KR870007959A - 폴리이미드 및 폴리이미드 내열성 접착제 - Google Patents

폴리이미드 및 폴리이미드 내열성 접착제 Download PDF

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KR870007959A
KR870007959A KR870001164A KR870001164A KR870007959A KR 870007959 A KR870007959 A KR 870007959A KR 870001164 A KR870001164 A KR 870001164A KR 870001164 A KR870001164 A KR 870001164A KR 870007959 A KR870007959 A KR 870007959A
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repeating unit
polyimide
polyamic acid
condensed polyaromatic
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히데아끼 오이가와
마사히로 오따
사부로 가와시마
쇼지 다마이
요시호 소노베
아끼히로 야마구찌
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도쯔가 야스아끼
미쓰이도 오아쯔 가가꾸 가부시기가이샤
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/40Polyesters derived from ester-forming derivatives of polycarboxylic acids or of polyhydroxy compounds, other than from esters thereof
    • C08G63/44Polyamides; Polynitriles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1046Polyimides containing oxygen in the form of ether bonds in the main chain
    • C08G73/105Polyimides containing oxygen in the form of ether bonds in the main chain with oxygen only in the diamino moiety
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1057Polyimides containing other atoms than carbon, hydrogen, nitrogen or oxygen in the main chain
    • C08G73/1064Polyimides containing other atoms than carbon, hydrogen, nitrogen or oxygen in the main chain containing sulfur
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1067Wholly aromatic polyimides, i.e. having both tetracarboxylic and diamino moieties aromatically bound
    • C08G73/1071Wholly aromatic polyimides containing oxygen in the form of ether bonds in the main chain
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1085Polyimides with diamino moieties or tetracarboxylic segments containing heterocyclic moieties
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09J179/00Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09J161/00 - C09J177/00
    • C09J179/04Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C09J179/08Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31721Of polyimide

Abstract

내용 없음

Description

폴리이미드 및 폴리이미드 내열성 접착제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제 1 도 및 제 2 도는 본 발명에 따른 폴리이미드의 I R 스펙트럼을 도시한 도이다.

Claims (8)

