KR870001250A - 상호 침투하는 중합체그물구조를 함유하는 중합체 유제 - Google Patents

상호 침투하는 중합체그물구조를 함유하는 중합체 유제 Download PDF

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KR870001250A
KR870001250A KR1019860005579A KR860005579A KR870001250A KR 870001250 A KR870001250 A KR 870001250A KR 1019860005579 A KR1019860005579 A KR 1019860005579A KR 860005579 A KR860005579 A KR 860005579A KR 870001250 A KR870001250 A KR 870001250A
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polymer
emulsion
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polyacrylonitrile
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케이 린드만 마르틴
디이콘 킴
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썬 케미칼 코오퍼레이션
버어너드 엠. 재프
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/08—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
    • C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F263/00—Macromolecular compounds obtained by polymerising monomers on to polymers of esters of unsaturated alcohols with saturated acids as defined in group C08F18/00
    • C08F263/02—Macromolecular compounds obtained by polymerising monomers on to polymers of esters of unsaturated alcohols with saturated acids as defined in group C08F18/00 on to polymers of vinyl esters with monocarboxylic acids
    • C08F263/04—Macromolecular compounds obtained by polymerising monomers on to polymers of esters of unsaturated alcohols with saturated acids as defined in group C08F18/00 on to polymers of vinyl esters with monocarboxylic acids on to polymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
    • C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C08L31/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/52—Aqueous emulsion or latex, e.g. containing polymers of a glass transition temperature (Tg) below 20°C
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/04—Polymer mixtures characterised by other features containing interpenetrating networks
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/903—Interpenetrating network
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2861—Coated or impregnated synthetic organic fiber fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2926—Coated or impregnated inorganic fiber fabric
    • Y10T442/2934—Coating or impregnation contains vinyl polymer or copolymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2926—Coated or impregnated inorganic fiber fabric
    • Y10T442/2934—Coating or impregnation contains vinyl polymer or copolymer
    • Y10T442/2943—Vinyl acetate polymer or copolymer

Abstract

내용 없음.

Description

상호 침투하는 중합체그물구조를 함유하는 중합체 유제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (24)

