5. 제1항에 있어서, 상기 아크릴산 무수물 중합체가 스티렌, 알킬 메타크릴레이트 또는 알킬 아크릴레이트(이때, 상기 알킬 그룹이 2 내지 4개의 탄소원자를 갖는다) 및 에틸렌령 불포화 무수물 또는 무수물로 전환된 에틸렌형 불포화 디카복실산의 중합된 단량체를 포함하는 피복 조성물.
  6. 제1항에 있어서, 상기 아크릴산 무수물 중합체가 부틸 아크릴레이트, 스티렌 및 무수물로 전환된 아티콘산의 중합된 단량체를 포함하는 피복 조성물.
  7. 제1항에 있어서, 상기 아크릴산 무수물 중합체가 말레산 무수물의 중합된 단위를 포함하는 피복 조성물.
  8. 제1항에 있어서, 알킬 오르쏘아세테이트 안정화제를 또한 포함하는 피복 조성물.
  9. 제4항에 있어서, 상기 폴리에스테르 우레탄이 약 20 내지 120의 하이드록시가 또는 20 내지 120의 산가를 갖는 피복 조성물.
  10. 제1항에 있어서, 알킬 메타크릴레이트 또는 알킨 아크릴레이트 또는 하이드록시 알킬 아크릴레이트 또는 하이드록시 알킬 메타크릴레이트 또는 이들의 혼합물(이때, 상기 알킬 그룹이 1 내지 12개의 탄소원자를 갖는다)의 단량체 및 에틸렌형 불포화 산을 중합시킴으로써 제조된 산 작용성 중합체를 또한 포함하는 피복 조성물.
  11. 제1항에 있어서, 상기 촉매가 포스포늄 화합물인 피복 조성물.
  12. 제1항에 있어서, 알콜 또는 글리콜과 디카복실산의 단량체 무수물의 반응 생성물인 반 에스테르를 또한 포함하는 피복 조성물.
  13. 제12항에 있어서, 상기 반에스테르가 알콜 또는 글리콜과 메틸헥사하이드로프 탈산 무수물의 반응 생성물인 피복 조성물.
  14. 제13항에 있어서, 상기 반 에스테르가 포스포늄 촉매와 무수물 성분의 혼합물을 가용화시키고 안정화시키기에 효과량으로 존재하는 피복 조성물.
  15. 제1항에 있어서, 상기 성분(c)가 하나 이상의 에폭시 작용성 단량체의 중합된 단위로 부터 생성된 에폭시 그룹을 포함하는 피복 조성물.
  16. 제14항에 있어서, 상기 반 에스테르가 약 2몰의 메틸헥사하이드로프탈산 무수물과 약 1몰의 에틸렌 글리콜의 반응 생성물인 피복 조성물.
  17. 제1항에 있어서, 상기 결합제의 중량을 기준으로 약 0. 1 내지 200 중량%의 안료를 함유하는 피복 조성물.
  18. 제1항의 조성물의 경화된 층으로 피복된 기재.
  19. 제17항에 있어서, 상기 기재가 플라스틱 또는 금속인 기재.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950701953A 1992-11-17 1993-11-16 실란 중합체로 개질된 무수물-에폭시 피복 조성물 KR100235424B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US7/977865 1992-11-17
US07/977,865 US5376706A (en) 1992-11-17 1992-11-17 Anhydride epoxy coating composition modified with a silane polymer
US07/977865 1992-11-17
PCT/US1993/010793 WO1994011427A1 (en) 1992-11-17 1993-11-16 An anhydride-epoxy coating composition modified with a silane polymer

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KR950704413A true KR950704413A (ko) 1995-11-20
KR100235424B1 KR100235424B1 (ko) 1999-12-15

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US (1) US5376706A (ko)
EP (1) EP0669955A4 (ko)
JP (1) JP2749017B2 (ko)
KR (1) KR100235424B1 (ko)
CA (1) CA2147826A1 (ko)
WO (1) WO1994011427A1 (ko)

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US11623901B1 (en) 2022-08-31 2023-04-11 Saudi Arabian Oil Company Catalyst systems that include silyl ether moieties
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CA2147826A1 (en) 1994-05-26
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WO1994011427A1 (en) 1994-05-26
JP2749017B2 (ja) 1998-05-13
JPH08503249A (ja) 1996-04-09
KR100235424B1 (ko) 1999-12-15
EP0669955A4 (en) 1996-08-07

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