KR890003914A - 유리섬유 보강 폴리에스테르 기질용 무프라이머 접착제 - Google Patents

유리섬유 보강 폴리에스테르 기질용 무프라이머 접착제 Download PDF

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KR890003914A
KR890003914A KR1019880010555A KR880010555A KR890003914A KR 890003914 A KR890003914 A KR 890003914A KR 1019880010555 A KR1019880010555 A KR 1019880010555A KR 880010555 A KR880010555 A KR 880010555A KR 890003914 A KR890003914 A KR 890003914A
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isocyanate
aliphatic
weight
substrate
parts
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에이.충 다니엘
지.다만 로렌스
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브이.에프.벤
앳슈랜드 오일, 인코포레이티드
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    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/721—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
    • C08G18/724—Combination of aromatic polyisocyanates with (cyclo)aliphatic polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C08G18/7628—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8108—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/12—Polyurethanes from compounds containing nitrogen and active hydrogen, the nitrogen atom not being part of an isocyanate group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/08—Reinforcements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00—Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31565—Next to polyester [polyethylene terephthalate, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]

Abstract

내용 없음

Description

유리섬유 보강 폴리에스테르 기질용 무프라이머 접착제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (15)

  1. 폴리올과 방향족 이소시아네이트의 반응 생성물로 되고, 3-15%의 유리이소시아네이트기를 갖는 프리폴리머 성분, 지방족 폴리이소사네이트 및 다작용성 폴리올로 되는 경화제 성분의 혼합물로 되는 무프라이머 접착제의 경화잔류물에 의해 저착,접합된 제2기질을 갖는 제1미애벌칠 섬유 보강 폴리에스테르 기질로 되는 라미네이트 복합체.
  2. 제1항에 있어서, 상기 지방족 폴리이소시아네이트가 상기 이소시아네이트기에 대해 알파 위치에 있는 지방조 탄소를 가지며, 여기서 상기 알파 탄소는 -CO2R, -CHRR′또는 -CHR′R′′이고, R,R′,R′′는 독립적으로 6내지 40의 탄소 원자수를 갖는치환 또는 비치환방향족기 또는 치환 또는 비치환 지방족기인 것을 특징으로 하는 라미네이트 복합체.
  3. 제2항에 있어서, 상기 지방족 이소시아네이트가 120내지 700의 분자량을 갖는 것을 특징으로 하는라미네이 기질.
  4. 제3항에 있어서, 상기 지방족 이소시아네이트가 이소포론 디이소시아네이트, 비스(4-이소시아네이토시클로헥실)메탄,m-크실릴렌디이소시아네이트, 1,3-비스(이소시아네이토메틸)시클로헥산, m-테트라메틸크실렌 디아소시아네이트, 디메틸-P-이소프로페닐 벤질 이소시아네이트, 트리메틸 헥사메틸렌 디이소시아네이트, 2-이소시아네이토에틸-2,6-디이소시아네이토헥사노에이트, 헥사메틸렌 디이소시아네이트 및 이들의 혼합물로 되는 군 중에서 선택되는 것임을 특징으로 하는 라미네이트 기질.
  5. 제4항에 있어서, 상기 무프라이머 접착제가 혼합된 프리폴리머 및 경화제 약 100중량부와지방족 이소시아네이트 0.5-6.0중량부로 되는 것임으 특징으로 하는 라미네이트 기질.
  6. 제5항에 있어서, 상기 무프라이머 접착제가 프리폴리머 50-85중량부, 지방족 이소시아네이트 0.5-6.0중량부 및 그 잔여부를 경화제로 하여 100중량부로 만든 것임을 특징으로 하는 라미네이트 기질.
  7. 제6항에 있어서, 상기 무프라이머 접착제가 프리폴리머 약80중량부, 경화제약 20중량부 및 m-크실릴렌디이소시아네이트 0.5-4.0중량부로 되는 것임을 특징으로 하는 라미네이트 기질.
  8. 제7항에 있어서, 상기무프라이머 접착제가 추가가로 우레탄 촉매를 포함하는 것임을 특징으로 하는 라미네이트기질.
  9. (A)폴리올과 방향족 이소시아네이트의 반응생성물로 되고, 3-15%의 유리 이소시아네이트기를 갖는 프리폴리머, 지방족 이소시아네이트 및 다작용성 폴리에테르 폴리올로 되는 경화제의 혼합물로 되는 무프라이머 접착제를 제1미애벌칠 섬유보강 폴리에스테르 기질에 도포하고,(B)제2기질을 상기 제1 접착제 피복 미애벌칠 섬유보강 폴리에스테르 기질에 라미네이팅하는 것으로 되는 라미네이트 복합체 형성방법.
  10. 제9항에 있어서, 상기 라미네이트 복합체를 가열하는 것을특징으로 하는 방법.
  11. 제9항에 있어서, 상기 지방족 폴리이소시아네이트가 상기 이소시아네이트기에 대해 알파 위치에 있는 지방조 탄소를 가지며, 여기서 상기 알파탄소는 -CO2R, -CORR′또는 -CORR′R″이고, R,R′,R″는 독립적으로 6내지 40의 탄소 원자수를 갖는치환 또는 비치환방향족기 또는 치환 또는 비치환 지방족기인 것을 특징으로 하는 방법.
  12. 제11항에 있어서, 상기 지방족 이소시아네이트가 120내지 700의 분자량을 갖는 것임을 특징으로 방법.
  13. 제12항에 있어서, 상기 가열단계가 상기 라미네이트 기질으 약 135℃로 약 30분 동안 가열하는 것으로 되는 방법.
  14. 제13항에 있어서, 상기 지방족 이소시아네이트가 이소포론 디이소시아네이트,비스(4-이소시아네이토시클로헥실)메탄,m-크실릴렌디이소시아네이트, 1,3-비스(이소시아네이토메틸)시클로헥산, m-테트라메틸크실렌 디아소시아네이트, 디메틸-P-이소프로페닐 벤질 이소시아네이트, 트리메틸 헥사메틸렌 디이소시아네이트, 2-이소시아네이토에틸-2,6-디이소시아네이토헥사노에이트 및 헥사메틸렌 디이소시아네이트로 되는 군 중에서 선택되는 것임을 특징으로 하는 방법.
  15. 제14항에 있어서, 상기 무프라이머 접착제가 프리폴리머, 지방족 이소시아네이트,경화제, 충전제, 산화 방지제 및 착색제로 되는 것임을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880010555A 1987-08-20 1988-08-19 경화된 접착제를 가지는 기질의 라미네이트 복합체 및 그의 제조방법 KR920000621B1 (ko)

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US07/087,194 US4923756A (en) 1987-08-20 1987-08-20 Primerless adhesive for fiberglass reinforced polyester substrates
US087,194 1987-08-20
US87194 1987-08-20

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KR890003914A true KR890003914A (ko) 1989-04-18
KR920000621B1 KR920000621B1 (ko) 1992-01-17

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US (1) US4923756A (ko)
EP (1) EP0304083B1 (ko)
JP (1) JPH0688387B2 (ko)
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JPS6469342A (en) 1989-03-15
ES2052655T3 (es) 1994-07-16
JPH0688387B2 (ja) 1994-11-09
US4923756A (en) 1990-05-08
KR920000621B1 (ko) 1992-01-17
DE3888427D1 (de) 1994-04-21
ATE102963T1 (de) 1994-04-15
EP0304083B1 (en) 1994-03-16
DE3888427T2 (de) 1994-10-06
EP0304083A3 (en) 1989-10-25
EP0304083A2 (en) 1989-02-22

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