KR910015625A - 새로운 방향족 폴리술폰에테르케톤 중합체 - Google Patents

새로운 방향족 폴리술폰에테르케톤 중합체 Download PDF

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Publication number
KR910015625A
KR910015625A KR1019900001238A KR900001238A KR910015625A KR 910015625 A KR910015625 A KR 910015625A KR 1019900001238 A KR1019900001238 A KR 1019900001238A KR 900001238 A KR900001238 A KR 900001238A KR 910015625 A KR910015625 A KR 910015625A
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KR
South Korea
Prior art keywords
ether ketone
structural formula
following structural
ketone polymer
aromatic
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KR1019900001238A
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English (en)
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KR930006259B1 (ko
Inventor
김영하
한양규
김대식
지성대
박종원
Original Assignee
이상수
한국과학기술원
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Application filed by 이상수, 한국과학기술원 filed Critical 이상수
Priority to KR1019900001238A priority Critical patent/KR930006259B1/ko
Priority to US07/638,318 priority patent/US5166305A/en
Priority to GB9100846A priority patent/GB2241245B/en
Priority to JP3031482A priority patent/JP2748987B2/ja
Publication of KR910015625A publication Critical patent/KR910015625A/ko
Application granted granted Critical
Publication of KR930006259B1 publication Critical patent/KR930006259B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/20—Polysulfones
    • C08G75/23—Polyethersulfones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/20—Polysulfones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
    • C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
    • C08G65/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group
    • C08G65/4012—Other compound (II) containing a ketone group, e.g. X-Ar-C(=O)-Ar-X for polyetherketones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/05—Polymer mixtures characterised by other features containing polymer components which can react with one another

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyethers (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

내용 없음

Description

새로운 방향족 폴리술폰에테르케톤 중합체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. 아래의 구조식(I)를 나타내는 반복 단위로 구성된 방향족 폴리술폰에테르케톤 중합체.
    위 식에서, Ar은 페닐렌, 바이페닐렌, 또는인데, 여기서 -Y-는, 또는 -O-이다.
  2. 제1항에 있어서, 환원 점도가 0.1-1.0인 것인 폴리술폰에테르케톤 중합체.
  3. 제1항에 있어서, 반복 단위가 아래 구조식(Ⅳ)로 나타내는 것인 무정형 폴리술폰에테르케톤 중합체.
  4. 제1항에 있어서, 반복단위가 아래 구조식(Ⅴ)로 나타내는 것인 무정형 폴리술폰에테르케톤 중합체.
  5. 제1항에 있어서, 반복 단위가 아래 구조식(Ⅵ)으로 나타내는 것인 무정형 폴리술폰에테르케톤 중합체.
  6. 아래 구조식(Ⅱ)의 방향족 디할로겐 화합물과 아래 구조식(Ⅲ)의 방향족 디올염을 몰당량비로 유기 극성 용매 속에서 140-250℃의 중합 온도에서 축합 반응시키는 것이 특징인 아래 구조식(I)로 나타내는 폴리술폰에테르케톤 중합체의 제조방법.
    X는 염소 또는 불소이며, M은 알칼리 금속이다.
  7. 제6항에 있어서, 방향족 디할로겐 화합물이 4-플루오로-4′-(4-플루오로벤조일페닐옥시)디페닐술폰인 방법.
  8. 제6항에 있어서, 방향족 디올염이 방향족 디올과 알칼리 금속 염기로부터 제조되는 것인 방법.
  9. 제8항에 있어서, 방향족 디올이 2,2-비스-(4-히드록시 페닐)프로판, 히드로퀴논 또는 4,4′-바이페놀중에서 선택되는 것인 방법.
  10. 제8항 또는 제9항에 있어서, 알칼리 금속 염기로서 포타슘 카보네이트를 방향족 디올의 농도에 대하여 1.0-20 wt%과량 사용하는 것인 방법.
  11. 제6항에 있어서, 유기 극성 용매가 디메틸술폭시드, 술폴란 또는 디페닐술폰 중에서 선택되는 것인 방법.
  12. 제6항에 있어서, 중합 반응기 내의 수분 함량을 방향족 디올염의 농도에 대하여 0.5wt% 이하로 하는 것인 방법.
  13. 제6항에 있어서, 중합 반응 시간이 1-12시간인 것인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900001238A 1990-02-02 1990-02-02 새로운 방향족 폴리술폰에테르케톤 중합체 KR930006259B1 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
KR1019900001238A KR930006259B1 (ko) 1990-02-02 1990-02-02 새로운 방향족 폴리술폰에테르케톤 중합체
US07/638,318 US5166305A (en) 1990-02-02 1991-01-04 Aromatic polysulfoneetherketone polymers
GB9100846A GB2241245B (en) 1990-02-02 1991-01-15 Novel aromatic polysulfoneetherketone polymers
JP3031482A JP2748987B2 (ja) 1990-02-02 1991-02-02 芳香族ポリスルホンエーテルケトン及びその製造方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019900001238A KR930006259B1 (ko) 1990-02-02 1990-02-02 새로운 방향족 폴리술폰에테르케톤 중합체

