KR860002300A - 신규의 포집제를 사용하는 기포 부유선광법에 의한 금속의 회수방법 - Google Patents

신규의 포집제를 사용하는 기포 부유선광법에 의한 금속의 회수방법 Download PDF

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KR860002300A
KR860002300A KR1019850006709A KR850006709A KR860002300A KR 860002300 A KR860002300 A KR 860002300A KR 1019850006709 A KR1019850006709 A KR 1019850006709A KR 850006709 A KR850006709 A KR 850006709A KR 860002300 A KR860002300 A KR 860002300A
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hydrocarbyl
integer
metal
omega
amino
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KR1019850006709A
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KR900002702B1 (ko
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알. 클림펠 리챠드
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리차드지. 워터맨
더 다우 케미칼 캄파니
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/02—Froth-flotation processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/001—Flotation agents
    • B03D1/004—Organic compounds
    • B03D1/014—Organic compounds containing phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/001—Flotation agents
    • B03D1/004—Organic compounds
    • B03D1/008—Organic compounds containing oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/001—Flotation agents
    • B03D1/004—Organic compounds
    • B03D1/01—Organic compounds containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/001—Flotation agents
    • B03D1/004—Organic compounds
    • B03D1/012—Organic compounds containing sulfur
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2201/00—Specified effects produced by the flotation agents
    • B03D2201/02—Collectors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2203/00—Specified materials treated by the flotation agents; specified applications
    • B03D2203/02—Ores

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  • Manufacture And Refinement Of Metals (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Physical Water Treatments (AREA)

Abstract

내용 없음

Description

신규의 포집제를 사용하는 기포 부유선광법에 의한 금속의 회수방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 수성 펄프형태의 금속광석을 하기 일반식에 상응하는 화합물로 이루어진 부유선광 포집제 존재하에 금속이 기포중에 회수되는 조건하에 기포 부유선광공정에 도입시키는 단계로 이루어진, 금속광석으로부터 금속을 회수하는 방법.
    상기식에서, R은또는 이의 혼합물이고 : n은 1내지 6의 정수이거나(여기서 m은 0내지 6의 정수이다)이며; R1및 각 R2는 독립적으로 C1-22하이드로카빌, 또는 하이드록시, 아미노, 포스포닐, 알콕시, 이미노, 카바밀, 카보닐, 티오카보닐, 시아노, 카복실, 하이드로카빌티오, 하이드로카빌옥시, 하이드로카빌아미노 및 하이드로카빌이미노중에서 선택된 1종 이상의 잔기로 치횐된 C1-22하이드로 카빌이고(단, R2는 N원자에 직접 결합되는 2개의 원자를 갖는 2가 라디칼일 수 있다);
    X는또는(여기서 R3는 수소 또는 C1-22하이드로카빌이다)이며; a는 0,1 또는 2의 정수이고 ; b는 0,1 또는 2의 정수이며 ; 단 R2가 N원자에 직접 결합되는 2개의 원자가를 갖는 2가 라디칼인 경우에 b=0 이고 a=1이거나일 경우에 a+b=0인 것을 제외하고 a+b는 2이고, X가또는경우에 상기 카보닌 그룹은 R1에 결합된다.
  2. 제1항에 있어서, 금속광석 화합물이 하기 일반식에 상응하는 방법.
    상기식에서, R1은 하나 이상의 하이드록시, 아미노, 포스포닌 또는 알콕시 잔기로 치환된 C1-22하이드로카빌이고; R2는 C1-6알킬, C1-6알킬카보닌, 아미노, 하이드록시 또는 포스포닌 잔기로 치환된 C1-6알킬그룹, 또는 아미노, 하이드록시 또는 포스포닐 잔기로 치환된 C1-6알킬카보닐 그룹이며; X,a,b 및 n은 제1항에서 정의한 바와 같다.
  3. 제2항에 있어서, R1이 C2-14하이드로카빌이고, R2는 C1-6알킬카보닐이며, R3가 수소 또는 C2-14하이드로카빌이고, a는 0 또는 1의 정수이며, b는 1또는 2의 정수이고, n은 1내지 4의 정수인방법.
  4. 제3항에 있어서, R1이 C4-11하이드로카빌이고, R2는 C1-4알킬 또는 C14알킬카보닐이며, R3가 수소 또는 C4-11하이드로카빌이고, n은 2또는 3의 정수이며, X가 -S-,또는 -O-인 방법.
  5. 제4항에 있어서, X가 -S- 또는인 방법.
  6. 제4항에 있어서, X가 -S-인 방법.
  7. 제1또는 2항에 있어서, 포집제가 오메가-(하이드로카빌티오)-알킬아몇, S-(오메가-아미노알킬)탄화수소 티오에이트, N-(하이드로카빌)-알파ㅡ 오메가-알칸디아민(오메가-아미노알킬)탄화수소아미드, 오메가-(하이드로카빌옥시-)-알킬아민, 오메가-아미노알킬 하이드로카보노에이트 및 이의 혼합물중에서 선택되는 방법.
  8. 제1내지 3항중 어느 하나에 있어서, 포집제를 5내지 250g/미터톤의 양으로 가하는 방법.
  9. 제1내지 4및 8항중 어느 하나에 있어서, 회수된 금속이 금속 황화물, 금속 산화물 또는 귀금속인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019850006709A 1984-09-13 1985-09-13 신규의 포집제를 사용하는 기포 부유선광법에 의한 금속의 회수방법 KR900002702B1 (ko)