  1. a) 활성가교제를 내포하는 제1중합체 유제를 형성하고, b) 제1중합체 유제와 제2단량체 유제를 혼합하며, c) 유제혼합물을 평형시키고, d) 제2중합체 그물구조와 분자크기를 뒤섞어 꼬이는 제1중합체 그물구조를 제공하여 유체혼합물을 중합시키며, 제2중합체가 제1중합체와 다르며 제1중합체가 고형물에 대해 유체혼합물의 중량기준으로 5 내지 95%로 이루어지는 것을 특징으로 하는 수성중합체를 제조하는 방법.
  2. 제1항에 있어서, 제1중합체 유제가 제1단량체 유제를 중합하므로써 형성되는 것을 특징으로 하는 방법.
  3. 제1항에 있어서, 제1중합체 유제가 중합체를 유화하므로써 형성되는 것을 특징으로 하는 방법.
  4. 제1항에 있어서, 제1중합체 유제가 유제혼합물의 중량기준으로 고형물에 대해 20 내지 80%로 이루어지는 것을 특징으로 하는 방법.
  5. 제1항에 있어서, 제2단량체 유제가 활성가교제, 잠재가교제 및 그들의 혼합물로 이루어지는 군으로부터 선택된 가교제를 내포하는 것을 특징으로 하는 방법.
  6. 제5항에 있어서, 제1중합체 유제와 제2단량체 유제의 적어도 하나가 잠재 교차결합단량체를 내포하는 것을 특징으로 하는 방법.
  7. 제6항에 있어서, 제1중합체 유제에서의 중합체는 폴리메틸 메타크릴레이트, 폴리비닐아세테이트, 폴리스티렌, 폴리아크릴리로니트릴 및 그들의 공중합체로 이루어지는 군으로부터 선택되는 것을 특징으로 하는 방법.
  8. 제7항에 있어서, 제2단량체 유제에서의 단량체는 아크릴로니트릴, 메틸메타크릴레이트, 부틸아크릴레이트, 스티렌 및 그들의 혼합물로 이루어지는 군으로부터 선택되는 것을 특징으로 하는 방법.
  9. 제1항에 있어서, 제1중합체 유제가 제2단량체 유제내의 단량체 중합에 대해 억지제가 아닌 단량체에 기준을 두는 것을 특징으로 하는 방법.
  10. 제1항에 있어서, 제1중합체 유제가 폴리비날아세테이트를 내포하고 제2단량체 유제가 스티렌, 메틸메타크릴레이트, 부틸아크릴레이트, 아크릴로니트릴 및 그들의 혼합물로 이루어지는 군으로부터 선택된 단량체를 내포하는 것을 특징으로 하는 방법.
  11. 제1항에 있어서, 제1중합체 유제가 공중합될 수 없는 제2단량체 유제내의 제2단량체의 단량체와 양립할 수 없는 단량체에 기준을 두는 것을 특징으로 하는 방법.
  12. 제1 또는 제5 내지 제11항중의 어느 하나에 있어서, 기체에 공중합 유제를 가한다음 제1 및 제2그물구조의 결합을 완료하기 위해서 건조 및 가열시키는 것으로 더 구성된 것을 특징으로 하는 방법.
  13. 특허청구의 범위 제1항 또는 제6 내지 제12항중의 어느 하나에서와 같은 방법으로 제조된 중합체 유제.
  14. 제12항에 있어서, 중합체 유제가 바인더, 부착제, 코팅제로서 기제에 가해지는 것을 특징으로 하는 방법.
  15. 제14항에 있어서, 중합체 유제가 섬유, 부직포, 제직물 편성물로 이루어지는 군으로부터 선택된 기제에 가해지는 것을 특징으로 하는 방법.
  16. 특허청구의 범위 제14항의 방법으로 제조된 제품.
  17. 제2중합체 그물구조와 분자크기로 뒤섞여 꼬인 활성 가교제를 내포하는 제1중합체 그물구조를 함유하는 수성중합체 유제로 이루어지며, 상기 제2중합체가 상기 제1중합체와 다르고 상기 제1중합체가 유제 혼합물의 중량기준으로 고형물에 대해 5 내지 95%로 이루어지는 바인더에 의해 접합된 섬유충전제로 구성되는 것을 특징으로 하는 섬유 충전제품.
  18. 제17항에 있어서, 제1중합체 그물구조의 중합체가 폴리메틸 메타크릴레이트, 폴리비닐아세테이트, 폴리스틸렌, 폴리아크릴로니트릴 및 그들의 공중합체로 이루어지는 군으로부터 선택되는 것을 특징으로 하는 섬유 충전제품.
  19. 제18항에 있어서, 제2중합체 그물구조의 중합체가 제1중합체와 다르며, 폴리아크릴로니트릴, 폴리메틸메타크릴레이트, 폴리부틸아크릴레이트, 폴리스티렌 및 그들의 공중합체로 이루어지는 군으로부터 선택되는 것을 특징으로 하는 섬유 충전제품.
  20. 제17항에 있어서, 제1중합체 및 제2중합체가 공중합될 수 없이 양립할 수 없는 것을 특징으로 하는 섬유 충전제품.
  21. 제2중합체 그물구조와 분자크기로 뒤섞여 꼬이는 활성가교제를 내포하는 제1중합체 그물구조로 이루어지며, 상기 제2중합체가 상기 제1중합체와 다르며, 상기 제1중합체가 유제혼합물의 중량기준으로 고형물에 5 내지 95%로 이루어지는 것을 특징으로 하는 중합체 유제.
  22. 제21항에 있어서, 제1중합체 그물구조의 중합체가 폴리메타크릴레이트, 폴리비닐아세테이트, 폴리스티렌, 폴리아크릴로니트릴 및 그들의 공중합체로 이루어지는 군으로부터 선택되는 것을 특징으로 하는 중합체 유제.
  23. 제22항에 있어서, 제2중합체 그물구조의 중합체가 제1중합체와 다르며, 폴리아크릴로니트릴, 폴리메틸메타크릴레이트, 폴리부틸아크릴레이트, 폴리스티렌 및 그들의 공중합체로 이루어지는 군으로부터 선택되는 것을 특징으로 하는 중합체 유제.
  24. 제21항에 있어서, 제1중합체와 제2중합체가 공중합될 수 없어 양립할 수 없는 것을 특징으로 하는 중합체 유제.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860005579A 1985-07-10 1986-07-10 상호 침투하는 중합체 그물구조를 함유하는 중합체 유제 KR950006267B1 (ko)

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US06/753,685 US4616057A (en) 1985-07-10 1985-07-10 Polymer emulsion containing an interpenetrating polymer network
US753,685 1985-07-10

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AR244705A1 (es) 1993-11-30
AU6001686A (en) 1987-01-15
IL79317A (en) 1990-09-17
ZA865072B (en) 1988-02-24
ES2000477A6 (es) 1988-03-01
FI862906A (fi) 1987-01-11
BR8603237A (pt) 1987-02-24
DK168668B1 (da) 1994-05-16
NO168363B (no) 1991-11-04
EP0209325A2 (en) 1987-01-21
DK318886A (da) 1987-01-11
FI90880B (fi) 1993-12-31
JPS6230105A (ja) 1987-02-09
KR950006267B1 (ko) 1995-06-13
FI90880C (fi) 1994-04-11
DK318886D0 (da) 1986-07-04
AU601155B2 (en) 1990-09-06
NO862778L (no) 1987-01-12
MX165076B (es) 1992-10-21
DE3684374D1 (de) 1992-04-23
IL79317A0 (en) 1986-10-31
CA1296455C (en) 1992-02-25
US4616057A (en) 1986-10-07
NZ216744A (en) 1989-10-27
US4683165A (en) 1987-07-28
IN167872B (ko) 1991-01-05
EP0209325A3 (en) 1988-07-20
NO168363C (no) 1992-02-12
EP0209325B1 (en) 1992-03-18
JP2626886B2 (ja) 1997-07-02
NO862778D0 (no) 1986-07-09
ATE73832T1 (de) 1992-04-15

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