KR830004353A - 메르캅토오르가노 폴리실록산 및 이를 함유한 경화성 조성물 - Google Patents

메르캅토오르가노 폴리실록산 및 이를 함유한 경화성 조성물 Download PDF

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KR830004353A
KR830004353A KR1019800004615A KR800004615A KR830004353A KR 830004353 A KR830004353 A KR 830004353A KR 1019800004615 A KR1019800004615 A KR 1019800004615A KR 800004615 A KR800004615 A KR 800004615A KR 830004353 A KR830004353 A KR 830004353A
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siloxane units
sulfur
radical
structural formula
same
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KR1019800004615A
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KR840001834B1 (ko
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렉스 호만 게리
리 지룡
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헤리 디·딩만
다우 코닝 코포레이션
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C08L83/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
    • C08G77/50—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms by carbon linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
    • C08G77/392—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/14—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms

Abstract

내용 없음

Description

메르캅토오르가노 폴리실록산 및 이를 함유한 경화성 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (2)

  1. 디메틸-실록산 단위, 트리메틸실록산 단위, 다음 구조식(I)의 황함유 실록산 단위, 및 다음 구조식(Ⅱ)의 펜던트형 황함유 실록산 단위에서 선택된 단위의 병합형태로 이루어진 오르가노 폴리실록산(여기에서 오르가노폴리실록산은 분자당 평균 2개 이상의 황함유 실록산 단위와 10몰% 이하(오르가노폴리실록산내의 실록산 단위 총수를 기준하여)의 펜던트형 황함유 실록산 단위를 함유한다).
    상기 구조식에서
    R 및 R1은 같거나 다르며 메틸 또는 에틸이고
    X는 2 또는 3이고
    a는 0 또는 1이고
    A 및 B는 같거나 다르며 -CmH2m- 또는 -CnH2n-(여기서 m 및 n은 같거나 다르며 2 내지 4임)의 2가 라디칼, 또는 (+)본드(bond)가 황원자에 결합하고, 다른 두개의 본드가 동일한 실리큰 원자에 결합하여 실라시클로펜타머를 형성하는 다음 구조식의 3가 라디칼이고,
    R2는 탄소수 1 내지 3의 알릴 또는 알콕시라디칼, 또는 페닐라디칼같은 1가 라디칼이고
    b는 1 또는 2이고
    R3는 메틸 또는 에틸이고
    c는 0 또는 1이며
    단, 2가 라디칼일 경우 탄소원자는 실리콘 및 황원자에 부착되지 않고
    A가 3가 라디칼일 경우 X는 2이고 a는 0이며
    B가 3가 라디칼일 경우 b는 1이고 c는 0이며
    B가 2가 라디칼일 경우 b는 2이고 c는 1이다.
  2. (A)디메틸-실록산단위, 트리메틸실록산 단위, 다음 구조식(I)의 황함유 실록산단위 및 다음 구조식(Ⅱ)의 펜던트형 황함유 실록산 단위에서 선택된 단위의 병합형태로 이루어진 오르가노 폴리실록산(여기에서 오르가노폴리실록산은 분자당 평균 2개 이상의 황함유실록산단위와 10몰%이하(오르가노폴리실록산내의 실록산 단위 총수를 기준하여)의 펜던트형 황함유 실록산단위를 함유함), (B)(A) 100중량부당 1 내지 10중량부의 경화용 촉매, (C)(A) 100중량부당 0 내지 200중량부의 충진제 및 (D)(A) 100중량부당 0 내지 10중량부의 교차결합제로 이루어진 경화성 조성물.
    상기 구조식에서
    R 및 R1은 같거나 다르며 메틸 또는 에틸이고
    X는 2 또는 3이고
    a는 0 또는 1이고
    A 및 B는 같거나 다르며 -CmH2m- 또는 -CnH2n-(여기서 m 및 n은 같거나 다르며 2 내지 4임)의 2가 라디칼, 또는 (+) 본드(bond)가 황원자에 결합하고 다른 두 개의 본드가 동일한 실리콘원자에 결합하여 실라시클로펜타머를 형성하는 다음 구조식의 3가 라디칼이고,
    R2는 탄소수 1 내지 3의 알킬 또는 알콕시라디칼, 또는 페닐 라디칼같은 1가 라디칼이고
    b는 1 또는 2이고
    R3는 메틸 또는 에틸이고
    c는 0 또는 1이며
    단, 2가 라디칼일 경우 탄소원자는 실리콘 및 황원자에 부착되지 않고,
    A가 3가 라디칼일 경우 X는 2이고 a는 0이며
    R가 3가 라디칼인 경우 b는 1이고 c는 0이며
    B가 2가 라디칼일 경우 b는 2이고 c는 1이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019800004615A 1979-12-03 1980-12-03 메르캅토 오르가노 폴리실록산-함유 경화성 조성물 KR840001834B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/099,300 US4269963A (en) 1979-12-03 1979-12-03 Mercaptoorganopolysiloxanes and curable compositions including same
US99,300 1979-12-03

Publications (2)

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KR830004353A true KR830004353A (ko) 1983-07-09
KR840001834B1 KR840001834B1 (ko) 1984-10-22

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Country Link
US (1) US4269963A (ko)
EP (1) EP0031994B1 (ko)
JP (1) JPS6126929B2 (ko)
KR (1) KR840001834B1 (ko)
BR (1) BR8008949A (ko)
CA (1) CA1155864A (ko)
DD (1) DD154992A5 (ko)
DE (1) DE3067477D1 (ko)
ES (3) ES8304593A1 (ko)
WO (1) WO1981001561A1 (ko)
ZA (1) ZA807407B (ko)

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KR20190013091A (ko) * 2017-07-31 2019-02-11 다우 실리콘즈 코포레이션 이중 경화성 수지 조성물, 그로부터 형성된 경화물, 및 그러한 경화물을 포함하는 전자 장치
JP2023165225A (ja) * 2022-05-02 2023-11-15 信越化学工業株式会社 メルカプト基およびアルコキシシリル基含有オルガノポリシロキサン、ならびにそれを含む組成物

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Also Published As

Publication number Publication date
EP0031994A3 (en) 1981-10-21
ES497378A0 (es) 1983-03-01
ES8207575A1 (es) 1982-10-01
BR8008949A (pt) 1981-10-20
ZA807407B (en) 1981-11-25
EP0031994A2 (en) 1981-07-15
US4269963A (en) 1981-05-26
ES8304593A1 (es) 1983-03-01
ES507999A0 (es) 1982-10-01
EP0031994B1 (en) 1984-04-11
ES518234A0 (es) 1984-01-01
DE3067477D1 (en) 1984-05-17
DD154992A5 (de) 1982-05-05
JPS6126929B2 (ko) 1986-06-23
JPS56501604A (ko) 1981-11-05
ES8401995A1 (es) 1984-01-01
WO1981001561A1 (en) 1981-06-11
KR840001834B1 (ko) 1984-10-22
CA1155864A (en) 1983-10-25

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