KR890017316A - 광 섬유 피복용 자외선 경화형 실리콘 수지 조성물 - Google Patents
광 섬유 피복용 자외선 경화형 실리콘 수지 조성물 Download PDFInfo
- Publication number
- KR890017316A KR890017316A KR1019890006338A KR890006338A KR890017316A KR 890017316 A KR890017316 A KR 890017316A KR 1019890006338 A KR1019890006338 A KR 1019890006338A KR 890006338 A KR890006338 A KR 890006338A KR 890017316 A KR890017316 A KR 890017316A
- Authority
- KR
- South Korea
- Prior art keywords
- sio
- component
- optical fiber
- resin composition
- silicone resin
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/104—Coating to obtain optical fibres
- C03C25/106—Single coatings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- General Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (6)
- (A)평균조성식(식중 R1은 비닐기를 제외한 치환 또는 비치환 1가의 탄화 수소기를 나타내고, a는 0.01a1, b는 0.8b3, (a+b)는 1.8a±b2.2의 범위이다.)로 표시되고, 25℃에 있어서의 점도가 50-10,000cP 범위의 유동성 비닐기를 함유하는 폴리오르가노실록산 100중량부, (B)R3 2SiO0.5단위, (CH2=CH)CR2-C 3SiO 단위(식중 R2및 R3는 R1과 같이 치환 또는 비치환의 1가의 탄화 수소기, C는 0, 1 또는 2이다) 및 SiO2단위로 구성되어 (CH2=CH)cR2-c 3SiO 단위에 대한 R3 2SiO0.5단위와 SiO2단위와의 합의 몰비가 3-20의 범위이고, 비닐기의 함유량이 1-25몰%인 비닐기를 함유하는 폴리오르가노 실록산 수지 30-300 중량부. (C) R3 2SiO0.5단위 Rd 4(HSR5)SiO단위 및 R2-e 6Re 7SiO 단위(식중 R2, R4, R6, R7은 R1과 같은 치환 또는 비치환의 1가의 탄화수소기, R5는 탄소수 2-6개의 2가의 탄화수소기, d는 0, 1또는 2, e는 0, 1또는 2이다.)로 구성되어 R2-e 6Re 7SiO단위에 대한 R3 2SiO0.5단위와 Rd 4(HSR5)SiO단위와의 합의 몰비가 0.05-0.5의 범위이고 SH기 함유량이 4-30몰%인 머 캡토 알킬기를 함유하는 폴리 오르가노 실록산 10-100중량부 (D) 광 개시제 0.01-50중량부 (E) 중합 금지제 0.001-10중량부 (F) 산화방지제 0.001-10중량부 및 (G)자외선 흡수제 0.001-10중량부로 구성되고 (C)성분중의 머 캡토 알킬기와 (A)성분과 (B)성분중의 비닐기의 합과의 몰비가 0.2-2.5로 되도록 조절해서 이루어지는 것을 특징으로 하는 광 섬유 피복용 자외선 경화형 실리콘 수지 조성물.
- 제 1 항에 있어서, (A)성분중의 1가 탄화수소기의 총수의 1-10%가 페닐기 인 것을 특징으로 하는 광섬유피복용 자외선 경화형 실리콘 수지 조성물.
- 제 1 항에 있어서, (D)성분의 광 개시제가 2-하이드록시-2-메틸-1-페닐 프로판-1-온 인것을 특징으로 하는광 섬유 피복용 자외선 경화형 실리콘 수지 조성물.
- 제 1 항에 있어서, (F)성분의 산화 방지제가 테트라기스-[메틸렌-3-(3′,5′,-디-t-부틸-4′-하이드록시페닐)프로피오 네이트]메탈인 것을 특징으로 하는 광섬유 피복용 자외선 경화형 실리콘 수지 조성물.
- 제 1 항에 있어서, (G)성분이 벤조 페논계 자외선 흡수제인 것을 특징으로 하는 광섬유 피복용 자외선 경화형 실리콘 수지 조성물.
