KR890017316A - 광 섬유 피복용 자외선 경화형 실리콘 수지 조성물 - Google Patents

광 섬유 피복용 자외선 경화형 실리콘 수지 조성물 Download PDF

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KR890017316A
KR890017316A KR1019890006338A KR890006338A KR890017316A KR 890017316 A KR890017316 A KR 890017316A KR 1019890006338 A KR1019890006338 A KR 1019890006338A KR 890006338 A KR890006338 A KR 890006338A KR 890017316 A KR890017316 A KR 890017316A
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South Korea
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sio
component
optical fiber
resin composition
silicone resin
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KR1019890006338A
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KR920004198B1 (ko
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휘 삼
모도 야쓰시 마쓰
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이찌세 와따루
도시바 실리콘 가부시끼가이샤
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/104—Coating to obtain optical fibres
    • C03C25/106—Single coatings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)
  • Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음

Description

광 섬유 피복용 자외선 경화형 실리콘 수지 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. (A)평균조성식
    (식중 R1은 비닐기를 제외한 치환 또는 비치환 1가의 탄화 수소기를 나타내고, a는 0.01a1, b는 0.8b3, (a+b)는 1.8a±b2.2의 범위이다.)로 표시되고, 25℃에 있어서의 점도가 50-10,000cP 범위의 유동성 비닐기를 함유하는 폴리오르가노실록산 100중량부, (B)R3 2SiO0.5단위, (CH2=CH)CR2-C 3SiO 단위(식중 R2및 R3는 R1과 같이 치환 또는 비치환의 1가의 탄화 수소기, C는 0, 1 또는 2이다) 및 SiO2단위로 구성되어 (CH2=CH)cR2-c 3SiO 단위에 대한 R3 2SiO0.5단위와 SiO2단위와의 합의 몰비가 3-20의 범위이고, 비닐기의 함유량이 1-25몰%인 비닐기를 함유하는 폴리오르가노 실록산 수지 30-300 중량부. (C) R3 2SiO0.5단위 Rd 4(HSR5)SiO
    단위 및 R2-e 6Re 7SiO 단위(식중 R2, R4, R6, R7은 R1과 같은 치환 또는 비치환의 1가의 탄화수소기, R5는 탄소수 2-6개의 2가의 탄화수소기, d는 0, 1또는 2, e는 0, 1또는 2이다.)로 구성되어 R2-e 6Re 7SiO단위에 대한 R3 2SiO0.5단위와 Rd 4(HSR5)SiO단위와의 합의 몰비가 0.05-0.5의 범위이고 SH기 함유량이 4-30몰%인 머 캡토 알킬기를 함유하는 폴리 오르가노 실록산 10-100중량부 (D) 광 개시제 0.01-50중량부 (E) 중합 금지제 0.001-10중량부 (F) 산화방지제 0.001-10중량부 및 (G)자외선 흡수제 0.001-10중량부로 구성되고 (C)성분중의 머 캡토 알킬기와 (A)성분과 (B)성분중의 비닐기의 합과의 몰비가 0.2-2.5로 되도록 조절해서 이루어지는 것을 특징으로 하는 광 섬유 피복용 자외선 경화형 실리콘 수지 조성물.
  2. 제 1 항에 있어서, (A)성분중의 1가 탄화수소기의 총수의 1-10%가 페닐기 인 것을 특징으로 하는 광섬유피복용 자외선 경화형 실리콘 수지 조성물.
  3. 제 1 항에 있어서, (D)성분의 광 개시제가 2-하이드록시-2-메틸-1-페닐 프로판-1-온 인것을 특징으로 하는광 섬유 피복용 자외선 경화형 실리콘 수지 조성물.
  4. 제 1 항에 있어서, (F)성분의 산화 방지제가 테트라기스-[메틸렌-3-(3′,5′,-디-t-부틸-4′-하이드록시페닐)프로피오 네이트]메탈인 것을 특징으로 하는 광섬유 피복용 자외선 경화형 실리콘 수지 조성물.
  5. 제 1 항에 있어서, (G)성분이 벤조 페논계 자외선 흡수제인 것을 특징으로 하는 광섬유 피복용 자외선 경화형 실리콘 수지 조성물.
  6. 제 1 항에 있어서, (G)성분이 벤조 트리아졸계 자외선 흡수제인 것을 특징으로하는 광 섬유 피복용 자외선경화형 실리콘 수지 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890006338A 1988-05-12 1989-05-11 광섬유 피복용 자외선 경화형 실리콘 수지조성물 KR920004198B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP63115493A JP2620303B2 (ja) 1988-05-12 1988-05-12 光ファイバー被覆用紫外線硬化型シリコーン樹脂組成物
JP115493 1988-05-12
JP63-115493 1988-05-12

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KR890017316A true KR890017316A (ko) 1989-12-15
KR920004198B1 KR920004198B1 (ko) 1992-05-30

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US (1) US4935455A (ko)
JP (1) JP2620303B2 (ko)
KR (1) KR920004198B1 (ko)

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JP2620303B2 (ja) 1997-06-11
US4935455A (en) 1990-06-19
KR920004198B1 (ko) 1992-05-30
JPH01286939A (ja) 1989-11-17

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