KR960022748A - 시클로올레핀 공중합체 조성물 - Google Patents
시클로올레핀 공중합체 조성물 Download PDFInfo
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- KR960022748A KR960022748A KR1019950061487A KR19950061487A KR960022748A KR 960022748 A KR960022748 A KR 960022748A KR 1019950061487 A KR1019950061487 A KR 1019950061487A KR 19950061487 A KR19950061487 A KR 19950061487A KR 960022748 A KR960022748 A KR 960022748A
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- cycloolefin
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- refractive index
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F232/00—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
- C08F232/08—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having condensed rings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L45/00—Compositions of homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic ring system; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
- C08L23/0823—Copolymers of ethene with aliphatic cyclic olefins
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
본 발명은 탄소수 2 이상의 α-올레핀(a)과 특정의 시클로올레핀 (b)을 방향족 환함유 비닐계 탄화수소/공역디엔 공중합체 또는 그 수화물(A)의 존재하에서 공중합하여 극한점도(η)가 0.5~5.0dl/g; 적어도 1개의 유리 전이온도(DSC로 측정)가 15℃ 이하, 중합가능 탄소-탄소 2중결합의 양이 옥소가 기준으로 2~150; 굴절률 1.50∼1.65인 시클로올레핀계 공중합체 조성물(C)에 관한 것이다. 조성물(C)에서 성분(A)의 함량은 1~40중량%이고, 성분(A)의 굴절률 nD(A)와 α-올레핀(a)과 시클로올레핀(b)을 성분(A)의 비존재하에서 공중합하여 얻어지는 시클로올레핀 공중합체성분(B)의 굴절률 nD(B)의 차△nD는 0.015이하이다. 이환상올레핀계 공중합체 조성물은 내충격성, 투명성 및 내열성이 우수하다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (2)
- (a) 적어도 탄소수 2 이상의 α-올레핀과, (b) 하기의 식(I) 또는 (II)로 표시되는 시클로올레핀(A)를 135℃ 데칼린에서 측정한 극한점도(η)가 0.5~5.Odl/g; DSC로 측정한 유리전이온도(Tg)가 15℃이하; 중합가능한 탄소-탄소 2중결합의 양이 옥소가 기준으로 2~150(g-옥소/100℃-중합체); 25℃에서 측정한 굴절률 nD(A)가 1.50~1.65의 성분(A)인 방향족환함유 비닐탈화수소/공역디엔공중합체 또는 그 수소화물의 존재하에서 공중합함으로써 얻어지는 시클로올레핀계 공중합체 조성물(C)로서, 이 공중합조성물(C)는 성분(A)의 함량이 1~40중량%이고, 굴절률차△nD는 0.015이다. 여기서 △nD는 nD(A)를 성분(A)의 굴절률, nD(B)를 α-올레핀 (a)와 시클로올레핀(b)를 성분(A)가 존재하지 않은 조건에서 공중합해서 얻어지는 시클로공중합체성분(B)의 굴절률이라 할 때 |nD(A)-nD(B)|인 것이 특징인 시클로올레핀 공중합체 조성물.상기 식중 n은 0 또는 1, m은 0 또는 양의 정수 r은 0 또는 1, R1-1818, Ra및 Rb는 각각 독립적으로 수소원자, 할로겐원자 또는 탄화수소기이며, R15-R18은 서로 결합되어 이중결합을 가질 수도 있는 단환 또는 다환구조를 형성할 수 있으며, R15와 R16또는 R17과 R18은 함께 알킬리덴기를 형성할 수 있다.상기 식중 p와 q는 각각 0 또는 1 이상의 정수, m과 n은 각각 0, 1 또는 2, R1-R19는 각각 독립적으로 수소원자, 할로겐원자, 지방족탄화수소기, 지환식 탄화수소기, 방향족 탄화수소기 또는 알콜시기이며, R9(또는 R10)이 결합된 탄소원자와 R13또는 R11결합된 탄소원자는 직접 또는 1~3 탄소원자의 알키렌기를 거쳐 결합됩 수 있고, n과 m이 0일때 R15와 R12또는 R15와 R19는 함께 결합되어 단환 또는 다환 방향환을 형성할 수 있다.
