KR950011480A - 올레핀 중합용 성분 및 촉매 - Google Patents

올레핀 중합용 성분 및 촉매 Download PDF

Info

Publication number
KR950011480A
KR950011480A KR1019940025210A KR19940025210A KR950011480A KR 950011480 A KR950011480 A KR 950011480A KR 1019940025210 A KR1019940025210 A KR 1019940025210A KR 19940025210 A KR19940025210 A KR 19940025210A KR 950011480 A KR950011480 A KR 950011480A
Authority
KR
South Korea
Prior art keywords
radicals
radical
cycloalkyl
alkyl
aryl
Prior art date
Application number
KR1019940025210A
Other languages
English (en)
Other versions
KR100347974B1 (ko
Inventor
모리니 지암삐에로
알비자띠 엔리꼬
지안니니 움베르또
스코르다마글리아 레이몬도
바리노 루이자
Original Assignee
케빈 이. 왈쉬
히몬트 인코포레이티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 케빈 이. 왈쉬, 히몬트 인코포레이티드 filed Critical 케빈 이. 왈쉬
Publication of KR950011480A publication Critical patent/KR950011480A/ko
Application granted granted Critical
Publication of KR100347974B1 publication Critical patent/KR100347974B1/ko

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0204—Ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0205—Oxygen-containing compounds comprising carbonyl groups or oxygen-containing derivatives, e.g. acetals, ketals, cyclic peroxides
    • B01J31/0208—Ketones or ketals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
    • C07C45/455—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation with carboxylic acids or their derivatives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/04—Saturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/12—Ketones containing more than one keto group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/782—Ketones containing a keto group bound to a six-membered aromatic ring polycyclic
    • C07C49/784—Ketones containing a keto group bound to a six-membered aromatic ring polycyclic with all keto groups bound to a non-condensed ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

하기식의 1,3-디케톤에서 선택된 전자 공여 화합물, 티탄 화합물 및 활성형태의 할로켄화 마그네슘을 포함하는 고형 촉매성분과 Al-알킬 화합물간의 반응 생성물을 포함하는 올레핀 중합용 촉매를 개시한다.
[상기 식중, R라디칼은 동일 또는 상이하고, RI라디칼도 동일 또는 상이하며 R및 Rl은 Cl∼C40알킬, C3-C20시클로알릴, C6-C20아킬, C7-C20아릴알킬 또는 알킬아릴 라디칼 또는 수소이고, 단, 1개 이상의 R라디칼은 수소가 아니며, 다른 R라디칼과 결합하여 고리형 구조를 이룰 수 있으며, 서로 결합하여 고리형 구조를 이루지 않는 1개 이상의 라디칼 RI은 측쇄알킬, 시클로알킬 또는 아릴 라디칼이거나, 1또는 2개의 R라디칼과 결합하여 고리형 구조를 형성한다].

