KR970061930A - 활성 에너지선-경화성 수지 조성물 - Google Patents

활성 에너지선-경화성 수지 조성물 Download PDF

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KR970061930A
KR970061930A KR1019970004592A KR19970004592A KR970061930A KR 970061930 A KR970061930 A KR 970061930A KR 1019970004592 A KR1019970004592 A KR 1019970004592A KR 19970004592 A KR19970004592 A KR 19970004592A KR 970061930 A KR970061930 A KR 970061930A
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group
carbon atoms
composition
defined above
resin
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KR1019970004592A
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KR100337685B1 (ko
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유 아까끼
후미오 야마시따
야스오 다까야
오사무 이소자끼
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사사끼 요시오
간사이 페인트 가부시끼가이샤
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Publication of KR970061930A publication Critical patent/KR970061930A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/16—Cyclic ethers having four or more ring atoms
    • C08G65/18—Oxetanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/14—Unsaturated oxiranes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C09D133/068—Copolymers with monomers not covered by C09D133/06 containing glycidyl groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Polyethers (AREA)
  • Paints Or Removers (AREA)
  • Epoxy Resins (AREA)

Abstract

본 발명은 (A) 분자내에 옥세탄 작용기 및 에폭시기를 갖는 수지, 및 (B) 광-유도 양이온성 중합화 개시제를 모두 함유하는 활성 에너지선-경화성 수지 조성물, 특히 활성 에너지선-경화성 피복 조성물에 관한 것이다.

Description

활성 에너지선-경화성 수지 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 하기 : (A) 분자내에, 하기 화학식(1)로 나타낸 에폭시기 및 옥세탄 작용기를 갖는 수지
    (1)
    〔식 중, R1은 수소원자, 1∼6탄소원자의 알킬기, 불소원자, 1∼6탄소원자의 플루오로알킬기, 알릴기, 아릴기, 아랄킬기, 푸릴기 또는 티에틸기이다〕, 및 (B) 광-유도 양이온성 중합화 개시제로 이루어진 활성 에너지선-경화성 수지 조성물.
  2. 제1항에 있어서, R1이 1∼4 탄소원자의 알킬기인 조성물.
  3. 제1항에 있어서, 수지(A)가, 분자내에, 평균 2∼100개의 옥세탄 작용기 및 평균 2∼100개의 에폭시기를 갖는 조성물.
  4. 제1항에 있어서, 수지(A)가 약 300∼200,000의 수평균 분자량을 갖는 아크릴 수지인 조성물.
  5. 제1항에 있어서, 광-유도 양이온성 중합화 개시제 (B)가 하기 화학식(3)∼(14)로 나타낸 화합물로부터 선택되는 조성물:
    Ar2I+·X-(3)
    (식중, Ar은 아릴기, 예를 들어, 페닐기이고; 및 X-는 PF6 -,SbF6 -또는 AsF6 -이다),
    Ar3S+·X-(4)
    (식 중, Ar 및 X-1각각 상기 정의된 바와 같다),
    (5)
    (5)
    (식 중, R2은 1∼12 탄소원자의 알킬기 또는 1∼12탄소원자의 알콕시기이고; n은 0∼3의 정수이고; 및 X-1는 상기 정의된 바와 동일하다),
    (6)
    (식 중, Y-는 PF6 -, SbF6 -, AsF6 -또는 SbF5(OH)-이다)
    (7)
    (7)
    (식 중, X-는 상기 정의된 바와 동일하다),
    (8)
    (8)
    (식 중 X-는 상기 정의된 바와 동일하다),
    (9)
    (9)
    (식 중 X-는 상기 정의된 바와 동일하다),
    (10)
    (10)
    (식 중 R3은 7∼15 탄소원자의 아랄킬기 또는 3∼9 탄소원자의 알케닐기이고; R4는 1∼7탄소원자의 탄화수소기 또는 히드록시페닐기이고; R5는 산소원자(들) 또는 황원자(들)를 함유할 수 있는 1∼5 탄소원자의 알킬기이고; 및 X-는 상기 정의된 바와 동일하다),
    (11)
    (11)
    (12)
    (12)
    (식중, R6및 R7은 각각 독립적으로 1∼12 탄소원자의 알킬기 또는 1∼12 탄소원자의 알콕시이다),
    (13)
    (13)
    (14)
    (14)
    (식 중 R6및 R7상기 정의된 바와 동일하다),
    (15)
    (15)
    (16)
    (16)
    (17)
    (17)
  6. 제1항에 있어서, 수지(A)의 비율이 (고형 함량으로서) 100중량부이고, 중합화 개시제 (B)의 비율이 0.01∼20중량부인 조성물.
  7. 제6항에 있어서, 수지(A)의비율이 (고형 함량으로서) 100중량부이고, 중합화 개시제 (B)의 비율이 0.05∼15중량부인 조성물.
  8. 제1항에 있어서, 모녹세탄 화합물을 더 함유하는 조성물.
  9. 제1항의 조성물을 함유하는 활성 에너지선-경화성 피복 조성물.
  10. 피복되어지는 재료상에 제9항의 조성물을 도포시켜 수득된 피복 물품.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970004592A 1996-02-16 1997-02-15 활성에너지선-경화성수지조성물 KR100337685B1 (ko)

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JP96-29483 1996-02-16
JP2948396 1996-02-16

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KR100337685B1 KR100337685B1 (ko) 2002-11-30

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JP2001310938A (ja) * 2000-04-28 2001-11-06 Showa Denko Kk 重合性組成物、その硬化物と製造方法
JP2002040632A (ja) 2000-07-21 2002-02-06 Showa Denko Kk レジストインキ組成物
TWI227374B (en) * 2001-01-24 2005-02-01 Sumitomo Chemical Co Colored photosensitive composition, method for making a color pattern and the use thereof
JP4214729B2 (ja) 2002-07-25 2009-01-28 コニカミノルタホールディングス株式会社 硬化性白インク組成物
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TWI428389B (zh) 2007-10-31 2014-03-01 Dainippon Ink & Chemicals 活性能量線硬化性組成物及其製造方法
JP5461809B2 (ja) * 2008-09-29 2014-04-02 富士フイルム株式会社 インク組成物、及び、インクジェット記録方法
KR20220081921A (ko) * 2020-12-09 2022-06-16 닛토덴코 가부시키가이샤 광경화성 수지 시트

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KR100337685B1 (ko) 2002-11-30
GB2310211B (en) 1999-12-08
GB2310211A (en) 1997-08-20
GB2310211A8 (en) 1997-11-17
US5882842A (en) 1999-03-16
GB9703076D0 (en) 1997-04-02

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