KR880002920A - 방사선 경화성 결합제를 가지는 피복 연마재 - Google Patents

방사선 경화성 결합제를 가지는 피복 연마재 Download PDF

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KR880002920A
KR880002920A KR1019870008745A KR870008745A KR880002920A KR 880002920 A KR880002920 A KR 880002920A KR 1019870008745 A KR1019870008745 A KR 1019870008745A KR 870008745 A KR870008745 A KR 870008745A KR 880002920 A KR880002920 A KR 880002920A
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리 터미 마이클
웬덴 밴지 도나
프란시스코 로빈스 아이다
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도날드 밀러 셀
미네소타 마이닝 앤드 매뉴팩츄어링 컴패니
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B24—GRINDING; POLISHING
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    • B24—GRINDING; POLISHING
    • B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract

내용 없음

Description

방사선 경화성 결합제를 가지는 피복 연마재
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 직물배킹물질상의 피복연마제의 횡단면도.
제2도는 종이배킹물질상의 피복연마재의 횡단면도

Claims (19)

  1. 배킹, 메이크피복층, 연마제과립층, 및 사이즈피복층으로 구성되고, 메이크피복층과 사이즈피복층중의 적어도 하나는 에틸렌성 불포화기 및 1,2-에폭시드기로 구성되는 전자기방사선경화성 조성물과, (1) 오늄양이온 및 금속 또는 비금속의 할로겐함유 음이온을 가지는 염, 및 (2) (a) 유기금속착양이온 및 금속 또는 비금속의 할로겐함유착 음이온을 가지는 적어도 하나의 염과, (b) 적어도 하나의 자유라디칼중합개시제의 혼합물로 이루어지는 군에서 선택된 적어도 하나의 중합광개시제로 구성되는 상기 조성물경화에 충분한 양의 광개시제부로 성형되는 것을 특징으로 하는 피복연마재 제품.
  2. 제1항에 있어서, 에틸렌성불포화기가 지방족히드록식함유화합물과 불포롸 카르복실산의 에스테르에 의해서 제공되는 것을 특징으로 하는 제품.
  3. 제2항에 있어서, 상기 에틸렌성불포화기가 아크릴산 또는 메타크릴산의 에스테르에 의해서 제공되는 것을 특징으로 하는 제품.
  4. 제1항에 있어서, 에틸렌성불포화기가 에틸렌글리크올디아크릴레이트, 트리메틸올프로판트리아크릴레이트, 펜타에리트리톨 크리아크릴레이트, 비스페놀 A의 디아-크릴레이트, 비스페놀 A의 에톡시화 디아크릴 레이트, 지방족우레탄 아크릴레이트 및 N-비닐-2-피롤리돈으로 이루어지는 군에서 선택된 화합물에 의해서 제공되는 것을 특징으로 하는 제품.
  5. 제1항에 있어서, 1,2-에폭시드기가 3,4-에폭시시클로헥실메틸 3,4-에폭시시클로헥산 카르복실레이트, 3,4-에폭시-2-메틸시클로헥실메틸 3,4-에폭시-2-메틸시클로 헥산카르복실레이트, 비스(3,4-에폭시-6-메틸시클로헥실메틸)아디페이트, 2,2-비스[4-(2,3-에폭시프로폭시)페닐)]프로판, 부틸 글리시딜에테르, 네오펜틸글리코올 디글리시딜에테르, 및 레졸시놀 디글리시딜에테르로 이루어진 군에서 선택된 화합물에 의해서 제공되는 것을 특징으로 하는 제품.
  6. 제1항에 있어서, 에틸렌성 불포화기 및 1,2-에폭시드기가 적어도 2개의 1,2-에폭시드기와 활성수소를 함유하는 에틸렌성불포화화합물의 화학양론적 부족량과의 반응생성물인 이 반응성화합물에 의해서 제공되는 것을 특징으로 하는 제품.