Description

올레핀 중합용 성분 및 촉매
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 활성 형태의 할로겐화 마그네슘을 포함하고, 이 할로겐화 마그네슘상에 담지된, 할로겐화 티탄 또는 티탄 할로겐 알콜레이트 및 하기식 (I)의 1,3-디케톤에서 선택된 전자 공여 화합물물 포함하며, 표준 방법을 사용하여 제조할때, 촉매 성분상에 고정되는 성질을 지닌 상기 1, 3-디케톤이 상기 촉매 성분상에 담지된 1, 3-디케톤과 티탄 사이의 몰비가 0.1 이상이 되도록 하는 양으로 포함됨을 특징으로 하는 올레핀 중합용 고형촉매성분.
    [상기 식중, R라디칼은 동일 또는 상이하고, RI라디칼도 동일 또는 상이하며 R및 Rl은 C1∼C20알킬, C3-C20시클로알킬, C6∼C20아릴, C7∼C20아릴알킬 또는 알킬아릴 라디칼 또는 수소이고, 단, 1개 이상의 R라디칼은 수소가 아니며, 다른 R 라디칼과 결합하여 고리형 구조를 이룰 수 있으며, 서로 결합하여 고리형 구조를 이루지 않는 1개 이상의 라디칼 RI은 측쇄알킬, 시클로알킬 또는 아릴 라디칼이거나, 1또는 2개의 R 라디칼과 결합하여 고리형 구조를 형성한다].
  2. 제1항에 있어서, 할로겐화 마그네슘이 염화 마그네슘이고, 할로겐화 티탄이 사염차 티탄임을 특징으로 하는 고형 촉매 성분.
  3. 제1항에 있어서, 하기식 (Ⅱ) 또는 (Ⅲ)의 1,3-티케톤에서 전자 공여 화합물을 선택함을 특징으로 하는 고형 촉매 성분 :
    [상기 식중, 1개 이상의 Rl라디칼은 동일 또는 상이하며, 카르보닐기에 결합된 3급 또는 4급 탄소원자를 지닌 측쇄 C3∼C20라디칼 이거나, C3-Cl8시클로알킬 또는 C6∼C18아릴 라디칼이고, 다른 Rl라디칼은 전술한 바와 같거나, Cl∼C20알킬, C4∼C20시클로알킬 또는 C7∼C20아릴알킬 라디칼이고 ; R은 Cl∼Cl2알킬, Cl∼Cl2알킬, C3∼Cl2시클로알킬, C6-Cl2아릴 또는 C4∼Cl2시클로알킬라디칼 이거나; 1개 이상의 Rl라디칼이 R 라디칼에 결합하여 고리형 구조를 형성한다]
    [상기 식중, R및 Rl라디칼은 동일 또는 상이하고, Cl∼C20알킬, C3-C20시클로알킬, C6∼C20아릴, C4∼C20시클로알킬알킬 또는 C7-C20아릴알킬 라디칼에서 선택되거나, R 라디칼이 서로 결합하여 고리형 구조를 이루고, 단, 1개 이상의 RI은 촉쇄알킬, 시클로알킬 또는 아릴 라디칼이거나, 1개 이상의 Rl라디칼이 1또는 2개의 R 라디칼과 결합하여 고리형 구조를 형성한다].
  4. 제3항에 있어서, 2.2,4,6,6-펜타메틸 -3,5-헵탄디온 및 2,2,6,6-테트라메틸 -4-에틸-3,5-헬탄디온 에서 전자 공여 화합물을 선택함을 특징으로 하는 고형 촉매 성분.
  5. Al-알킬 화합물과 제1항에서 청구된 고형 촉매 성분간의 반응 생성물을 포함하는 올레핀 중합용 촉매.
  6. 제5항에 있어서, 외부 전자 공여 화합물을 촉매에 첨가함을 특징으로 하는 촉매.
  7. 제6항에 있어서, 2.2,6,6-테트라메틸피페리딘, 2,2,5,5-테트라메틸피롤리딘; Al-디에틸-2,2,6,6-테트라메틸피페리다이드, Al-디클로로모노페녹시 및 하기식의 화합물로 부터 외부 전자 공여체를 선택함을 특징으로 하는 촉매 :
    RmSiYnXp
    [상기 식에서, R은 C1∼C20알킬, C2∼C20알켄, C6∼C20아릴, C7∼C20아릴알킬 또는 C3∼C20시크로알킬이고; Y는 -OR', -OCOR', -NR'2라디칼(여기에서, R'는 R과 동일 또는 상이하며 R과 동일한 의미를 갖는다)이며; X는 할로겐 또는 수소원자 이거나 -OCOR" 또는 -NR"2기 (여기에서, R"는 R'과 동일 또는 상이하고, R'과 동일한 의미를 갖는다)이고; m, n 및 p는 m이 0∼3, n이 1∼4, p가 0∼1인 수이며, m+n+p=4이다).
  8. 제6항에 있어서, 외부 전자 공여체가 하기식의 1,3-디에테르임을 특징으로 하는 촉매 :
    [상기 식중 R, Rl, RⅡ, RⅢ, RⅣ및 Rv는 동일 또는 상이하고, H 또는 탄소수 1∼18의, 직쇄 또는 측쇄 알킬, 시클로알킬, 아릴, 알킬아릴 또는 아릴알킬 라디칼이며 : RⅥ및 RⅦ는 수소를 제외하고, R∼Rv의 라디칼과 동일한 의미를 지니며: 단. R및 Rl라디칼의 1개 이상은 수소와 다르며, Rl-Rv의 라디칼이 수소이고. RⅥ과 RⅦ이 메틸인 경우, R은 메틸이 아니고: R∼RⅦ라디칼의 1개 이상이 결합하여 고리형 구조를 이룰수 있다].
  9. 하기식 (Ⅱ)의 1,3-디케톤 화합물 :
    [상기 식중, 1개 이상외 Rl라디칼은 동일 또는 상이하며, 카르보닌기에 결합된 3급 또는 4급 탄소원자를 지닌 측쇄 C3-C20라디칼 이거나, C3-Cl8시클로알킬 또는 C6∼C18아필 라디칼이고, 다른 Rl라디칼은 전술한 바와 같거나, C1-C20알킬, C4∼C20시클로알킬 또는 C7∼C2O아릴알킬 라디칼이고; R은 Cl∼C12알킬, C3∼Cl2시클로알킬, C6∼C12아릴 또는 C4∼C12시클로알킬라디칼 이거나; 1개 이상의 Rl라디칼이 R 라디칼에 결합하여 고리형 구조틀 형성한다].
  10. 하기식(Ⅲ)의 1,3-디케톤 화합물 :
    [상기 식중, R및 Rl라디칼은 동일 또는 상이하고, Cl∼C20알킬, C3-C2O시클로알킬, C6∼C2O아릴, C4∼C20시클로알킬알킬 또는 C7-C20아릴알킬 라디칼이거나, R 라디칼이 서로 결합하여 고리형 구조를 이루고, 단, 1개 이상의 Rl라디칼은 측쇄알킬, 시클로알킬 또는 아릴 라디칼이거나, 1개 이상의 RI라디칼이 1 또는 2개의 R 라디칼과 결합하여 고리형 구조를 형성한다].
  11. 2,2,4,6,6-펜타메틸-3,5-헵탄디온.
  12. 2,2,6,6-테트라메틸-4-에틸-3.5-헵탄디온
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940025210A 1993-10-01 1994-10-01 올레핀중합용성분및촉매 KR100347974B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI93A002102 1993-10-01
ITMI932102A IT1270842B (it) 1993-10-01 1993-10-01 Componenti e catalizzatori per la polimerizzazione di olefine

