KR960007726A - 발수 처리제 - Google Patents

발수 처리제 Download PDF

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Publication number
KR960007726A
KR960007726A KR1019950024786A KR19950024786A KR960007726A KR 960007726 A KR960007726 A KR 960007726A KR 1019950024786 A KR1019950024786 A KR 1019950024786A KR 19950024786 A KR19950024786 A KR 19950024786A KR 960007726 A KR960007726 A KR 960007726A
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South Korea
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group
carbon atoms
integer
general formula
monovalent hydrocarbon
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KR1019950024786A
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KR100370899B1 (ko
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미쓰오 아사이
히또시 우에하라
이찌로오 오노
히로아끼 고바야시
쥰 가와구찌
사또시 시이끼
가즈이시 미따니
Original Assignee
카나가와 치히로
신에쓰 가가꾸 고교 가부시끼가이샤
마쯔무라 미노루
닛뽕 이따 가라스 가부시끼가이샤
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Publication of KR100370899B1 publication Critical patent/KR100370899B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/24—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen halogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
    • C08G77/50—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms by carbon linkages
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/14—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Paints Or Removers (AREA)

Abstract

발수 효과 및 물방울의 낙하성 개선 효과가 우수하고, 내구성도 우수하며, 피처리물 표면에 우수한 발포성 및 방오염성을 장기간에 걸쳐 부여하는 발수 처리제를 수득한다.
(1) 다음 일반식(I)로 표시되는 퍼플루오로알킬기 함유 유기 규소 화합물과, 다음 일반식(II)로 표시되는 가수 분해성기 함유 메틸폴리실록산 화합물과의 친수성 용매중에서의 공가수 분해물과, (2) 다음 일반식(III)으로 표시되는 오르가노폴리실록산 및 (3) 강산을 배합한다.
상기 식에서, R1은 탄소원자수 1 내지 4의 1가 탄소수소기이고, R2는 탄소원자수 1 내지 4의 알콕시기 또는 아실옥시기이며, Q는 탄소원자수 2 내지 10의 2가의 유기기이고, a는 0 또는 1이며, P는 1 내지 12의 정수이다. R3은 탄소원자수 1 내지 4의 1가 탄화수소기이고, R4는 탄소원자수 1 내지 4의 알콕시기 또는 아실옥시기이며, A는 메틸기 또는 -Z-Si(R3 b)R4 3-b(여기서 b는 0, 1 또는 2이다.)로 표시되는 기이고, Z는 산소원자 또는 탄소원자수 2 내지 10의 2가의 유기산이다. 또한, m은 3 내지 100의 정수이고, n은 0 내지 50의 정수이며, 또 5≤m+n≤100이고, n=0인 경우에는 양말단의 A의 적어도 어느 한쪽이 -Z-Si(R3 b)R4 3-b로 표시되는 기이다.
상기 식에서, R5는 동일하거나 상이한 탄소원자수 1 내지 20의 1가 탄화수소기이고, B는 동일하거나 상이한 히드록시기 또는 탄소원자수 1 내지 4의 1가 탄화수소기, 알콕시기 또는 아실옥시기이며, r은 1 내지 100의 정수이다.

Description

발수 처리제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (1)

  1. (1) 다음 일반식(I)로 표시되는 퍼플루오로알킬기 함유 유기 규소 화합물과, 다음 일반식(II)로 표시되는 가수 분해성기 함유 메틸폴리실록산 화합물과의 친수성 용매중에서의 공가수 분해물; (2) 아래 일반식(III)으로 표시되는 오르가노폴리실록산; 및 (3) 강산을 배합하여 이루어지는 것을 특징으로 하는 발수 처리제.
    상기 식에서, R1은 탄소원자수 1 내지 4의 1가 탄소수소기이고, R2는 탄소원자수 1 내지 4의 알콕시기 또는 아실옥시기이며, Q는 탄소원자수 2 내지 10의 2가의 유기기이고, a는 0 또는 1이며, P는 1 내지 12의 정수이다. R3은 탄소원자수 1 내지 4의 1가 탄화수소기이고, R4는 탄소원자수 1 내지 4의 알콕시기 또는 아실옥시기이며, A는 메틸기 또는 -Z-Si(R3 b)R4 3-b(여기서 b는 0, 1 또는 2이다.)로 표시되는 기이며, Z는 산소원자 또는 탄소원자수 2 내지 10의 2가의 유기산이고, m은 3 내지 100의 정수이고, n은 0 내지 50의 정수이며, 또 5≤m+n≤100이고, n=0인 경우에는 양말단의 A의 적어도 어느 한쪽이 -Z-Si(R3 b)R4 3-b로 표시되는 기이며, R5는 동일하거나 상이한 탄소원자수 1 내지 20의 1가 탄화수소기이고, B는 동일하거나 상이한 히드록시기 또는 탄소원자수 1 내지 4의 1가 탄화수소기, 알콕시기 또는 아실옥시기이며, r은 1 내지 100의 정수이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950024786A 1994-08-12 1995-08-11 발수처리제 KR100370899B1 (ko)

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Application Number Priority Date Filing Date Title
JP94-212121 1994-08-12
JP21212194 1994-08-12

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KR960007726A true KR960007726A (ko) 1996-03-22
KR100370899B1 KR100370899B1 (ko) 2003-03-19

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EP (1) EP0696627B1 (ko)
KR (1) KR100370899B1 (ko)
DE (1) DE69507551T2 (ko)

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Also Published As

Publication number Publication date
EP0696627A1 (en) 1996-02-14
DE69507551T2 (de) 1999-07-15
US5599893A (en) 1997-02-04
KR100370899B1 (ko) 2003-03-19
DE69507551D1 (de) 1999-03-11
EP0696627B1 (en) 1999-01-27

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