Publications (2)

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KR910015625A true KR910015625A (ko) 1991-09-30
KR930006259B1 KR930006259B1 (ko) 1993-07-09

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US (1) US5166305A (ko)
JP (1) JP2748987B2 (ko)
KR (1) KR930006259B1 (ko)
GB (1) GB2241245B (ko)

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EP1497375B1 (en) * 2002-04-15 2007-12-26 Solvay Advanced Polymers, LLC Polysulfone compositions exhibiting very low color and high light transmittance properties and articles made therefrom
CN100374483C (zh) * 2006-03-29 2008-03-12 长春吉大高科技股份有限公司 聚醚醚砜和聚醚醚酮三元共聚物的制备方法
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US8916672B2 (en) * 2009-12-11 2014-12-23 ICUF-HYU (Industry-University Cooperation Foundation Hanyang University) Transparent polyarylene ether polymer with high heat resistance and method for preparing the same
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RU2528400C2 (ru) * 2012-04-06 2014-09-20 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования Кабардино-Балкарский государственный университет им. Х.М. Бербекова Ароматические блок-сополиэфиры
RU2556228C2 (ru) * 2013-08-27 2015-07-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Кабардино-Балкарский государственный университет им. Х.М. Бербекова" (КБГУ) Ароматические полиэфирсульфонкетоны
RU2556230C2 (ru) * 2013-09-17 2015-07-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Кабардино-Балкарский государственный университет им. Х.М. Бербекова" (КБГУ) Ароматические полиэфирсульфонкетоны
RU2556233C2 (ru) * 2013-09-27 2015-07-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Кабардино-Балкарский государственный университет им. Х.М. Бербекова" (КБГУ) Ароматические полиэфирсульфонкетоны
CN104861167B (zh) * 2015-05-29 2017-04-05 常州大学 一类含多个季铵盐苯侧基结构聚芳醚砜及其制备方法
RU2643033C1 (ru) * 2017-02-08 2018-01-30 Федеральное государственное бюджетное образовательное учреждение высшего образования "Кабардино-Балкарский государственный университет им. Х.М. Бербекова" (КБГУ) Галогенсодержащие блок-сополиэфиркетонсульфоны
US20220169793A1 (en) 2019-04-01 2022-06-02 Basf Se Amorphous polymer (p) comprising segments (s1), (s2) and (s3)
CN116171194A (zh) * 2020-08-24 2023-05-26 巴斯夫欧洲公司 包含无定形聚合物的膜

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Also Published As

Publication number Publication date
JPH04213330A (ja) 1992-08-04
GB9100846D0 (en) 1991-02-27
GB2241245A (en) 1991-08-28
GB2241245B (en) 1993-02-17
JP2748987B2 (ja) 1998-05-13
KR930006259B1 (ko) 1993-07-09
US5166305A (en) 1992-11-24

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