- 제 1 항에 있어서, (G)성분이 벤조 트리아졸계 자외선 흡수제인 것을 특징으로하는 광 섬유 피복용 자외선경화형 실리콘 수지 조성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63-115493 | 1988-05-12 | ||
JP63115493A JP2620303B2 (ja) | 1988-05-12 | 1988-05-12 | 光ファイバー被覆用紫外線硬化型シリコーン樹脂組成物 |
JP115493 | 1988-05-12 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR890017316A true KR890017316A (ko) | 1989-12-15 |
KR920004198B1 KR920004198B1 (ko) | 1992-05-30 |
Family
ID=14663878
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019890006338A KR920004198B1 (ko) | 1988-05-12 | 1989-05-11 | 광섬유 피복용 자외선 경화형 실리콘 수지조성물 |
Country Status (3)
Country | Link |
---|---|
US (1) | US4935455A (ko) |
JP (1) | JP2620303B2 (ko) |
KR (1) | KR920004198B1 (ko) |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5073583A (en) * | 1988-06-06 | 1991-12-17 | Dow Corning Corporation | Organosiloxane elastomers exhibiting improved physical properties |
US5100993A (en) * | 1989-01-27 | 1992-03-31 | Shin-Etsu Chemical Co., Ltd. | UV curable compositions of organopolysiloxane containing mercaptoalkyl and phenylene groups |
US5632057A (en) * | 1989-09-20 | 1997-05-27 | Lyden; Robert M. | Method of making light cure component for articles of footwear |
JPH04198270A (ja) * | 1990-11-27 | 1992-07-17 | Toshiba Silicone Co Ltd | 光硬化型シリコーン組成物及びその接着剤組成物 |
US5459175A (en) * | 1990-11-28 | 1995-10-17 | Loctite Corporation | Optical fiber primary coatings and fibers coated therewith |
US5371181A (en) * | 1990-11-28 | 1994-12-06 | Loctite Corporation | Thiol-ene compositions with improved cure speed retention |
EP0492830B1 (en) * | 1990-12-28 | 1996-07-17 | Dow Corning Corporation | Method of indicating a cure point for ultraviolet radiation curing compositions by color change |
DE4120418A1 (de) * | 1991-06-20 | 1992-12-24 | Wacker Chemie Gmbh | Haertbare organo(poly)siloxanmassen |
US5177142A (en) * | 1991-08-22 | 1993-01-05 | General Electric Company | Silicone release coating compositions |
US5214734A (en) * | 1992-03-24 | 1993-05-25 | At&T Bell Laboratories | Optical fiber with improved moisture resistance |
US5670255A (en) * | 1995-01-23 | 1997-09-23 | Ppg Industries, Inc. | Antioxidant compositions for coating substrates, substrates coated with the same and methods for inhibiting the oxidation of such compositions applied to a substrate |
US6939502B2 (en) * | 1995-08-02 | 2005-09-06 | Robert M. Lyden | Method of making custom insoles and point of purchase display |
JP3417230B2 (ja) * | 1996-09-25 | 2003-06-16 | 信越化学工業株式会社 | 型取り母型用光硬化性液状シリコーンゴム組成物 |
WO1998057902A1 (en) * | 1997-06-18 | 1998-12-23 | Dsm N.V. | Radiation-curable optical fiber coatings having reduced yellowing and fast cure speed |
DE50013562D1 (de) * | 2000-06-20 | 2006-11-16 | Abb Research Ltd | Vergussmassen für die Herstellung von elektrischen Isolierungen |
EP1757979B1 (en) * | 2005-08-26 | 2012-12-12 | Cmet Inc. | Rapid prototyping resin compositions |
US8293810B2 (en) * | 2005-08-29 | 2012-10-23 | Cmet Inc. | Rapid prototyping resin compositions |
CN102869727B (zh) * | 2010-04-26 | 2014-10-08 | 三键精密化学有限公司 | 光固化性硅凝胶组合物及其用途 |
PT2657301E (pt) * | 2010-12-22 | 2015-03-25 | Momentive Performance Mat Jp | Composição de resina de silicone curável por radiação ultravioleta e dispositivo de exibição de imagem utilizando a mesma |
CN103180394B (zh) | 2010-12-22 | 2015-04-08 | 迈图高新材料日本合同公司 | 热固化型聚有机硅氧烷组合物及其使用 |
JP5587520B1 (ja) * | 2013-05-08 | 2014-09-10 | モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社 | 画像表示装置用のダム材組成物、及びそれを用いた画像表示装置 |
JP5587519B1 (ja) * | 2013-05-08 | 2014-09-10 | モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社 | 画像表示装置用のダム材組成物、及びそれを用いた画像表示装置 |
US9834679B2 (en) * | 2014-08-01 | 2017-12-05 | Momentive Performance Materials Inc. | Thermally stable, high refractive index curable silicone compositions |
WO2016101129A1 (en) * | 2014-12-23 | 2016-06-30 | Henkel (China) Company Limited | 1k high temperature debondable adhesive |
US9442264B1 (en) | 2014-12-23 | 2016-09-13 | Superior Essex International LP | Tight buffered optical fibers and optical fiber cables |