  7. 제6항에 있어서, 상기 이 반응성화합물이 0.4 내지 0.6당량의 아크릴산과 1몰의 비스페놀 A의 디글리시딜에테르, 1,4-부탄디올의 디글리시딜에테르, 페놀-포름알데히드 노볼락의 폴리글리시딜에테르, 크레졸-포름알데히드 노볼락의 폴리글리시딜에테르, 디글리시딜 테레프탈레이트, 3,4-에폭시시클로헥실메틸 3,4-에폭시시클로헥산카르복실레이트, 및 비스(3,4-에폭시-6-메틸시클로헥실) 메틸 아디페이트로 이루어진 군에서 선택되는 물질의 반응생성물인 것을 특징으로 하는 제품.
  8. 제1항에 있어서, 순수열활성 중합개시제를 함유하는 것을 특징으로 하는 제품.
  9. 제1항에 있어서, 상기 조성물이 조성물 100g 당 적어도 약 0.2당량의 에틸렌성 불포화기와 적어도 약 0.05당량의 1,2-에폭시드기를 포함하는 것을 특징으로 하는 제품.
  10. 제1항에 있어서, 광개시제의 총량이 상기 방사선경화성조성물의 약 0.05 내지 약 10중량부의 범위 내인 것을 특징으로 하는 제품.
  11. 제1항에 있어서, 상기 메이크피복층 및 사이즈피복층중 적어도 하나가 페놀수지로 성형되는 것을 특징으로 하는 제품.
  12. 배킹, 메이크피복층, 연마재과립층, 및 사이즈피복층으로 구성되고, 메이크피복층과 사이즈피복층중의 적어도 하나는 하기의 경화성부와 광개시제부로 구성되는 전자기방사선경화성 조성물로 성형되는 것을 특징으로 하는 피복연마재제품 : (1) 하기의 군에서 선택된 경화성부 : (A) 적어도 하나의 에틸렌성불포화기 및 적어도 하나의 1,2-에폭시드기를 함유하는 적어도 하나의 이반응성화합물, (B) 적어도 하나의 에틸렌성 불포화화합물과 적어도 하나의 1,2-에폭시드기를 함유하는 적어도 하나의 화합물, (C) 적어도 하나의 에틸렌성 불포화기와 적어도 하나의 1,2-에폭시드기를 함유하는 적어도 하나의 이반응성화합물, 및 적어도 하나의 에틸렌성 불포화화합물, (D) 적어도 하나의 에틸렌성불포화기와 적어도 하나의 1,2-에폭시드기를 함유하는 적어도 하나의 이반응성화합물, 및 적어도 하나의 1,2-에폭시드기를 함유하는 적어도 하나의 화합물, 및 (E) 적어도 하나의 에틸렌성불포화기 및 적어도 하나의 1,2-에폭시드기를 함유하는 적어도 하나의 이반응성 화합물, 적어도 하나의 에틸렌성 불포화화합물, 및 적어도 하나의 1,2-에폭시드기를 함유하는 적어도 하나의 화합물, (2) 하기의 군에서 선택된 적어도 하나의 중합광개시제로 구성되고, 상기 조성물을 경화하는데 충분한 양의 광개시제부 : (a) 오늄양이온 및 금속 또는 비금속의 할로겐함유착음이온을 가지는 염 및 (b)(a)금속 또는 비금속의 유기금속착음이온을 가지는 적어도 하나의 염과 (b) 적어도 하나의 자유라디칼 중합개시제의 혼합물.
  13. 배킹, 메이크피복층, 연마제과립층, 및 사이즈피복층으로 구성되고, 상기 배킹은 적어도 하나의 포화제피복층, 프리사이즈피복층, 또는 백사이즈피복층을 가지고, 적어도 하나의 상기 포화제피복층, 프리사이즈피복층, 또는 백사이즈피복층은 에틸렌성불포화기와 1,2-에폭시드기를 함유하는 전자기방사선 경화성 조성물과, (1) 오늄양이온과 금속 또는 비금속의 할로겐함유 음이온 및 (2) (a) 유기금속착양이온과 금속 또는 비금속의 할로겐함유착음이온을 가지는 적어도 하나의 염과 (b) 적어도 하나의 자유라디칼 중합개시제의 혼합물로 이루어지는 군에서 선택된 적어도 하나의 중합광개시제로 구성되는 상기 조성물경화에 충분한 양의 광개시제부로 성형되는 것을 특징으로 하는 피복연마재 제품.
  14. 배킹, 메이크피복층, 연마재과립층, 및 사이즈피복층으로 구성되고, 상기 배킹은 적어도 하나의 포화제피복층, 프리사이즈피복층, 또는 백사이즈피복층을 가지고, 상기 포화제피복층, 프리사이즈피복층, 또는 백사이즈 피복층중의 하나는 하기의 경화성부와 광개시제부로 구성되는 전자기방사선경화성 조성물로 성형되는 것을 특징으로 하는 피복연마재 제품 : (1) 하기의 군에서 선택된 경화성부 : (A)적어도 하나의 에틸렌성불포화기 및 적어도 하나의 1,2-에폭시드기를 함유하는 적어도 하나의 이반응성화합물, (B) 적어도 하나의 에틸렌성불포화화합물과 적어도 하나의 1,2-에폭시드기를 함유하는 적어도 하나의 화합물, (C) 적어도 하나의 에틸렌성불포화기와 적어도 하나의 1,2-에폭시드기를 함유하는 적어도 