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US64989084A 1984-09-13 1984-09-13
US649890 1984-09-13

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KR860002300A true KR860002300A (ko) 1986-04-24
KR900002702B1 KR900002702B1 (ko) 1990-04-23

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EP (1) EP0174866B1 (ko)
JP (2) JPS6186960A (ko)
KR (1) KR900002702B1 (ko)
CN (3) CN85107378A (ko)
AR (1) AR242135A1 (ko)
AU (1) AU562083B2 (ko)
BR (1) BR8504419A (ko)
CA (1) CA1265877A (ko)
DE (1) DE3587166D1 (ko)
ES (1) ES8700699A1 (ko)
FI (1) FI79951C (ko)
MX (1) MX169955B (ko)
MY (1) MY101975A (ko)
NO (1) NO166846C (ko)
PH (1) PH21358A (ko)
PL (1) PL146943B1 (ko)
RO (1) RO95694B (ko)
SU (1) SU1419507A3 (ko)
TR (1) TR25780A (ko)
YU (1) YU45741B (ko)
ZA (1) ZA856955B (ko)
ZM (1) ZM6585A1 (ko)
ZW (1) ZW15285A1 (ko)

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CN104028387B (zh) * 2014-06-17 2017-01-25 扬州大学 一种新型煤炭浮选剂的合成
CN104874488B (zh) * 2015-06-05 2017-05-24 昆明冶金研究院 一种捕收剂及其制备方法与应用
CN106669959B (zh) * 2016-06-20 2019-02-22 中国矿业大学 一种细粒中煤的浮选药剂及其应用
CN107138289B (zh) * 2017-06-26 2019-07-12 乌拉特前旗西沙德盖钼业有限责任公司 一种阳离子型选矿用起泡剂
CN109174463B (zh) * 2018-08-21 2020-02-28 中国矿业大学 用于氧化煤煤泥浮选的捕收剂以及制备方法、浮选方法
JP7344504B2 (ja) * 2018-09-14 2023-09-14 国立大学法人九州大学 選鉱方法
CN109365138B (zh) * 2018-11-30 2021-03-05 河南城建学院 一种用于硫化铜镍矿浮选的新型复合浮选剂
CN109530094B (zh) * 2019-01-17 2021-05-28 湖南中医药大学 酰胺基羟基羧酸/羟肟酸类化合物及其在矿物浮选中的应用
CN110015727B (zh) * 2019-05-09 2021-07-09 安徽工业大学 一种电解气浮除去水体中微塑料的方法
CA3188495A1 (en) 2020-08-11 2022-02-17 Alexej Michailovski Method for flotation of a silicate-containing iron ore
CN112058502B (zh) * 2020-09-07 2021-08-27 中南大学 一种硫化锌的高效浮选捕收剂及其应用
CN113245064A (zh) * 2021-04-30 2021-08-13 瓮福（集团）有限责任公司 一种复杂难选胶磷矿中倍半氧化物的脱除方法

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MY101975A (en) 1992-02-29
MX169955B (es) 1993-08-02
KR900002702B1 (ko) 1990-04-23
RO95694B (ro) 1989-01-31
PH21358A (en) 1987-10-15
JPH0152063B2 (ko) 1989-11-07
EP0174866B1 (en) 1993-03-10
CN85107378A (zh) 1987-03-18
PL255363A1 (en) 1987-10-19
FI853490A0 (fi) 1985-09-12
NO853580L (no) 1986-03-14
AU562083B2 (en) 1987-05-28
AR242135A1 (es) 1993-03-31
YU144085A (en) 1987-12-31
SU1419507A3 (ru) 1988-08-23
ZM6585A1 (en) 1987-04-30
BR8504419A (pt) 1986-07-15
ZW15285A1 (en) 1987-04-08
FI79951B (fi) 1989-12-29
ES546919A0 (es) 1986-10-16
ES8700699A1 (es) 1986-10-16
CN85109643A (zh) 1987-04-15
DE3587166D1 (de) 1993-04-15
TR25780A (tr) 1993-07-28
JPS63107761A (ja) 1988-05-12
RO95694A (ro) 1989-01-30
PL146943B1 (en) 1989-04-29
ZA856955B (en) 1987-05-27
CN1006689B (zh) 1990-02-07
NO166846B (no) 1991-06-03
CN1020551C (zh) 1993-05-12
EP0174866A2 (en) 1986-03-19
CN85106476A (zh) 1987-03-25
FI853490L (fi) 1986-03-14
EP0174866A3 (en) 1989-09-06
AU4739785A (en) 1986-03-20
FI79951C (fi) 1990-04-10
CA1265877A (en) 1990-02-13
YU45741B (sh) 1992-07-20
JPS6186960A (ja) 1986-05-02
NO166846C (no) 1991-09-11

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