KR900016344A - 우수한 페인트 접착력을 갖는 열가소성 수지 또는 엘라스토머 조성물 및 상기 열가소성 엘라스토머의 층 및 폴리우레탄 층으로 구성된 적층체 - Google Patents

우수한 페인트 접착력을 갖는 열가소성 수지 또는 엘라스토머 조성물 및 상기 열가소성 엘라스토머의 층 및 폴리우레탄 층으로 구성된 적층체 Download PDF

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KR900016344A
KR900016344A KR1019890004637A KR890004637A KR900016344A KR 900016344 A KR900016344 A KR 900016344A KR 1019890004637 A KR1019890004637 A KR 1019890004637A KR 890004637 A KR890004637 A KR 890004637A KR 900016344 A KR900016344 A KR 900016344A
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weight
parts
thermoplastic resin
elastomer composition
peroxide
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KR1019890004637A
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KR970004919B1 (ko
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도시유키 마에다
야수히코 오타와
가츠호 오카모도
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다케바야시 쇼오고
미쓰이 세키유 가카쿠 고오교오 가부시기가이샤
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Priority claimed from JP63084991A external-priority patent/JPH01259048A/ja
Priority claimed from JP63084992A external-priority patent/JPH01259047A/ja
Priority claimed from JP63124891A external-priority patent/JP2595302B2/ja
Application filed by 다케바야시 쇼오고, 미쓰이 세키유 가카쿠 고오교오 가부시기가이샤 filed Critical 다케바야시 쇼오고
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/0036—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C08F255/06—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethene-propene-diene terpolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/14—Peroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2375/00—Polyureas; Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond

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  • Chemical & Material Sciences (AREA)
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  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

내용 없음.

Description

우수한 페인트 접착력을 갖는 열가소성 수지 또는 엘라스토머 조성물 및 상기 열가소성 엘라스토머의 층 및 폴리우레탄 층으로 구성된 적층체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. (a) 퍼록사이드-가교 결합성 올레핀계 공중합체 및/또는 (b) 올레핀계 플라스틱(성분 (a) 및 (b)의 합계가 100중량부임)가 (c) 0.01 내지 10중량부의 불포화 카르복실산 또는 그들의 유도체로 구성된 혼합물을 유기퍼록사이드 존재하에 격렬하게 열처리하여 산출된 일가소성 수지 또는 엘라스토머 100중량부를 가열하에 (d) 최소한 한개의 아미노기를 포함하는 단량체 0. 01 내지 10중량부와 혼합하여 제조된 열가소성 수지 또는 엘라스토머 조성물.
  2. (a) 퍼록사이드-가교 결합성 올레핀계 공중합체 및/또는 (b) 올레핀계 플라스틱(성분(a) 및 (b)의 합계가 100중량부임], (c) 불포화 카르복실산 무수물 또는 그들의 유도체 0.01 내지 10중량부 및 (d) 최소한 한개의 아미노기를 포함하는 단량체 0.01 내지 10중량부로 구성된 혼합물을 유기 퍼록사이드 존재하에 격렬하게 열처리함으로써 제조된 열가소성 수지 또는 엘라스토머 조성물.
  3. (a) 퍼록사이드 가교 걸합성 올레핀계 공중합체 및/또는 (b) 올레핀계 플라스틱(성분 (a) 및 (b)의 합계는 100중량부임) 및 (d) 최소한 한개의 아미노기를 포함하는 단량체 0.01 내지 10중량부로 구성된 혼합물을 유기퍼록사이드 존재하에 격렬하게 열처리하여 제조된 열가소성 수지 또는 엘라스토머 조성물.
  4. 제3항에 있어서, 제조된 열가소성수지 또는 엘라스토머 100중량부 가열하에 (c) 0.01 내지 10중량부의 불포화 카르복실산 또는 그들의 유도체와 혼합하는 열가소성 수지 또는 엘라스토머 조성물.
  5. 제1항 내지 제4항중 어느 한 항에 있어서, 성분 (a) 및 (b)의 합계 100중량부당 (e) 0.01 내지 100중량부의 퍼록사이드-비가교결합성 고무물질, (f) 0. 01 내지 200중량부의 광물유계 연화제 및 (g) 0.01 내지 100중량부의 섬유성 충전제로 구성된 군중 선택된 최소한 일종의 첨가제를 상기 혼합물에 또한 투입하는 열가소성 수지 또는 엘라스토머 조성물.
  6. 제1항 내지 제5항중 어느 한 항에 있어서, 상기 불포화 카르복실산 또는 그들의 유도체는 말레산 무수물인 열가소성 수지 또는 엘라스토머 조성물.
  7. 제1항 내지 제5항중 어느 한 항에 있어서, 상기 최소한 한개의 아미노기를 포함하는 단량체는 N-아미노에틸에탄올아민인 열가소성 수지 또는 엘라스토머 조성물.
  8. (A) 열가소성 엘라스토머의 층 및 (B) 폴리우레탄의 층으로 구성된 적층체에 있어서, 상기 열가소성 엘라스토머층(A)은 (a) 퍼록사이드-가교 결합성 올레핀계 공중합체, (b) 올레핀계 플라스틱[성분(a) 및 (b)의 합계가 100중량부임] 및 (c) 불포화 카르복실산 또는 그들의 유도체 0.01 내지 10중량부를 유기 퍼록사이드 존재하에 격렬하게 열처리하여 얻어진 열가소성 엘라스토머 조성물을 (d) 최소한 한개의 아미노기를 포함하는 단량체 0.01 내지 10중량부와 혼합한뒤 이 혼할물을 열처리함으로써 얻어진 열가소성 엘라스토머 조성물로 구성되는 것을 특징으로 하는 적층체.
  9. 제8항에 있어서, 상기 열가소성 엘라스토머층(A)은 상기 열가소성 엘라스토머 조성물 100중량부 및 올레핀계 플라스틱 300중량부 정도를 포함하는 혼합물인 적층체.
  10. 제9항에 있어서, 상기 올레핀계 플라스틱의 용융 지수는 0.1 내지 50인 적층체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890004637A 1988-04-08 1989-04-08 도료 밀착성이 우수한 열가소성 엘라스토머 조성물, 및 상기 열가소성 엘라스토머 층 및 폴리우레탄 층으로 구성된 적층제 KR970004919B1 (ko)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
JP84992/88 1988-04-08
JP84993/88 1988-04-08
JP63084993A JP2585699B2 (ja) 1988-04-08 1988-04-08 ポリウレタン接着用部分架橋熱可塑性エラストマー組成物
JP63084991A JPH01259048A (ja) 1988-04-08 1988-04-08 塗料密着性に優れた熱可塑性樹脂乃至エラストマー組成物
JP63084992A JPH01259047A (ja) 1988-04-08 1988-04-08 塗料密着性に優れた熱可塑性樹脂乃至エラストマー組成物
JP84991/88 1988-04-08
JP124891/88 1988-05-24
JP63124891A JP2595302B2 (ja) 1988-05-24 1988-05-24 積層体

