KR900004882A - 자동차 피복 조성물 - Google Patents

자동차 피복 조성물 Download PDF

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KR900004882A
KR900004882A KR1019890012822A KR890012822A KR900004882A KR 900004882 A KR900004882 A KR 900004882A KR 1019890012822 A KR1019890012822 A KR 1019890012822A KR 890012822 A KR890012822 A KR 890012822A KR 900004882 A KR900004882 A KR 900004882A
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compound
coating composition
group
composition according
polymer
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KR1019890012822A
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KR930002219B1 (ko
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이찌로 다부찌
노보루 나까이
오사부 이소자끼
다까오 마또바
신지 스기우라
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야마다 모또조오
간사이뻬인또 가부시끼가이샤
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C09D183/06—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0091—Complexes with metal-heteroatom-bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)

Abstract

내용 없음.

Description

자동차 피복 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. (i) (a) 70 내지 99.999몰 퍼센트의 하기 일반식(1)의 화합물(A)와 30 내지 0.001몰 퍼센트의 하기일반식(2)의 화합물(B)를 반응시켜 수득할 수 있는 분자당 히드록실 및 알콕시기로 구성된 클라스로부터 선택된 2개이상의 관능기를 함유하며 수평균 분자량이 400 내지 100,000인 폴리실록산 고단량체, 및 공단량체 단위로서 옥시란기 함유비닐 단량체를 함유하는 공중합체 또는 (b) 필수적 단량체 단위로서 상기 폴리실록산 고단량체를 함유하는 중합체(I) 및 필수적 단량체 단위로서 옥시란기 함유비닐단량체를 함유하는중합체(II)의 혼합물 물중 하나인 100중량부의 기초수지 및 (ii) 알루이늄킬레이트 화합물, 티타늄 킬레이트 화합물 및 지르코늄킬레이트 화합물로 구성된 클라스로부터 선댁된 0.1 내지 30중량부의 킬레이트 화합물을 함유하는 자동차 피복조성물.
    (상기식에서, R1은 1 내지 8탄소원자의 지방족 탄화수소기 또는 페닐기이고 ; R2,R3및 R4는 독립적으로 1내지 4탄소원자의 알콕시기 또는 히드록실기를 의미하며 ; R5는 수소원자 또는 에틸기이며 ; R6,R7및 R8은 히드록실기, 1 내지 4탄소원자의 알콕시기 또는 1 내지 8탄소원자의 지방족 탄화수소기이나 R6, R7및 R8모두다 1 내지 8탄소원자의 지방족 탄화수소는 아니며 ; n은 1 내지 6의 정수이다).
  2. 제1항에 있어서, 상기 화합물(A) 가 메틸트리메톡시실란, 페닐트리메톡시실란, 부틸트리메톡시실란, 메틸트리에톡시실란, 메틸트리부톡시실란, 페닐트리실라놀 및 메틸트리실라놀로 구성된 클라스로부터 선택된 적어도 하나의 화합물이고 상기 화합물(B)가 γ1-메타크릴옥시프로필트리메톡시실란, γ-메타크릴옥시프로필트리에톡시실란, γ- 아크릴옥시프로필트리메톡시실란, γ-메타크릴옥시부틸트리에톡시실란, γ-아크릴옥시프로필트리실라놀, γ-아크릴옥시프로필메틸디메톡시실란 및 γ-메타크릴옥시프로필에틸디메톡시실란으로 구성된 클라스로부터 선택된 적어도 하나의 화합물인 자동차 피복조성물.
  3. 제1항에 있어서, 상기 폴리실록산 고단량체가 분자당 평균 0.2 내지 1.9 중합가능한 불포화 결함을 갖는 자동차 피복조성물.
  4. 제1항에 있어서, 상기 옥시란기 함유 비닐 단량체가 지환족옥시란기함유 비닐 단량체인 자동차 피복조성물.
  5. 제1항에 있어서, 상기 기초수지가 폴리실록산 고단량체 및 공단량체 단위로서 옥시란기 함유비닐단량체를 함유하며 3,000 내지 30,000의 수평균 분자량을 갖는 자동차 피복조성물.
  6. 제1항에 있어서, 상기 기초수지가 중합체의 총량을 기준으로 5 내지 95중량 퍼센트의 상기 중합체(I) 및 95 내지 5중량 퍼센트의 상기 중합체(II)로 구성된 중합체 혼합물인 자동차 피복조성물
  7. 제1항에 있어서, 상기 킬레이트 화합물이 킬레이트 고리형성 리간드로서 케토-에놀토오토메리즘을 할 수 있는 화합물을 함유하는 자동차 피복조성물.
  8. 제1항에 있어서, 분자당 적어도 2개의 옥시란기를 함유하며 수평균 분자량이 2000이하인 저분자량 화합물을 상기 기초수지 100중량부를 기준으로 5 내지 60중량부의 비율로 더 함유하는 자동차 피복조성물.
  9. 제1 또는 8항에 있어서, 중간피복으로서 사용되는 자동차 피복조성물.
  10. 제1 또는 8항에 있어서, 톱 피복으로서 사용되는 자동차 피복조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890012822A 1988-09-05 1989-09-05 자동차 피복 조성물 KR930002219B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP22214688 1988-09-05
JP222146 1988-09-05
JP63227094A JP2668083B2 (ja) 1988-09-05 1988-09-09 自動車用塗料組成物
JP227094 1988-09-09

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KR900004882A true KR900004882A (ko) 1990-04-13
KR930002219B1 KR930002219B1 (ko) 1993-03-27

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US (1) US5051473A (ko)
EP (1) EP0358153B1 (ko)
JP (1) JP2668083B2 (ko)
KR (1) KR930002219B1 (ko)
CA (1) CA1335909C (ko)
DE (1) DE68912244T2 (ko)

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JPS63108048A (ja) * 1986-05-15 1988-05-12 Kansai Paint Co Ltd 硬化性組成物及び硬化方法
JPS63108049A (ja) * 1986-06-05 1988-05-12 Kansai Paint Co Ltd 硬化性組成物及び硬化方法
JPH07103341B2 (ja) * 1986-06-11 1995-11-08 関西ペイント株式会社 被覆用組成物
JPS63221123A (ja) * 1987-03-09 1988-09-14 Kansai Paint Co Ltd 低温硬化性樹脂組成物
GB2212165B (en) * 1987-11-09 1992-07-01 Kansai Paint Co Ltd Resin composition curable at low temperature
GB2212503B (en) * 1987-11-16 1991-11-20 Kansai Paint Co Ltd Composition curable at low temperature

Also Published As

Publication number Publication date
EP0358153A3 (en) 1991-11-06
DE68912244D1 (de) 1994-02-24
DE68912244T2 (de) 1994-04-28
EP0358153B1 (en) 1994-01-12
US5051473A (en) 1991-09-24
KR930002219B1 (ko) 1993-03-27
EP0358153A2 (en) 1990-03-14
JPH02160879A (ja) 1990-06-20
CA1335909C (en) 1995-06-13
JP2668083B2 (ja) 1997-10-27

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