Related Child Applications (1)

Application Number Title Priority Date Filing Date
KR1020010084218A Division KR100368786B1 (ko) 1993-10-01 2001-12-24 올레핀 중합용 성분 및 촉매

Publications (2)

Publication Number Publication Date
KR950011480A true KR950011480A (ko) 1995-05-15
KR100347974B1 KR100347974B1 (ko) 2002-11-22

Family

ID=11366974

Family Applications (2)

Application Number Title Priority Date Filing Date
KR1019940025210A KR100347974B1 (ko) 1993-10-01 1994-10-01 올레핀중합용성분및촉매
KR1020010084218A KR100368786B1 (ko) 1993-10-01 2001-12-24 올레핀 중합용 성분 및 촉매

Family Applications After (1)

Application Number Title Priority Date Filing Date
KR1020010084218A KR100368786B1 (ko) 1993-10-01 2001-12-24 올레핀 중합용 성분 및 촉매

Country Status (15)

Country Link
US (1) US5468704A (ko)
EP (1) EP0646605B1 (ko)
JP (2) JP3688308B2 (ko)
KR (2) KR100347974B1 (ko)
CN (2) CN1054139C (ko)
AT (1) ATE180793T1 (ko)
AU (1) AU677422B2 (ko)
BR (1) BR9403967A (ko)
CA (1) CA2133352A1 (ko)
DE (1) DE69418808T2 (ko)
DK (1) DK0646605T3 (ko)
ES (1) ES2133459T3 (ko)
FI (1) FI112237B (ko)
IT (1) IT1270842B (ko)
TW (1) TW264486B (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160064597A (ko) * 2014-11-28 2016-06-08 한화토탈 주식회사 프로필렌 중합용 고체촉매 및 이를 이용한 폴리프로필렌 제조 방법

