KR890014662A - 열가소성 수지 조성물 - Google Patents

열가소성 수지 조성물

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Publication number
KR890014662A
KR890014662A KR1019890004283A KR890004283A KR890014662A KR 890014662 A KR890014662 A KR 890014662A KR 1019890004283 A KR1019890004283 A KR 1019890004283A KR 890004283 A KR890004283 A KR 890004283A KR 890014662 A KR890014662 A KR 890014662A
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South Korea
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resin composition
thermoplastic resin
weight
polypropylene
unsaturated
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KR1019890004283A
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English (en)
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KR0142436B1 (ko
Inventor
다까유끼 오까다
다쯔유끼 미쯔노
다께시 후지이
겐따로 야마꾸지
미쓰지 쓰지
미즈유끼 오까다
다께요시 니시오
도시오 요꼬이
다까오 노무라
Original Assignee
니시자와 요시히꼬
스미또모 가가꾸고오교 가부시끼가이샤
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Publication of KR890014662A publication Critical patent/KR890014662A/ko
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Publication of KR0142436B1 publication Critical patent/KR0142436B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0869—Acids or derivatives thereof
    • C08L23/0884—Epoxide containing esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Body Structure For Vehicles (AREA)

Abstract

내용 없음.

Description

열가소성 수지 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 관통 충격 강도를 평가하는 측정 도표의 예를 나타낸다.

Claims (12)

  1. 폴리프로필렌 상에 불포화 카르복실산 또는 그와 유도체 및 불포화 방향족 단량체를 그라프트 공중합하여 수득한 변성 폴리프로필렌(A) 및 변성 폴리프로필렌(A) 및 폴리프로필렌(B)로 구성된 조성물로 구성되는 군으로부터 선택한 폴리프로필렌계 수지(C) 1 내지 99중량% 및 적어도 1종류의 포화 폴리에스테르 수지(D)의 99 내지 1중량%로 구성된 수지 조성물 100중량부 에폭시기 함유 공중합체(E) 0.1 내지 300중량부 에틸렌계 공중합체 고무상에 불포화 카르복실산 또는 그의 유도체 및 불포화 방향족 단량체를 그라프트 공중합하여 수득한 변성 에틸렌계 공중합체 고무(F) 0.1 내지 300중량부, 및 반응 폭진제로서 임의로 부가된 염기성 화합물 5중량부 이하의 혼합물(blend)이고, 열가소성 수지 조성물중의 포화 폴리에스테르 수지의 함량이 50중량% 미만임을 특징으로 하는 열가소성 수지 조성물.
  2. 제1항에 있어서, 열가소성 수지 조성물이 또한 폴리프로필렌상에 불포화 카르복실산 또는 그의 유도체 및 불포화 방향족 단량체를 그라프트 공중합체하여 수득된 변성 폴리프로필렌(A) 및 변성 폴리프로필렌(A) 및 폴리프로필렌(B)의 조성물로 구성되는 군에서 선택한 폴리프로필렌계 수지(C) 1 내지 99중량% 및 적어도 1종류의 포화 폴리에스테르 수지(D) 99 내지 1중량%로 구성된 수지 조성물 100중량부 당 0.01 내지 300중량부의 양으로 충진제(H)를 함유함을 특징으로 하는 열가소성 수지 조성물.
  3. 제1항 또는 2항에 있어서, 변성 폴리프로필렌(A) 중에서, 불포화 카르복실산 또는 그의 유도체가 말레산 무수물이고, 불포화 방향족 단량체가 스티렌임을 특징으로 하는 열가소성 수지 조성물.
  4. 제1항 또는 2항에 있어서, 포화 폴리에스테르 수지(D)가 폴리에틸렌 테레프탈레이트 및/또는 폴리 부틸렌테레프탈레이트임을 특징으로 하는 열가소성 수지 조성물.
  5. 제1항 또는 2항에 있어서, 에폭시기 함유 공중합체(E)가 불포화 에폭시 화합물 및 에틸렌의 공중합체, 또는 불포화 에폭시 화합물, 에틸렌 및 에틸렌을 제외한 에틸렌계 불포화 화합물의 공중합체 임을 특징으로 하는 열가소성 수지 조성물.
  6. 제1항 또는 2항에 있어서, 변성 에틸렌계 공중합체 고무(F)중에서, 불포화 카르복실산 또는 그의 유도체가 말레산 무수물이고, 불포화 방향족 단량체가 스티렌임을 특징으로 하는 열가소성 수지 조성물.
  7. 제1항 또는 2항에 있어서, 변성 에틸렌계 공중합체 고무(F)중에서, 에틸렌공중합체 고무가 에틸렌-α-올레핀 공중합체 고무 및/또는 에틸렌-α-올레핀 비공역 디엔 공중합체 고무임을 특징으로 하는 열가소성 수지 조성물.
  8. 제1항 또는 2항에 있어서, 염기성 화합물(G)가 유기 아민 화합물임을 특징으로 하는 열가소성 수지 조성물.
  9. 제2항에 있어서, 충진제(H)가 유리섬유, 칼륨 티탄화물 휘스커(potassium titanate whisker), 활석, 운모 및 탄산칼슘으로 구성되는 군에서 선택된 무기 충진제임을 특징으로 하는 열가소성 수지 조성물.
  10. 제1항 또는 2항에 따른 열가소성 수지 조성물을 성형하여 수득하는 자동차용 성형부품.
  11. 제10항에 있어서, 성형부품이 범퍼임을 특징으로 하는 자동차용 성형부품.
  12. 제10항에 있어서, 성형부품이 펜더(fender)임을 특징으로 하는 자동차용 성형부품.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890004283A 1988-03-31 1989-03-31 열가소성 수지 조성물 KR0142436B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP63-82042 1988-03-31
JP63-82041 1988-03-31
JP8204288 1988-03-31
JP8204188 1988-03-31

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KR890014662A true KR890014662A (ko) 1989-10-25
KR0142436B1 KR0142436B1 (ko) 1998-07-01

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US (1) US4981896A (ko)
EP (1) EP0335394B1 (ko)
JP (1) JP2782225B2 (ko)
KR (1) KR0142436B1 (ko)
BR (1) BR8901528A (ko)
CA (1) CA1329436C (ko)
DE (1) DE68910556T2 (ko)

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CA1329436C (en) 1994-05-10
US4981896A (en) 1991-01-01
EP0335394B1 (en) 1993-11-10
DE68910556T2 (de) 1994-05-11
KR0142436B1 (ko) 1998-07-01
BR8901528A (pt) 1989-11-14
JP2782225B2 (ja) 1998-07-30
JPH0236253A (ja) 1990-02-06
EP0335394A3 (en) 1990-12-05
EP0335394A2 (en) 1989-10-04
DE68910556D1 (de) 1993-12-16

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