KR910018445A - 필름 형성 공중합체 및 수증기 침투성 피복물에서의 이의 용도 - Google Patents

필름 형성 공중합체 및 수증기 침투성 피복물에서의 이의 용도 Download PDF

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KR910018445A
KR910018445A KR1019910006640A KR910006640A KR910018445A KR 910018445 A KR910018445 A KR 910018445A KR 1019910006640 A KR1019910006640 A KR 1019910006640A KR 910006640 A KR910006640 A KR 910006640A KR 910018445 A KR910018445 A KR 910018445A
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units
sio
monovalent
film forming
organosilicon compound
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KR0167787B1 (ko
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에드워드 크레이 스티븐
로우렌즈 마틴
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원본미기재
다우 코닝 리미티드
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/647Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31652Of asbestos
    • Y10T428/31663As siloxane, silicone or silane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2139Coating or impregnation specified as porous or permeable to a specific substance [e.g., water vapor, air, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2221Coating or impregnation is specified as water proof
    • Y10T442/223Organosilicon containing

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Laminated Bodies (AREA)
  • Paints Or Removers (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Silicon Polymers (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)

Abstract

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Description

필름 형성 공중합체 및 수증기 침투성 피복물에서의 이의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 유리 실리콘 화합물이 필수적으로 4가 sio2단위와 1가 R3SIO1/2및 R1R2SiO1/2단위[여기서, 4가 단위에 대한 1가 단위의 비는 0. 4/1내지 2/1이고, 유기 실리콘 화합물 속에 존재하는 모든 1가 단위의 40내지 90%는 R′R2SiO1/2단위[여기서, R은 탄소원자수가 8개까지인 1가 탄화수소 그룹이고, R′은 하이드록실 그룹에 의해 종결되는 폴리옥시알킬렌 그룹이다)이다]로 이루어짐을 특징으로 하는, 100중량부의 경화성 폴리우레탄 수지와 10내지 100중량부가 유기 실리콘 화합물을 공중합시킴으로써 형성된 형성된 필름 형성 공중합체.
  2. 제1항에 있어서, 폴리 우레탄 수지가 용액 또는 분산액으로서 제공되는 경우에 고체 함량의 범위가 35내지 50중량%이수성 성분 폴리 우레탄 수지임을 특징으로 하는 필름 형성 공중합체.
  3. 제1항에 있어서, 폴리우레탄 수지가 용액 또는 분산액으로서 제공되는 경우에 고체 함량의 범위가 35내지 50중량%인 용매계 2성분 폴리우레탄 수지임을 추가의 특징으로 하는 필름 형성 공중합체.
  4. 제1항 내지 제3항 중의 어느 한 항에 있어서, 유기 실리콘 화합물 속의 모든 R그룹의 적어도 80%가 저급알킬 또는 아릴 그룹임을 추가의 특징으로 하는 필름 형성 공중합체.
  5. 제1항 내지 제4항중의 어느 한 항에 있어서, 그룹 R′에서 모든 옥시 알킬렌 그룹의 적어도 80%는 옥시에킬렌 그룹이고 폴리옥시알킬렌 그룹을 -SIC-결합을 경유하여 실리콘 원자에 결합시킴을 추가의 특징으로 하는 필름 형성 공중합체.
  6. 제1항 내지 제5항 중의 어느 한 항에 있어서, 폴리옥시알킬렌 그룹의 분자량이 300내지 1000임을 추가의 특징으로 하는 필름 형성 공중합체.
  7. 제1항 내지 제6항중의 어느 한항에 있어서, 유기 실리콘 화합물 속에 존재하는 모든 1가 단위의 40내지 90%기 일반식 R′R2SiO1/2의 단위임을 추가의 특징으로 하는 필름 형성 공중합체.
  8. 제1항 내지 제7항중의 어느 한항에 있어서, 유기 실리 화합물 속의 4가 실록산 단위에 대한 1가 실록산 단위의 비가 1. 3/1 내지 1.8/1임을 추가의 특징으로 하는 필름 형성 공중합체.
  9. 제1항 내지 제8항중의 어느 한항에 있어서, 15내지 70부의 유기 실리콘 화합물을 100중량부의 폴리우레탄 수지에 대하여 사용함을 추가의 특징으로 하는 필름 형성 공중합체.
  10. 100중량부의 경화성 폴리우레탄 수지의 필수적으로 4가 SiO2단위와 R3SiO1/2및 R′R2SiO1/2단위[여기서, 4가 단위에 대한 1가 단위의 비는 0. 4/1 내지 2/1이고, 유기 실리콘 화합물속에 존재하는 모든 1가 단위의 40내지 90%는 R′R2SiO1/2단위(여기서, R은 탄소원자수가 8개 까지인 1가 탄화수소 그룹이고 R′는 하이드록실 그룹에 의해 종결된 폴리옥시알킬렌 그룹이다)이다]로 이루어진 25내지 100중량부의 유기 실리콘 화합물을 포함하는 조성물을 직물에 가한 다음, 조성물을 직물에 접착하는 필름에 경화시킴을 포함함을 특징으로 하여 직물을 방수 피복물로 처리하는 방법.
  11. 100중량부의 경화성 폴리우레탄 수지와 필수적으로 4가 SiO2단위와 1가 R3SiO1/2및 R′R3SiO1/2단위[여기서, 4가 단위에 대한 1가 단위의 비는 0.4/1 내지 2/1이고 유기 실리콘 화합물속에 존재하는 모든 1가 단위의 40내지 90%는 R′R2SiO1/2단위(여기서, R은 탄수원자수가 8개까지인 1가 탄화수소 그룹이고 R′은 하이드록실 그룹에 의해 종결된 폴리옥시알킬렌 그룹이다)이다]로 이루어진 10내지 100중량부의 유기 실리콘 화합물을 포함함을 조성물로부터 자체 보조 공중합체를 형성시킴을 포함함을 특징으로 하여 직물을 방수 피복물로 처리하는 방법.
  12. 제1항 내지 제9항 중의 어느 한 항에 따르는 필름 형성 공중합체를 사용하여 피복시킨 기질 또는 직물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910006640A 1990-04-26 1991-04-25 필름 형성 공중합체 및 수증기 침투성 피복물에서의 이의 용도 KR0167787B1 (ko)

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GB9009409.5 1990-04-26
GB909009409A GB9009409D0 (en) 1990-04-26 1990-04-26 Film-forming copolymers and their use in water vapour permeable coatings

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KR910018445A true KR910018445A (ko) 1991-11-30
KR0167787B1 KR0167787B1 (ko) 1999-03-20

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US (2) US5169906A (ko)
EP (1) EP0454391B1 (ko)
JP (1) JPH04227717A (ko)
KR (1) KR0167787B1 (ko)
CA (1) CA2039076C (ko)
DE (1) DE69102096T2 (ko)
ES (1) ES2055536T3 (ko)
GB (1) GB9009409D0 (ko)

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ES2055536T3 (es) 1994-08-16
EP0454391A3 (en) 1993-01-13
US5169906A (en) 1992-12-08
EP0454391B1 (en) 1994-05-25
DE69102096T2 (de) 1994-10-06
US5310597A (en) 1994-05-10
GB9009409D0 (en) 1990-06-20
CA2039076A1 (en) 1991-10-27
KR0167787B1 (ko) 1999-03-20
EP0454391A2 (en) 1991-10-30
DE69102096D1 (de) 1994-06-30
CA2039076C (en) 1999-03-30
JPH04227717A (ja) 1992-08-17

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