하나의 이반응성화합물, 및 적어도 하나의 에틸렌성 불포화화합물, (D) 적어도 하나의 에틸렌성불포화기와 적어도 하나의 1,2-에폭시드기를 함유하는 적어도 하나의 이반응성화합물, 및 적어도 하나의 1,2-에폭시드기를 함유하는 적어도 하나의 화합물, 및 (E) 적어도 하나의 에틸렌성불포화기 및 적어도 하나의 1,2에폭시드기를 함유하는 하나의 이반응성화합물, 적어도 하나의 에틸렌성불포화화합물, 적어도 하나의 1,2-에폭시드기를 함유하는 적어도 하나의 화합물, (2) 하기의 군에서 선택된 적어도 하나의 중합광개시제로 구성되고, 상기 조성물을 경화하는데 충분한 양의 광개시제부 : (a) 오늄양이온 및 금속 또는 비금속의 할로겐함유착음이온을 가지는 염 및 (b) (a)금속 또는 비금속의 유기금속착음이온을 가지는 적어도 하나의 염과(b)적어도 하나의 자유라디칼 중합개시제의 혼합물.
  15. 제13항에 있어서, 광개시제의 총량이 상기 방사선경화성조성물의 약 0.05 내지 약 10중량부의 범위내인 것을 특징으로 하는 제품.
  16. 제13항에 있어서, 상기 메이크피복층 및 사이즈피복층중 적어도 하나가 페놀수지로 성형되는 것을 특징으로 하는 제품.
  17. 수지성결합제 물질에 의해서 배킹의 적어도 하나의 주표면에 지지 및 접착되는 연마제과립으로 구성되고, 상기 수지성 결합제 물질은 에틸렌성불포화기와 1,2-에폭시드기를 함유하는 전자기방사선 경화성조성물과, (1) 오늄양이온과 금속 또는 비금속의 할로겐함유음이온, 및 (2) (a) 유기금속착양이온과 금속 또는 비금속의 할로겐함유착음이온을 가지는 적어도 하나의 염과 (b) 적어도 하나의 자유라디칼 중합개시제의 혼합물로 이루어지는 군에서 선택된 적어도 하나의 중합광개시제로 구성되는 상기 조성물 경화에 충분한 양의 광개시제부로 구성되는 것을 특징으로 하는 피복연마제품.
  18. 하기의 단계로 이루어지는 제1항의 피복연마재제품의 제조방법. (1) 배킹을 준비하고, (2) 상기 배킹위에 메이크복층을 도포하고, (3) 상기 메이크피복층위에 연마재과립층을 도포하고, (4) 상기 연마재과립층 위에 사이즈피복층을 도포하고, (5) 상기 메이크피복층 또는 사이즈피복층중 적어도 하나를 전자기방사에 의해 경화한다.
  19. 하기의 단계로 이루어지는 제13항의 피복연마제제품의 제조방법. (1) 적어도 하나의 포화제피복층, 피리사이즈피복층, 또는 백사이즈피복층을 가지는 배킹을 준비하고, (2) 적어도 하나의 상기 포화제피복층, 프리사이즈피복층 또는 백사이브피복층을 전자기방사에 의해 경화하고, (3) 상기 배킹위에 메이크피복층을 도포하고, (4) 상기 메이크피복층 위에 연마재과립층을 도포하고, (5) 상기 연마재과립층 위에 사이즈피복층을 도포하고, (6) 상기 메이크피복층과 사이즈피복층을 경화한다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870008745A 1986-08-11 1987-08-10 방사선 경화성 결합제를 가지는 피복연마재 KR940011166B1 (ko)

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ZA874819B (en) 1989-02-22
DE3781346D1 (de) 1992-10-01
AU595629B2 (en) 1990-04-05
KR940011166B1 (ko) 1994-11-24
JP2664156B2 (ja) 1997-10-15
EP0257757A2 (en) 1988-03-02
AU7538987A (en) 1988-02-18
DE3781346T2 (de) 1993-03-04
HK94593A (en) 1993-09-17
EP0257757B1 (en) 1992-08-26
JPS6347068A (ja) 1988-02-27
BR8704055A (pt) 1988-04-05
EP0257757A3 (en) 1990-05-09
CA1285395C (en) 1991-07-02
ES2051739T3 (es) 1994-07-01
US4751138A (en) 1988-06-14
MX165798B (es) 1992-12-04

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