KR930009650A - 망간 촉매 - Google Patents

망간 촉매 Download PDF

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Publication number
KR930009650A
KR930009650A KR1019920022432A KR920022432A KR930009650A KR 930009650 A KR930009650 A KR 930009650A KR 1019920022432 A KR1019920022432 A KR 1019920022432A KR 920022432 A KR920022432 A KR 920022432A KR 930009650 A KR930009650 A KR 930009650A
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manganese
group
groups
composition
catalyst
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KR1019920022432A
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KR960008938B1 (ko
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마리에 해리 옷-주렐러 샤론
린네 커쉬너 주디스
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원본미기재
유니레버 엔브이
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Priority to KR1019960005435A priority Critical patent/KR960015159B1/ko
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3932—Inorganic compounds or complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Detergent Compositions (AREA)
  • Catalysts (AREA)

Abstract

본 발명은 신규한 표백 및 산화촉매, 이러한 촉매를 함유하는 표백세제 조성물, 및 기질로부터 오염을 제거시키는 방법에 관한 것이다. 본 발명의 촉매는 다음과 같은 일반식(A)을 가지는 망간 착화합물이다.
[LMnIV(OR)3]Y (A)
이식에서 Mn은 산화수가 +4인 망간이며, R은 알킬기, 시클로알키기, 아릴기, 벤질기 및 이러한 기의 혼합체 중에서 선택되는 C1-C20인 기이고, 또한 2이상의 R 기의 망간과 배위결합하는 두산소사이에 브리징 단위를 형성 하도록 서로 결합될 수 있으며, L은 망간과 배위결합하는 3이상의 질소원자를 가지는 C3-C60인 기로부터 선택되는 리간드이고, Y는 산화적으로 안정한 카운터이온다.

Description

망간촉매
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. 다음과 같은 일반식(A)을 가지는 촉매.
    [LMnIV(OR)3]Y (A)
    (이식에서 Mn은 산화수가 +4인 망간이며, R은 알킬기, 시클로알키기, 아릴기, 벤질기 및 이러한 기의 혼합체 중에서 선택되는 C1-C20인 기이고, 또한 2이상의 R기의 망간과 배위결합하는 두 산소사이에 브리징 단위를 형성 하도록 서로 결합될 수 있으며, L은 망간과 배위결합하는 3이상의 질소원자를 가지는 C3-C60인 기로부터 선택되는 리간드이고, Y는 산화적으로 안정한 카운터이온임.)
  2. 제1항에 있어서, 리간드(L)는 1, 4, 7 - 트리메틸 - 1, 4, 7 - 트리아자시클로노난 및 2 - 메틸 - 1, 4, 7 - 트리메틸 - 1, 4, 7 - 트리아자시클로노난으로부터 선택되는 것을 특징으로 하는 촉매.
  3. 제1항에 있어서, Mn(IV) (Me3TACN) (OCH3)3(PF6)인 촉매.
  4. 다음과 같은 물질을 함유하는 표백조성물.
    (i) 약 1-약 60중량%의 퍼옥시 화합물, (ii) 퍼옥시화합물의 표백활성을 촉매하는데 효과적인 양의 다음과 같은 구조식을 가지는 망간 착화합물. [LMnIV(OR)3]Y (A)
    (이식에서 Mn은 산화수가 +4인 망간이며, R은 알킬기, 시클로알키기, 아릴기, 벤질기 및 이러한 기의 혼합체 중에서 선택되는 C1-C20인 기이고, 또한 2이상의 R 기의 망간과 배위결합하는 두산소사이에 브리징 단위를 형성 하도록 서로 결합될 수 있으며, L은 망간과 배위결합하는 3이상의 질소원자를 가지는 C3-C60인 기로부터 선택되는 리간드이고, Y는 산화적으로 안정한 카운터 이온임.)
  5. 제4항에 있어서, 2-30중량%의 퍼옥시 화합물과 망간 함량이 0.0005-0.5중량%에 해당되는 양의 상기 촉매를 함유하는 것을 특징으로 하는 조성물.
  6. 제4항에 있어서, 망간 함량이 0.001-0.25중량%인 것을 특징으로 하는 조성물.
  7. 제4항에 있어서, 상기 퍼옥시화합물은 과산화수소, 과산화 수소-방출화합물, 과산화수소-발생계, 퍼옥시산 및 그염, 퍼옥시산 표백제 전구체 및 이러한 물질의 혼합물 중에서 선택되는 것을 특징으로 하는 조성물.
  8. 제4항에 있어서, 0.5-50중량%의 계면활성제 물질을 또한 함유하는 것을 특징으로 하는 조성물.
  9. 제4항에 있어서, 5-80중량%의 세정력 빌더를 또한 함유하는 것을 특징으로 하는 조성물.
  10. 제4항에 있어서, 프로테아제, 셀룰라제, 리파제, 아밀라제, 옥시다제 및 그 혼합무 중에서 선택되는 효소를 또한 함유하는 것을 특징으로 하는 조성물.
  11. 각각 서로 상호작용하여 기질에 세정효과를 제공하는데 효과적인 양의 퍼옥시 화합물과 망간 착화합물을 함유하는 수성매질에 오염된 기질을 접촉시킴으로써 오염된 기질을 표백하는 방법으로서, 망간 착화합물은 다음과 같은 식을 가지는 것을 특징으로 하는 방법.
    [LMnIV(OR)3]Y (A)
    (이식에서 Mn은 산화수가 +4인 망간이며, R은 알킬기, 시클로알키기, 아릴기, 벤질기 및 이러한 기의 혼합체 중에서 선택되는 C1-C20인 기이고, 또한 2이상의 R기는 망간과 배위하는 두산소 사이에 브리징 단위를 형성 하도록 서로 결합될 수 있으며, L은 망간과 배위하는 3이상의 질소원자를 가지는 C3-C60인 기로부터 선택되는 리간드이고, Y는 산화적으로 안정한 카운터 이온임.)
  12. 제11항에 있어서, 기질은 직물, 식기류 및 치아로부터 선택되는 것을 특징으로 하는 방법.
  13. 0.001ppm-100ppm의 망간 농도의 제1항에 따르는 망간 촉매와 0.01ppm-250ppm의 농도의 활성 산소를 방출하는 퍼옥시 화합물을 함유하는 수성 매질.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920022432A 1991-11-26 1992-11-26 망간 촉매 KR960008938B1 (ko)

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KR1019960005435A KR960015159B1 (ko) 1991-11-26 1996-02-29 세제용 표백제 조성물

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US07/798,396 US5194416A (en) 1991-11-26 1991-11-26 Manganese catalyst for activating hydrogen peroxide bleaching
US07/798396 1991-11-26

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KR960008938B1 KR960008938B1 (ko) 1996-07-10

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US (1) US5194416A (ko)
EP (1) EP0544519B1 (ko)
JP (1) JPH06121933A (ko)
KR (1) KR960008938B1 (ko)
CN (1) CN1034022C (ko)
AU (1) AU652867B2 (ko)
BR (1) BR9204548A (ko)
CA (1) CA2083658C (ko)
DE (1) DE69216786T2 (ko)
ES (1) ES2097291T3 (ko)
MX (1) MX9206810A (ko)
TW (1) TW242159B (ko)
ZA (1) ZA929186B (ko)

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