- 제1항에 있어서, 성분 (A)에 함유된 탄소-탄소 2중 결합의 양은 옥소가 기준으로 2~50(g-옥소/100g-중합체)의 벙위인 것을 특징으로 하는 시클로올레핀계 공중합체 조성물.※ 참고사항 :최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP94-328549 | 1994-12-28 | ||
JP32854994 | 1994-12-28 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR960022748A true KR960022748A (ko) | 1996-07-18 |
KR100318412B1 KR100318412B1 (ko) | 2002-07-27 |
Family
ID=18211525
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019950061487A KR100318412B1 (ko) | 1994-12-28 | 1995-12-28 | 시클로올레핀 공중합체 조성물 |
Country Status (7)
Country | Link |
---|---|
US (1) | US5854349A (ko) |
EP (1) | EP0719806B1 (ko) |
KR (1) | KR100318412B1 (ko) |
CN (1) | CN1075536C (ko) |
CA (1) | CA2166160C (ko) |
DE (1) | DE69504632T2 (ko) |
TW (1) | TW387904B (ko) |
Families Citing this family (40)
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US6255396B1 (en) | 1999-09-09 | 2001-07-03 | Baxter International Inc. | Cycloolefin blends and method for solvent bonding polyolefins |
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US6297322B1 (en) | 1999-09-09 | 2001-10-02 | Baxter International Inc. | Cycloolefin blends and method for solvent bonding polyolefins |
US6497676B1 (en) | 2000-02-10 | 2002-12-24 | Baxter International | Method and apparatus for monitoring and controlling peritoneal dialysis therapy |
US6743523B1 (en) | 2000-03-16 | 2004-06-01 | Baxter International Inc. | Multiple layer film of a new non-PVC material |
US6372848B1 (en) | 2000-10-10 | 2002-04-16 | Baxter International Inc. | Blend of ethylene and α-olefin copolymers obtained using a metallocene catalyst for fabricating medical films and tubings |
US20020139088A1 (en) | 2001-03-08 | 2002-10-03 | Archie Woodworth | Polymeric syringe body and stopper |
CN1321971C (zh) * | 2001-10-10 | 2007-06-20 | Jsr株式会社 | 降冰片烯衍生物及其降冰片烯系开环聚合物 |
US20030125662A1 (en) | 2002-01-03 | 2003-07-03 | Tuan Bui | Method and apparatus for providing medical treatment therapy based on calculated demand |
US6913056B2 (en) | 2002-01-31 | 2005-07-05 | Baxter International Inc. | Apparatus and method for connecting and disconnecting flexible tubing |
US7238164B2 (en) | 2002-07-19 | 2007-07-03 | Baxter International Inc. | Systems, methods and apparatuses for pumping cassette-based therapies |
DE602004005827T2 (de) * | 2003-01-28 | 2008-01-10 | Cryovac, Inc. | Cycloolefinpolymer für hochmodulige folien |
US20050085785A1 (en) * | 2003-10-17 | 2005-04-21 | Sherwin Shang | High impact strength film and non-pvc containing container and pouch and overpouch |
US20050186377A1 (en) * | 2004-02-19 | 2005-08-25 | Hurst William S. | Solventless plastic bonding of medical devices and container components through infrared heating |
JP5137569B2 (ja) | 2005-02-21 | 2013-02-06 | 三井化学株式会社 | ハイブリッドポリマーおよびその製造方法 |
US8148472B1 (en) | 2006-08-04 | 2012-04-03 | Exxonmobil Research And Engineering Company | Polymer compositions comprising cyclic olefin polymers, polyolefin modifiers and non-functionalized plasticizers |
EP2052022A1 (en) * | 2006-08-04 | 2009-04-29 | ExxonMobil Chemical Patents Inc. | Polymer compositions comprising cyclic olefin copolymers and polyolefin modifiers |