  1. 전구물질인 폴리암산이 하기 일반식 (2)의 반복단위를 갖이며, N,N-디메틸아세트아미드용매 100ml중 전술한 폴리암산 0.5g 용액의 35°C에서의 측정한 고유점도가 0.1 내지 3.0dl/g임을 특징으로 하는 하기 일반식 (1)의 반복단위를 갖는 폴리이미드.
    상기 식에서, R은 탄소원자수 2 이하의 지방족기, 환상지방족기, 모노방향족기, 축합폴리방향족기 및 비축합폴리방향족기(방향족기는 화학결합 또는 가교결합에 의해 서로 연결됨)으로 구성되는 군 중에서 선택되는 4가의 기이다.
  2. 제 1 항에 있어서,
    R이 하기 구조식 (4) 또는 (5)의 4가의 기임을 특징으로 하는 폴리이미드.
  3. 2,6-비스(3-아미노페녹시)피리딘을 유기용매중에서 하기일반식 (3)의 테트라카르복실산 2무수물과 반응시켜 얻어지며 N,N-디메틸아세트아미드 용매 100ml중 하기 일반식 (2)의 반복단위를 갖는 폴리암산 0.5g 용액의 35℃에서의 측정한 고유점도가 0.1 내지 3.0dl/g인 전술한 폴리암산을 열적으로 또는 화학적으로 이미드화시킴을 특징으로 하는 하기 일반식 (1)의 반복단위를 갖는 폴리이미드의 제조방법.
    상기 식들에 있어서, R은 탄소원자수 2 이하이 지방족기, 환상지방족기, 모노방향족기, 축합 폴리방향족기 및 비축합 폴리방향족기(방향족기는 화학결합 또는 가교결합에 의해 서로 연결됨)으로 구성되는 군 중에서 선택되는 4가의 기이다.
  4. 제 3 항에 있어서,
    R이 하기 구조식 (4) 또는 (5)의 4가의 기임을 특징으로 하는 폴리이미드의 제조방법.
  5. N,N-디메틸아세트아미드용매 100ml 중 하기 일반식 (2)의 반복단위를 갖는 폴리암산 전구물질 0.5g 용액의 35℃에서의 측정한 고유점도가 0.1 내지 3.0dl/g이고, 전술한 폴리암산이 하기 일반식 (2)의 반복단위를 갖임을 특징으로 하는 하기 일반식(Ⅰ)의 반복단위를 갖는 내열성 폴리이미드의 접착제.
    상기 식에서, R은 탄소원자수 2 이하의 지방족기, 환상지방족기, 모노방향족기, 축합폴리방향족기 및 비축합폴리방향족기(방향족기는 화학결합 또는 가교결합에 의해 서로 연결됨)으로 구성되는 군중에서 선택되는 4가의 기이다.
  6. 제 5 항에 있어서,
    R이 하기 구조식 4가의 기임을 특징으로 하는 내열성 폴리이미드 접착제.
  7. N,N-디메틸아세트아미드 용매 100ml중 하기 일반식 (2)의 반복단위를 갖는 폴리암산 전구물질 0.5g 용액의 35℃에서의 측정한 고유점도가 0.1 내지 3.0dl/g이고, 하기 일반식 (1)의 반복단위를 갖는 폴리이미드를 기질상에 도포 부착시키고, 이 기질을 제 2 의 기질로 중첩시킨 다음 폴리이미드의 글라스전이점 이상의 압력하에 가열시킴을 특징으로 하는 접착방법.
    상기 식들에 있어서, R은 탄소원자수 2 이하의 지방족기, 환상지방족기, 모노방향족기, 축합폴리방향족기 및 비축합폴리방향족기(방향족기는 화학결합 또는 가교결합에 의해 서로 연결됨)로 구성되는 군 중에서 선택되는 4가의 기이다.
  8. 제 7 항에 있어서,
    R이 하기 구조식의 4가의 기임을 특징으로 하는 접착방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870001164A 1985-09-03 1987-02-12 내열성 접착제용 폴리이미드의 제조방법 및 접착방법 KR900008963B1 (ko)

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JP60193020A JPS6253388A (ja) 1985-09-03 1985-09-03 耐熱性接着剤
JP26936 1986-02-12
JP61026936A JPS62185714A (ja) 1985-09-03 1986-02-12 ポリイミドおよびポリイミドよりなる耐熱性接着剤

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KR900008963B1 KR900008963B1 (ko) 1990-12-15

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US (1) US4797466A (ko)
EP (1) EP0233069B1 (ko)
JP (2) JPS6253388A (ko)
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AU (2) AU579272B2 (ko)
CA (2) CA1274937A (ko)
CH (1) CH671230A5 (ko)
DE (1) DE3788441T2 (ko)
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NL (1) NL8700005A (ko)

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EP0233069B1 (en) 1993-12-15
CA1274938A (en) 1990-10-02
AU579272B2 (en) 1988-11-17
DE3788441T2 (de) 1994-05-19
EP0233069A3 (en) 1988-09-07
AU6717387A (en) 1988-07-07
KR900008963B1 (ko) 1990-12-15
GB8700164D0 (en) 1987-02-11
NL8700005A (nl) 1988-08-01
US4797466A (en) 1989-01-10
DE3788441D1 (de) 1994-01-27
AU580468B2 (en) 1989-01-12
CH671230A5 (ko) 1989-08-15
AU6867987A (en) 1987-08-13
JPS62185714A (ja) 1987-08-14
EP0233069A2 (en) 1987-08-19
JPH0530851B2 (ko) 1993-05-11
CA1274937A (en) 1990-10-02
GB2199586A (en) 1988-07-13
GB2199586B (en) 1990-05-23
JPS6253388A (ja) 1987-03-09

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