KR850005867A - 개선된 실온 안정성을 갖는 열경화성 실리콘 조성물 - Google Patents
개선된 실온 안정성을 갖는 열경화성 실리콘 조성물 Download PDFInfo
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- KR850005867A KR850005867A KR1019850000713A KR850000713A KR850005867A KR 850005867 A KR850005867 A KR 850005867A KR 1019850000713 A KR1019850000713 A KR 1019850000713A KR 850000713 A KR850000713 A KR 850000713A KR 850005867 A KR850005867 A KR 850005867A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/045—Polysiloxanes containing less than 25 silicon atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/12—Polysiloxanes containing silicon bound to hydrogen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/24—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen halogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/70—Siloxanes defined by use of the MDTQ nomenclature
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (7)
- (A) 일반식(1)의 폴리유기실록산(이 폴리유기실록산은 폴리유기실록산당 후술할 Q라디칼 및 히드록실 라디칼 중에서 선택된 라디칼 하나이상을 함유한다); (B) 실리콘 원자에 결합된 수소원자-함유폴리유기실록산; (C) 촉매; (D) 5 내지 12개의 탄소원자, 말단 에티닐그룹 및 이 네티닐 그룹과 공액된 에테닐 그룹을 함유하는 공액 엔-인; 및 (E) 일반식(2)의 비닐시클로실록산으로 이루어진 경화성 실리콘조성물.상기식에서, R1은 일가의 비-올레핀계 탄화수소 또는 할로겐화 탄화수소 라디칼이고; Q는 일반식(CnH2n)CH=CH2(여기서, n은 0내지 4이다)의 비닐-함유라디칼이며; R2는 R1라디칼, Q라디칼 및 히드록실 라디칼 중에서 선택되며;x는 18 내지 6000이고; a는 0,1 또는 2이며; b는 0,1 또는 2이고; 단, a+b의 평균합은 1.8내지 2.2이고 ; 각 R5는 메틸, 에틸 또는 페닐이고 m은 3내지 6의 평균값을 나타낸다.
- 제1항에 있어서, 성분(A)가 0.5 내지 99.48부로 존재하고; 성분 (B)가 0.5 내지 99.48부로 존재하며; 성분(C)가 0.000001 내지 1.0부로 존재하고; 성분(D)가 0.01 내지 10부로 존재하며; 성분(E)가 0.01 내지 10부로 존재(여기서 성분(A)+(B)+(C)+(D)+(E)는 총 100부이고 여기서 모든부는 중량부이다)하는 경화성 실리콘 조성물.
- 제1항에 있어서, 성분(D)가인 경화성 실리콘 조성물.
- 제1항에 있어서, 상기 조성물에 충진제가 더 첨가된 경호성 수지조성물.
- (A) 일반식(1)의 폴리유기실록산 0.5 내지 99.48부(이 폴리유기실록산은 분자당 비닐 및 OH기중에서 선택된 라디칼 하나이상을 함유한다); (B) 일반식 (4)의 폴리유기실록산 0.5 내지 99.48부(이 폴리유기실록산은 분자당 실리콘에 결합된 수소원자 하나이상을 함유한다); (C) 금속중에 대하여, 촉매 0.000001 내지 1.0부; (D) 5 내지 12개의 탄소원자, 말단 에티닐그룹 및 이 에티닐 그룹과 공액된 에티닐그룹을 함유하는 탄화수소인 방지제 0.1 내지 10부; (E) 일반식(2)의 비닐시클로실록산 0.01 내지 10부; 및 (G) 용매 0 내지 4000부로 이루어진, 기질용 경화성 피복조성물.상기식에서 R1은 일가의 비-올레핀계 탄화수소 또는 할로겐화 탄화수소 라디칼이고; Q는 비닐-함유라디칼이며; R2는 Q라디칼, R1라디칼 및 OH 라디칼 중에서 선택되며; a는 0,1 또는 b는 0,1 또는 2이고; b는 0,1 또는 2이며; 단, a+b의 평균합은 1.8 내지 2.2이고; x는 18 내지 4000이고; R3는 일가의 비-올레핀계 탄화수소 또는 할로겐화 탄화수소 라디칼이고; H는 수소원자이며; R4는 수소원자 및 R3라디칼 중에서 선택되고; c는 0,1 또는 2이며; d는 0,1 또는 2이고 ; 단, c+d의 평균합은 1.8 내지 2.2이고 y는 18 내지 500이며; 각 R5는 메틸, 에틸 또는 페닐이고; m은 3내지 6의 평균값을 나타내며; 상기의 모든 부는 성분 (A)+(B)+(C)+(D)+(E) 총 100부에 대한 중량부이다.
- 5내지 12개의 탄소원자, 말단에티닐 그룹 및 이 에티닐 그룹과 공액된 에네닐그룹을 함유하는 공액 엔-인 1 내지 99중량부; 및 일반식(2)의 비닐시클로실록산 1내지 99중량부로 주로 구성된 촉매방지제 조성물(상기 성분들의 합은 총 100부이다)(R5CH2=CHSiO)m(2)상기식에서, 각 R5는 메틸, 에틸 또는 페닐이고 m은 3내지 6의 평균값을 나타낸다.