US8344070B2 (en) * | 2006-08-04 | 2013-01-01 | Exxonmobil Chemical Patents Inc. | Polymer compositions comprising cyclic olefin polymers, polyolefin modifiers, and fillers |
US7998115B2 (en) | 2007-02-15 | 2011-08-16 | Baxter International Inc. | Dialysis system having optical flowrate detection |
US8870812B2 (en) | 2007-02-15 | 2014-10-28 | Baxter International Inc. | Dialysis system having video display with ambient light adjustment |
US8558964B2 (en) | 2007-02-15 | 2013-10-15 | Baxter International Inc. | Dialysis system having display with electromagnetic compliance (“EMC”) seal |
US7731689B2 (en) | 2007-02-15 | 2010-06-08 | Baxter International Inc. | Dialysis system having inductive heating |
US8361023B2 (en) | 2007-02-15 | 2013-01-29 | Baxter International Inc. | Dialysis system with efficient battery back-up |
US7727705B2 (en) * | 2007-02-23 | 2010-06-01 | Fujifilm Electronic Materials, U.S.A., Inc. | High etch resistant underlayer compositions for multilayer lithographic processes |
US8519056B2 (en) | 2007-06-01 | 2013-08-27 | Exxonmobil Chemical Patents Inc. | Blends of co-precipitated hydrogenated ethylene-dicyclpentadiene and elastomeric polymers to provide impact modified structural polyolefins |
EP2237038B1 (en) | 2007-10-22 | 2015-04-29 | Becton Dickinson and Company | Medical articles coated with organopolysiloxane containing a protein solution and non-ionic surfactant |
CN102209800A (zh) | 2008-09-22 | 2011-10-05 | 贝克顿·迪金森公司 | 使用光解和/或热化学气相沉积法涂布容器内部的系统、设备和方法 |
US8802603B2 (en) | 2010-06-17 | 2014-08-12 | Becton, Dickinson And Company | Medical components having coated surfaces exhibiting low friction and low reactivity |
DE102012006287A1 (de) | 2012-03-29 | 2013-10-02 | Topas Advanced Polymers Gmbh | Transparente thermoplastische Harzzusammensetzung mit hoher Duktilität und deren Verwendung |
USD684539S1 (en) | 2012-07-06 | 2013-06-18 | Apple Inc. | Connector |
CN104597079B (zh) * | 2015-01-22 | 2017-07-21 | 天津大学 | 棕榈油碘值的测定方法 |
CN107063940B (zh) | 2016-02-10 | 2019-10-18 | 贝克顿迪金森法国公司 | 用于评价基于蛋白质的制剂的稳定性的方法 |
US11179516B2 (en) | 2017-06-22 | 2021-11-23 | Baxter International Inc. | Systems and methods for incorporating patient pressure into medical fluid delivery |
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-
1995
- 1995-12-22 TW TW084113761A patent/TW387904B/zh not_active IP Right Cessation
- 1995-12-27 CA CA002166160A patent/CA2166160C/en not_active Expired - Fee Related
- 1995-12-28 KR KR1019950061487A patent/KR100318412B1/ko not_active IP Right Cessation
- 1995-12-28 DE DE69504632T patent/DE69504632T2/de not_active Expired - Fee Related
- 1995-12-28 CN CN95119499A patent/CN1075536C/zh not_active Expired - Fee Related
- 1995-12-28 EP EP95120664A patent/EP0719806B1/en not_active Expired - Lifetime
-
1997
- 1997-04-14 US US08/843,292 patent/US5854349A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE69504632T2 (de) | 1999-02-25 |
EP0719806A3 (en) | 1997-02-12 |
EP0719806B1 (en) | 1998-09-09 |
US5854349A (en) | 1998-12-29 |
DE69504632D1 (de) | 1998-10-15 |
CN1075536C (zh) | 2001-11-28 |
KR100318412B1 (ko) | 2002-07-27 |
CA2166160C (en) | 2004-06-08 |
TW387904B (en) | 2000-04-21 |
EP0719806A2 (en) | 1996-07-03 |
CA2166160A1 (en) | 1996-06-29 |
CN1131168A (zh) | 1996-09-18 |
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