EP3249016A4 (en) * | 2015-01-22 | 2018-06-20 | Dow Corning Toray Co., Ltd. | Curable organopolysiloxane composition, cured product thereof, and cured film formation method |
WO2017155919A1 (en) * | 2016-03-07 | 2017-09-14 | Dow Corning Corporation | Photocurable silicone composition and cured product thereof |
CN110494498A (zh) * | 2017-04-13 | 2019-11-22 | 信越化学工业株式会社 | 剥离性放射线固化性有机硅组合物和剥离片 |
US10031303B1 (en) | 2017-08-29 | 2018-07-24 | Superior Essex International LP | Methods for forming tight buffered optical fibers using compression to facilitate subsequent loosening |
JP7152113B2 (ja) * | 2018-02-05 | 2022-10-12 | スリーエム イノベイティブ プロパティズ カンパニー | メルカプト官能性ポリオルガノシロキサンを含有する積層造形技術のための放射線硬化性組成物 |
WO2020072269A1 (en) | 2018-10-01 | 2020-04-09 | Dow Toray Co., Ltd. | Organosilicon compound, method for producing thereof, and use thereof |
CN110183665B (zh) * | 2019-05-28 | 2022-01-14 | 安庆北化大科技园有限公司 | 一种含巯基mtq树脂的制备方法及其应用 |
EP4150385A1 (en) | 2020-05-13 | 2023-03-22 | Haute Ecole Arc | Optical waveguide and method of fabrication thereof |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3816282A (en) * | 1971-04-15 | 1974-06-11 | Gen Electric | Radiation induced polymerization of polysiloxanes |
JPS5935044A (ja) * | 1982-08-18 | 1984-02-25 | Shin Etsu Chem Co Ltd | 光通信フアイバ−用被覆剤 |
JPS59206465A (ja) * | 1983-05-10 | 1984-11-22 | Shin Etsu Chem Co Ltd | 放射線硬化性オルガノポリシロキサン組成物 |
US4608312A (en) * | 1983-08-26 | 1986-08-26 | General Electric Company | Ultraviolet radiation curable silicone release compositions |
CA1236248A (en) * | 1983-10-26 | 1988-05-03 | Dow Corning Corporation | Fast ultraviolet radiation curing silicone composition |
JPS60191039A (ja) * | 1984-03-07 | 1985-09-28 | Shin Etsu Chem Co Ltd | 光フアイバ−用被覆材 |
US4611042A (en) * | 1985-10-03 | 1986-09-09 | Dow Corning Corporation | Resinous copolymeric siloxanes containing alkenyldimethylsiloxanes |
-
1988
- 1988-05-12 JP JP63115493A patent/JP2620303B2/ja not_active Expired - Lifetime
-
1989
- 1989-05-10 US US07/349,674 patent/US4935455A/en not_active Expired - Fee Related
- 1989-05-11 KR KR1019890006338A patent/KR920004198B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
JP2620303B2 (ja) | 1997-06-11 |
KR920004198B1 (ko) | 1992-05-30 |
US4935455A (en) | 1990-06-19 |
JPH01286939A (ja) | 1989-11-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR890017316A (ko) | 광 섬유 피복용 자외선 경화형 실리콘 수지 조성물 | |
KR900001759A (ko) | 탈착 코딩용 실리콘 조성물 | |
KR840008672A (ko) | 액체 오가노실록산 수지조성물 | |
US4780486A (en) | Fast ultraviolet radiation curing silicone composition | |
KR830004353A (ko) | 메르캅토오르가노 폴리실록산 및 이를 함유한 경화성 조성물 | |
KR950011553A (ko) | 저점성 경화성 오가노실록산 조성물 | |
BR0210737A (pt) | Composição de organopolissiloxano curável a temperatura ambiente | |
KR900004899A (ko) | 실리콘 실란트의 모듈러스 조절 방법 | |
EP1780242A3 (en) | Resin composition for sealing optical device and method of sealing semiconductor element | |
GB1433461A (en) | Release characteristics of substrates | |
GB1131483A (en) | Improvements in low temperature organopolysiloxane vulcanizing composition and article made therefrom | |
TW200738828A (en) | Curable silicone rubber compositions and cured products thereof | |
ES2087785T3 (es) | Composiciones de siloxano reticulable y revestimientos anti-adhesivos. | |
KR970061930A (ko) | 활성 에너지선-경화성 수지 조성물 | |
KR910000938A (ko) | 무취(無臭)인 uv 경화성 오르가노폴리실록산 박리 코팅 조성물 및 그 코팅법 | |
KR900014548A (ko) | 수지 조성물, 경화성 조성물 및 도료 조성물 | |
KR890008258A (ko) | 저온 경화성 조성물 | |
KR900007967A (ko) | 실리콘 고무 조성물 | |
US5124212A (en) | Articles prepared from fast ultraviolet radiation curing silicone composition | |
KR960017715A (ko) | 광학재료용 조성물 및 그 용도 | |
JPH05156163A (ja) | 紫外線硬化性珪素樹脂−有機メルカプタン組成物 | |
KR880012721A (ko) | 광경화성 유리 접착용 조성물 | |
KR920005734A (ko) | 오르가노폴리실록산 조성물 및 그의 경화물 | |
KR920018094A (ko) | 안정화된 메틸메타크릴레이트 중합체 | |
KR900016407A (ko) | 경화성 포스파젠(Phosphazene)조성물 및 피복부재 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
G160 | Decision to publish patent application | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
FPAY | Annual fee payment |
Payment date: 20010419 Year of fee payment: 10 |
|
LAPS | Lapse due to unpaid annual fee |