- 비닐-함유 또는 히드록실-함유폴리유기실록산, 실리콘 원자에 결합된 수소원자-함유폴리유기수소실록산, 촉매 및 촉매방지제로 이루어진 경화성 실리콘 조성물에 있어서, 촉매방지제로서, 5내지 12개의 탄소원자, 말단에티닐 그룹 및 이 에티닐 그룹과 공액돤 에테닐 그룹을 함유하는 고액 엔-인 1내지 99중량부 및 일반식(2)의 비닐시클로실록산 1내지 99중량부로 주로 구성된 조성물을 사용함을 특징으로 하는 경화성 실리콘 조성물.(R5CH2=CHSiO)m(2)상기식에서, 각 R5는 메틸, 에틸 또는 페닐이고 m은 3내지 6의 평균값을 나타낸다.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US576,985 | 1984-02-06 | ||
US576985 | 1984-02-06 | ||
US06/576,985 US4472563A (en) | 1984-02-06 | 1984-02-06 | Heat curable silicones having improved room temperature stability |
Publications (2)
Publication Number | Publication Date |
---|---|
KR850005867A true KR850005867A (ko) | 1985-09-26 |
KR920009395B1 KR920009395B1 (ko) | 1992-10-16 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019850000713A KR920009395B1 (ko) | 1984-02-06 | 1985-02-05 | 실온 안정성이 개선된 열경화성 실리콘 조성물 |
Country Status (7)
Country | Link |
---|---|
US (1) | US4472563A (ko) |
EP (1) | EP0154411B1 (ko) |
JP (1) | JPS60188461A (ko) |
KR (1) | KR920009395B1 (ko) |
AU (1) | AU571052B2 (ko) |
CA (1) | CA1261502A (ko) |
DE (1) | DE3567667D1 (ko) |
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GB0905204D0 (en) | 2009-03-26 | 2009-05-13 | Dow Corning | Preparation of organosiloxane polymers |
GB0905205D0 (en) | 2009-03-26 | 2009-05-13 | Dow Corning | Preparation of organosiloxane polymer |
US8933187B2 (en) | 2011-12-08 | 2015-01-13 | Momentive Performance Material Inc. | Self-crosslinking silicone pressure sensitive adhesive compositions, process for making and articles made thereof |
US9487677B2 (en) | 2014-05-27 | 2016-11-08 | Momentive Performance Materials, Inc. | Release modifier composition |
EP3161083A4 (en) | 2014-06-27 | 2018-02-21 | Dow Corning (China) Holding Co. Ltd. | Silicone release coating composition and low release force emulsion silicone release coating for films and papers having cured release coating |
KR102548854B1 (ko) | 2014-12-18 | 2023-06-27 | 모멘티브 파포만스 마테리아루즈 쟈판 고도가이샤 | 성형용 폴리오르가노실록산 조성물, 광학용 부재, 광원용 렌즈 또는 커버, 및 성형방법 |
WO2023227714A1 (en) | 2022-05-25 | 2023-11-30 | Momentive Performance Materials Gmbh | New substituted phosphite transition metal compounds |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4340709A (en) * | 1980-07-16 | 1982-07-20 | General Electric Company | Addition curing silicone compositions |
US4340710A (en) * | 1981-04-02 | 1982-07-20 | General Electric Company | Addition cure coating with improved adhesion |
JPS6054991B2 (ja) * | 1982-04-02 | 1985-12-03 | ト−レ・シリコ−ン株式会社 | オルガノポリシロキサン組成物 |
JPS59133252A (ja) * | 1983-01-19 | 1984-07-31 | Toray Silicone Co Ltd | オルガノポリシロキサン組成物 |
FR2554118B1 (fr) * | 1983-10-26 | 1986-01-17 | Rhone Poulenc Spec Chim | Agent inhibiteur cetonique pour catalyseur d'un metal du groupe du platine et compositions organopolysiloxaniques le contenant |
US4562096A (en) * | 1984-12-24 | 1985-12-31 | Dow Corning Corporation | Heat-curable silicone compositions, use thereof and stabilizer therefor |
-
1984
- 1984-02-06 US US06/576,985 patent/US4472563A/en not_active Expired - Lifetime
- 1984-12-21 CA CA000470770A patent/CA1261502A/en not_active Expired
-
1985
- 1985-02-05 AU AU38464/85A patent/AU571052B2/en not_active Ceased
- 1985-02-05 DE DE8585300762T patent/DE3567667D1/de not_active Expired
- 1985-02-05 EP EP85300762A patent/EP0154411B1/en not_active Expired
- 1985-02-05 KR KR1019850000713A patent/KR920009395B1/ko not_active IP Right Cessation
- 1985-02-05 JP JP60019389A patent/JPS60188461A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
EP0154411B1 (en) | 1989-01-18 |
JPS60188461A (ja) | 1985-09-25 |
US4472563A (en) | 1984-09-18 |
AU3846485A (en) | 1985-08-15 |
DE3567667D1 (en) | 1989-02-23 |
EP0154411A2 (en) | 1985-09-11 |
EP0154411A3 (en) | 1986-04-30 |
KR920009395B1 (ko) | 1992-10-16 |
AU571052B2 (en) | 1988-03-31 |
CA1261502A (en) | 1989-09-26 |
JPH0129512B2 (ko) | 1989-06-12 |
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