KR900014543A - 불소계 수지 조성물, 경화성 조성물 및 도료 조성물 - Google Patents

불소계 수지 조성물, 경화성 조성물 및 도료 조성물 Download PDF

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KR900014543A
KR900014543A KR1019900002673A KR900002673A KR900014543A KR 900014543 A KR900014543 A KR 900014543A KR 1019900002673 A KR1019900002673 A KR 1019900002673A KR 900002673 A KR900002673 A KR 900002673A KR 900014543 A KR900014543 A KR 900014543A
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monomer
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KR940009864B1 (ko
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아끼마사 나까하따
노부시게 누마
마사히로 야마네
오사무 이소자끼
노보루 나까이
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다나까 마스오
간사이뻬인또 가부시끼가이샤
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/30—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen
    • C08G59/306—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/70—Chelates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L43/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Compositions of derivatives of such polymers
    • C08L43/04—Homopolymers or copolymers of monomers containing silicon

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Paints Or Removers (AREA)
  • Epoxy Resins (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음

Description

불소계 수지 조성물, 경화성 조성물 및 도료 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. (a) 분자 중에 (ⅰ) 규소원자에 직접 결합된 가수분해성기 및/또는 실란올기 및 (ⅱ) 에폭시기를 갖는 불소계 수지, 또는 (b) 규소원자에 직접 결합된 가수분해성기 및/또는 실란올기를 갖는 성분(Ⅰ) 및 에폭시기를 갖는 성분 (Ⅱ)의 혼합물(성분 (Ⅰ) 및 (Ⅱ)중 적어도 하나는 불소계 수지이다)을 함유함을 특징으로 하는 불소계 수지 조성물.
  2. 제1항에 있어서, 조성물이 a) 규소원자에 직접 결합된 가수분해성기 및/또는 실란올기 및 에폭시기를 갖는 불소계 수지, b) 규소원자에 직접 결합된 가수분해성기 및/또는 실란올기를 갖는 불소계 수지와 에폭시기를 갖는 불소계 수지와의 혼합물, c) 규소원자에 직접 결합된 가수분해성기 및/또는 실란올기를 갖는 불소계 수지와 에폭시기를 갖는 불소-미함유 수지 또는 화합물과의 혼합물, 또는 d) 에폭시기를 갖는 불소계 수지와 규소원자에 직접 결합된 가수분해성기 및/또는 실란올기를 갖는 불소-미함유 수지 또는 화합물과의 혼합물을 함유하는 조성물.
  3. 제1항에 있어서, 조성물이 (1) 작용기를 갖는 불소계 수지(A), 에폭시기 및 화합물(A)의 작용기와 상보 반응성인 작용기를 갖는 화합물(B), 및 실란기 및 화합물(A)의 작용기와 상보 반응성인 작용기를 갖는 화합물(C)를 반응시켜 제조한 반응 생성물(D) ; (2) 작용기를 갖는 수지(E)와 수지(E)의 작용기와 상보 반응성인 작용기 및 에폭시기를 갖는 화합물(B)의 반응생성물인 생성물(F), 및 작용기를 갖는 수지(G)와 수지(G)의 작용기와 상보 반응성인 작용기 및 실란기를 갖는 화합물(C)의 반응 생성물인 생성물(H)의 혼합물(I) (생성물(F) 및/또는 생성물(H)는 불소계 수지이다); (3) 단량체 성분으로서 에폭시-함유 중합성 불포화 단량체 (J), 실란-함유 중합성 불포화 단량체 (K), 불소-함유 중합성 불포화 단량체(V), 실란-함유 중합성 불포화 단량체(K) 및 불소-함유 중합성 불포화 단량체(b) 및 필요하다면 