KR930016493A - 반도체소자 밀봉용 에폭시수지 조성물 - Google Patents

반도체소자 밀봉용 에폭시수지 조성물 Download PDF

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KR930016493A
KR930016493A KR1019920000704A KR920000704A KR930016493A KR 930016493 A KR930016493 A KR 930016493A KR 1019920000704 A KR1019920000704 A KR 1019920000704A KR 920000704 A KR920000704 A KR 920000704A KR 930016493 A KR930016493 A KR 930016493A
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epoxy resin
resin composition
semiconductor device
imide
positive integer
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KR1019920000704A
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KR960010845B1 (ko
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김환건
이지윤
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이대원
제일모직 주식회사
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Priority to KR1019920000704A priority Critical patent/KR960010845B1/ko
Priority to JP4281187A priority patent/JP2501071B2/ja
Priority to US08/001,082 priority patent/US5266612A/en
Publication of KR930016493A publication Critical patent/KR930016493A/ko
Priority to KR1019960012981A priority patent/KR960007929B1/ko
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Publication of KR960010845B1 publication Critical patent/KR960010845B1/ko

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D405/00Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/14Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing three or more hetero rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32Epoxy compounds containing three or more epoxy groups
    • C08G59/3236Heterocylic compounds
    • C08G59/3245Heterocylic compounds containing only nitrogen as a heteroatom
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/12Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/24Ethers with hydroxy compounds containing no oxirane rings with polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32Epoxy compounds containing three or more epoxy groups
    • C08G59/3227Compounds containing acyclic nitrogen atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1003Preparatory processes
    • C08G73/1007Preparatory processes from tetracarboxylic acids or derivatives and diamines
    • C08G73/101Preparatory processes from tetracarboxylic acids or derivatives and diamines containing chain terminating or branching agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1046Polyimides containing oxygen in the form of ether bonds in the main chain
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1046Polyimides containing oxygen in the form of ether bonds in the main chain
    • C08G73/1053Polyimides containing oxygen in the form of ether bonds in the main chain with oxygen only in the tetracarboxylic moiety
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/04Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C08L79/08Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/28Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection
    • H01L23/29Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection characterised by the material, e.g. carbon

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
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  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
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  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Epoxy Resins (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Structures Or Materials For Encapsulating Or Coating Semiconductor Devices Or Solid State Devices (AREA)

Abstract

본 발명은 에폭시수지, 경화제, 경화촉진제, 무기충진제, 가소성부여제로 이루어진 에폭시 조성물에 일반식(Ⅰ)의 아미드 에폭시수지를 전체 조성물에 대해 0.1 내지 20중량% 함유시켜서된 내열성 및 내습성등이 향상된 반도체소자 밀봉용 에폭시수지 조성물에 관한 것이다.
(여기에서 R1,R2는 H 또는 (CH2)nCH3기이고 n은 0 또는 1 이상의 양의 정수이다.)

Description

반도체소자 밀봉용 에폭시수지 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. 크레졸노블락형 에폭시수지와 경화제, 경화촉진제, 무기충진제로 이루어지는 반도체소자 밀봉용 에폭시수지 조성물에 있어서, 하기 일반식(Ⅰ)으로 표시되는 이미드-에폭시수지가 첨가됨을 특징으로하는 내열성 및 내습성이 향상된 반도체소자 밀봉용 에폭시수지 조성물.
    (여기에서 R1,R2는 H 또는 (CH2)nCH3기이고 n은 0 또는 1 이상의 양의 정수이다.)
  2. 제1항에 있어서, 상기 이미드-에폭시수지는 전체 수지조성물에 대하여 0.1-20.0중량% 만큼 첨가되는 것을 특징으로 하는 반도체 소자 밀봉용 에폭시수지 조성물.
  3. 하기 구조식(Ⅱ)의 에폭시수지를 유기용매중에서 소량의 촉매와 1-브로모-2,5-피롤리딘디온을 적하하여 브롬치환 에폭시수지를 수득하고, 이를 알콕시아민과 반응시켜 아민이 치환된 에폭시수지를 얻은후, 다시 하기 구조식(Ⅲ)의 말레이미드와 반응시켜 하기 일반식(Ⅰ)의 아미드 에폭시수지를 얻는 것을 특징으로 하는 이미드 에폭시수지의 제조방법.
    (여기에서 R1,R2는 H 또는 (CH2)nCH3기이고 n은 0 또는 1 이상의 양의 정수이다.)
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920000704A 1992-01-18 1992-01-18 반도체소자 밀봉용 에폭시수지 조성물 KR960010845B1 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
KR1019920000704A KR960010845B1 (ko) 1992-01-18 1992-01-18 반도체소자 밀봉용 에폭시수지 조성물
JP4281187A JP2501071B2 (ja) 1992-01-18 1992-10-20 半導体素子密封用エポキシ樹脂組成物
US08/001,082 US5266612A (en) 1992-01-18 1993-01-06 Imide epoxy resin composition for sealing semiconductor elements
KR1019960012981A KR960007929B1 (ko) 1992-01-18 1996-04-25 이미드 에폭시수지의 제조방법