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5916990A (en) * 1994-05-12 1999-06-29 Showa Denko K.K. Propylene-based polymer, method of its production, composition thereof, catalyst component for polymerization, and method for its production
AU706739B2 (en) * 1994-05-12 1999-06-24 Showa Denko Kabushiki Kaisha A method for the production of propylene-based polymers, catalyst component or polymerization and method for its production
US6184328B1 (en) 1994-09-07 2001-02-06 Showa Denko Kabushiki Kaisha Propylene-based polymer, method for its production, composition thereof, catalyst component for polymerization, and method for its production
IT1274253B (it) * 1995-02-21 1997-07-15 Himont Inc Processo per la preparazione di componenti catalitici solidi per la polimerizzazione di olefine
CN1063188C (zh) * 1996-12-17 2001-03-14 中国科学院化学研究所 一种合成间规聚苯乙烯催化剂体系及其制法
IE980775A1 (en) 1998-09-17 2000-03-22 Loctite R & D Ltd Auto-oxidation systems for air-activatable polymerisable compositions
CN100362026C (zh) * 2000-03-30 2008-01-16 住友化学株式会社 烯烃聚合用催化剂的制备方法和烯烃聚合物的制备方法
SG96207A1 (en) 2000-03-30 2003-05-23 Sumitomo Chemical Co Process for producing catalyst for olefin polymerization and process for producing olefin polymer
CN1318457C (zh) * 2004-09-02 2007-05-30 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分和催化剂
CN100338018C (zh) * 2004-10-29 2007-09-19 中国石油化工股份有限公司 一种环戊酯类化合物及其合成方法和应用
CN101139407B (zh) * 2006-09-07 2010-10-06 北京金鼎科化工科技有限公司 一种用于乙烯聚合或共聚合的催化剂前体及其制备方法
CN101412775B (zh) * 2007-10-15 2010-12-22 北京金鼎科化工科技有限公司 一种用于丙烯聚合或共聚合的催化剂前体及其制备方法
EP2070954A1 (en) * 2007-12-14 2009-06-17 Total Petrochemicals Research Feluy Process for the production of a propylene polymer having a broad molecular weight distribution and a low ash content
EP2093315A1 (en) * 2008-02-22 2009-08-26 Total Petrochemicals Research Feluy Fibres and nonwoven prepared from polypropylene having a large dispersity index
CN101671410B (zh) * 2008-09-11 2011-12-28 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其催化剂
EP2679609A1 (en) 2012-06-28 2014-01-01 Lummus Novolen Technology Gmbh Sterically demanding dialkoxydialkylsilanes as external donors for ziegler catalysts for the polymerization of propylene
CN105330774B (zh) * 2014-06-24 2017-10-03 中国石油化工股份有限公司 一种宽立构规整度分布聚丙烯的制备方法及得到的聚丙烯
CN105330772A (zh) * 2014-06-24 2016-02-17 中国石油化工股份有限公司 一种聚丙烯立构规整度调节剂及其应用
CN108059689B (zh) * 2016-11-09 2020-05-08 中国石油天然气股份有限公司 烯烃聚合前催化剂组合物及其制备方法、烯烃聚合催化剂组合物
WO2018161854A1 (zh) 2017-03-10 2018-09-13 北京利和知信科技有限公司 用于烯烃聚合的固体催化剂组分、催化剂及其应用
CN110950985B (zh) * 2018-09-26 2022-01-04 中国石油化工股份有限公司 一种用于烯烃聚合的催化剂组分、催化剂及烯烃聚合方法
CN110950983B (zh) * 2018-09-26 2022-01-04 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分、催化剂及烯烃聚合方法
ES2877132T3 (es) 2019-06-14 2021-11-16 Sky Light As Elemento flexible para formar un cubierto desechable
KR20230043174A (ko) 2020-08-26 2023-03-30 미쓰이 가가쿠 가부시키가이샤 에스터 화합물
EP4265593A1 (en) 2020-12-21 2023-10-25 Mitsui Chemicals, Inc. Ester compound
CN116041577A (zh) 2021-10-28 2023-05-02 中国石油化工股份有限公司 烯烃聚合催化剂组分、催化剂体系及应用和烯烃聚合方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL8002599A (nl) * 1980-05-07 1981-12-01 Stamicarbon Werkwijze voor de bereiding van een polymerisatiekatalysator en bereiding van etheenpolymeren daarmee.
US4540680A (en) * 1980-11-24 1985-09-10 National Distillers And Chemical Corporation Intermetallic compounds of polymeric transition metal oxide alkoxides and catalytic use thereof
IT1190683B (it) * 1982-02-12 1988-02-24 Montedison Spa Componenti e catalizzatori per la polimerizzazione di olefine
JPH0686490B2 (ja) * 1985-04-05 1994-11-02 三菱油化株式会社 オレフイン重合体の製造法
IT1227258B (it) * 1988-09-30 1991-03-28 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
JP2805344B2 (ja) * 1989-07-11 1998-09-30 昭和電工株式会社 オレフィン重合触媒の製造方法およびオレフィンの重合方法
IT1241093B (it) * 1990-03-30 1993-12-29 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160064597A (ko) * 2014-11-28 2016-06-08 한화토탈 주식회사 프로필렌 중합용 고체촉매 및 이를 이용한 폴리프로필렌 제조 방법