기타 중합성 불포화 단량체(M)을 함유한 공중 합체(L); (4) 단량체(J)의 단일 중합체 또는 단량체(J)와 기타 중합성 불포화 단량체(M)의 공중합체인 중합체(N), 및 단량체(K)의 단일 중합체 또는 단량체(K)와 중합성 불포화 단량체(M)의 공중합체인 중합체(P)의 혼합물 (중합체 (N) 및/또는 중합체(P)는 불소계 중합체이다); (5) 단량체 성분으로 작용기를 갖는 중합성 불포화 단량체(Q), 에폭시-함유 중합성 불포화 단량체(J) 및 불소-함유 중합성 불포화 단량체 (b)를 함유하는 공중합체(R)와, 단량체(Q)로부터 유도된 작용기와 상보 반응성인 작용기 및 실란기를 갖는 화합물(S)의 반응생성물(T); (6) 단량체 성분으로 작용기를 갖는 중합성 불포화 단량체(b)을 함유하는 공중합체(V)와, 단량체(U)로부터 유도된 작용기와 상보 반응성인 작용기 및 에폭시기를 갖는 화합물(W)의 반응 생성물(X); (7) 중합체(N) 및 반응 생성물(H)의 혼합물(Y) (중합체 (N) 및/또는 반응 생성물(H)는 불소를 함유한다); (8) 중합체(P) 및 반응 생성물(F)의 혼합물(Z) (중합체 (P) 및/또는 반응 생성물(F)는 불소를 함유한다); (9) 실란-함유 불소계 수지 및 분자당 평균 2개 이상의 에폭시기를 갖는 화합물의 혼합물; 또는 (10) 에폭시-함유 불소계 수지 및 분자당 평균 2개 이상의 실란기를 갖는 화합물을 함유하는 조성물.
  4. 제1항에 있어서, 조성물이 불소계 수지의 단량체 성분으로 비휘발성 함량을 기준으로 약 1~약70중량%의 불소-함유 중합성 불포화 단량체(b)를 함유하는 조성물.
  5. 제4항에 있어서, 단량체(b)가 하기 일반식 (Ⅰ) 표시되거나 하기 일반식 (Ⅱ)로 표시되는 것인 조성물.
    [상기 식중, X기들은 동일하거나 상이할 수 있으며 각각은 H, Cl, Br, F, 알킬기 또는 할로알킬기를 나타내며, (단, 분자중에 불소원자가 하나이상 존재한다) Z는 수소원자 또는 메틸기이고, R2은 플루오로알킬기이며, n은 1~10의 정수이다.]
  6. 제1항에 있어서, 불소계 수지가 약 1,000~약 200,000의 수평균 분자량을 갖는 조성물.
  7. 제1~6항중 어느 한 항에서 정의된 수지 조성물 및 금속 킬레이트 화합물을 경화성 조성물.
  8. 필수 성분으로서 제1항 및 제7항 중 어느 한 항에서 정의된 조성물을 함유하는 도료 조성물.
  9. 제7항 또는 제8항에 있어서, 금속 킬레이트 화합물이 알루미늄 킬레이트 화합물, 티타늄 킬레이트 화합물 및 지르코늄 킬레이트 화합물로 구성된 군 중에서 선택된 하나이상의 화합물인 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900002673A 1989-03-02 1990-02-28 불소계 수지 조성물, 경화성 조성물 및 도료 조성물 KR940009864B1 (ko)

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Application Number Priority Date Filing Date Title
JP1-50587 1989-03-02
JP1050587A JPH02228351A (ja) 1989-03-02 1989-03-02 樹脂組成物、硬化性組成物及び塗料組成物
JP50587 1989-03-02

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KR900014543A true KR900014543A (ko) 1990-10-24
KR940009864B1 KR940009864B1 (ko) 1994-10-18

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US (1) US5387646A (ko)
JP (1) JPH02228351A (ko)
KR (1) KR940009864B1 (ko)
CA (1) CA2011356C (ko)
DE (1) DE4006439C2 (ko)
GB (1) GB2229730B (ko)

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GB2229730B (en) 1993-07-07
DE4006439C2 (de) 1994-11-03
JPH02228351A (ja) 1990-09-11
GB2229730A (en) 1990-10-03
KR940009864B1 (ko) 1994-10-18
DE4006439A1 (de) 1990-09-13
GB9004102D0 (en) 1990-04-18
US5387646A (en) 1995-02-07
CA2011356A1 (en) 1990-09-02
CA2011356C (en) 1997-11-11

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