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019920000704A KR960010845B1 (ko) 1992-01-18 1992-01-18 반도체소자 밀봉용 에폭시수지 조성물

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KR1019960012981A Division KR960007929B1 (ko) 1992-01-18 1996-04-25 이미드 에폭시수지의 제조방법

Publications (2)

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KR930016493A true KR930016493A (ko) 1993-08-26
KR960010845B1 KR960010845B1 (ko) 1996-08-09

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KR1019920000704A KR960010845B1 (ko) 1992-01-18 1992-01-18 반도체소자 밀봉용 에폭시수지 조성물
KR1019960012981A KR960007929B1 (ko) 1992-01-18 1996-04-25 이미드 에폭시수지의 제조방법

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EP1763569B1 (de) * 2004-07-02 2018-01-17 Merck Patent GmbH Flüssigkristallmedium und dieses enthaltende elektrooptische anzeige
US8310442B2 (en) 2005-02-23 2012-11-13 Pixtronix, Inc. Circuits for controlling display apparatus
US8519945B2 (en) 2006-01-06 2013-08-27 Pixtronix, Inc. Circuits for controlling display apparatus
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US9261694B2 (en) 2005-02-23 2016-02-16 Pixtronix, Inc. Display apparatus and methods for manufacture thereof
US9229222B2 (en) * 2005-02-23 2016-01-05 Pixtronix, Inc. Alignment methods in fluid-filled MEMS displays
US8482496B2 (en) 2006-01-06 2013-07-09 Pixtronix, Inc. Circuits for controlling MEMS display apparatus on a transparent substrate
US9158106B2 (en) 2005-02-23 2015-10-13 Pixtronix, Inc. Display methods and apparatus
US20070205969A1 (en) 2005-02-23 2007-09-06 Pixtronix, Incorporated Direct-view MEMS display devices and methods for generating images thereon
US7999994B2 (en) 2005-02-23 2011-08-16 Pixtronix, Inc. Display apparatus and methods for manufacture thereof
US9082353B2 (en) 2010-01-05 2015-07-14 Pixtronix, Inc. Circuits for controlling display apparatus
US8526096B2 (en) 2006-02-23 2013-09-03 Pixtronix, Inc. Mechanical light modulators with stressed beams
US9176318B2 (en) 2007-05-18 2015-11-03 Pixtronix, Inc. Methods for manufacturing fluid-filled MEMS displays
US8169679B2 (en) 2008-10-27 2012-05-01 Pixtronix, Inc. MEMS anchors
EP2531997A1 (en) 2010-02-02 2012-12-12 Pixtronix Inc. Circuits for controlling display apparatus
EP2826777B1 (en) 2012-03-14 2020-08-05 Korea Institute of Industrial Technology Epoxy compound having alkoxy silyl group, composition comprising same, cured product, use thereof and method for preparing epoxy compound having alkoxy silyl group
US9134552B2 (en) 2013-03-13 2015-09-15 Pixtronix, Inc. Display apparatus with narrow gap electrostatic actuators
KR102232340B1 (ko) 2019-11-15 2021-03-26 한국생산기술연구원 알콕시실릴기를 갖는 에폭시 수지의 조성물 및 이의 복합체

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KR960005064B1 (ko) * 1991-09-26 1996-04-20 제일모직주식회사 신규한 이미드-에폭시수지와 그 제조방법

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Publication number Publication date
US5266612A (en) 1993-11-30
JP2501071B2 (ja) 1996-05-29
KR960010845B1 (ko) 1996-08-09
JPH07188384A (ja) 1995-07-25
KR960007929B1 (ko) 1996-06-17

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