Also Published As

Publication number Publication date
DE69418808D1 (de) 1999-07-08
EP0646605A1 (en) 1995-04-05
CN1105671A (zh) 1995-07-26
CN1138743C (zh) 2004-02-18
DE69418808T2 (de) 1999-10-07
JP3847768B2 (ja) 2006-11-22
EP0646605B1 (en) 1999-06-02
CN1054139C (zh) 2000-07-05
ITMI932102A0 (it) 1993-10-01
AU7435094A (en) 1995-04-13
AU677422B2 (en) 1997-04-24
FI944573A (fi) 1995-04-02
KR100347974B1 (ko) 2002-11-22
CA2133352A1 (en) 1995-04-02
JPH07233209A (ja) 1995-09-05
US5468704A (en) 1995-11-21
JP2005226076A (ja) 2005-08-25
ATE180793T1 (de) 1999-06-15
TW264486B (ko) 1995-12-01
KR100368786B1 (ko) 2003-01-24
JP3688308B2 (ja) 2005-08-24
BR9403967A (pt) 1995-06-27
FI112237B (fi) 2003-11-14
ES2133459T3 (es) 1999-09-16
ITMI932102A1 (it) 1995-04-01
FI944573A0 (fi) 1994-09-30
DK0646605T3 (da) 1999-06-23
CN1257061A (zh) 2000-06-21
IT1270842B (it) 1997-05-13

Similar Documents

Publication Publication Date Title
KR950011480A (ko) 올레핀 중합용 성분 및 촉매
KR910007973A (ko) 헤미이소택틱 폴리프로필렌 제조용 촉매
KR910014404A (ko) 올레핀 중합용 촉매 성분 및 이로부터 수득되는 촉매
KR960031489A (ko) 올레핀 중합용 촉매 성분 및 촉매
KR900011794A (ko) 올레핀류의 중합용 촉매
KR940014423A (ko) 플루오레닐형 리간드를 갖는 메탈로센 화합물
KR890008153A (ko) 가교구조의 비스치환된 시클로펜타디에닐 배위자를 갖는 천이금속 화합물
TW286321B (ko)
JPS6445406A (en) Polymerization of ethylene
ES485256A1 (es) Procedimiento para la preparacion de catalizadores para la polimerizacion de olefinas
KR970074808A (ko) 엘라스토머 ep(d)m 공중합체의 제조 방법
KR910014403A (ko) 올레핀 제조용 촉매성분 및 촉매
KR970702100A (ko) 고활성 폴리에틸렌 촉매(high activity polyethylene catalysts)
KR920005724A (ko) 폴리올레핀의 제조방법
WO2001025297B1 (en) Unsaturated nitrogenous compounds as electron donors for use with ziegler-natta catalysts
KR950032301A (ko) 중합 촉매로서 유용한 고체 오가노알루미녹시 생성물의 제조 방법
KR960037693A (ko) 다핵 메탈로센 화합물, 이의 제조 방법 및 촉매로서의 이의 용도
EP0955304A3 (en) Bridged metallocene complex for the (co)polymerization of olefins
KR940003970A (ko) 올레핀 중합촉매에 대한 활성감소제
KR960041200A (ko) 유기 금속 화합물
KR920018083A (ko) 올레핀 중합용 촉매 및 성분
ATE223444T1 (de) Hochaktive polyethylenkatalysatoren
KR960041199A (ko) 유기금속 화합물
KR970006310A (ko) 메탈로센 화합물
KR970021102A (ko) 올레핀 중합용 촉매 성분의 제조 방법, 올레핀 중합용 촉매, 및 상기 촉매를 이용한 올레핀 중합체의 제조 방법

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
A107 Divisional application of patent
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20080722

Year of fee payment: 7

LAPS Lapse due to unpaid annual fee