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KR900016344A true KR900016344A (ko) 1990-11-13
KR970004919B1 KR970004919B1 (ko) 1997-04-08

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EP (2) EP0336780B1 (ko)
KR (1) KR970004919B1 (ko)
AT (2) ATE173485T1 (ko)
AU (1) AU620386B2 (ko)
CA (1) CA1339286C (ko)
DE (2) DE68928855T2 (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100763292B1 (ko) * 2000-05-19 2007-10-04 카오카부시키가이샤 폴리우레탄 폼

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JPH04154850A (ja) * 1990-10-18 1992-05-27 Sumitomo Chem Co Ltd オレフィン系樹脂組成物
US5212239A (en) * 1991-02-22 1993-05-18 Arco Chemical Technology, L.P. Resin blends containing crystalline propylene polymers and styrenic copolymers
CA2066501C (en) * 1991-04-22 1998-12-01 Kazuhiko Murata Thermoplastic elastomer laminates and glass run channels molded therefrom
DE69304576T2 (de) * 1992-03-25 1997-04-17 Showa Denko Kk Thermoplastische Harzzusammensetzung und daraus hergestellter farbbeschichteter Formkörper
US5602203A (en) * 1992-11-26 1997-02-11 Sumitomo Chemical Company, Limited Olefin resin composition
JP3333251B2 (ja) * 1992-11-26 2002-10-15 三洋化成工業株式会社 オレフィン系樹脂組成物
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AU620386B2 (en) 1992-02-20
EP0336780B1 (en) 1995-07-12
EP0614940A2 (en) 1994-09-14
DE68923392D1 (de) 1995-08-17
EP0336780A3 (en) 1991-01-09
ATE124965T1 (de) 1995-07-15
CA1339286C (en) 1997-08-12
ATE173485T1 (de) 1998-12-15
DE68923392T2 (de) 1995-12-21
EP0614940A3 (en) 1994-11-09
AU3255789A (en) 1989-10-12
EP0614940B1 (en) 1998-11-18
DE68928855T2 (de) 1999-08-05
DE68928855D1 (de) 1998-12-24
KR970004919B1 (ko) 1997-04-08

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