KR840005981A - 메타크롤레인 합성용 촉매 - Google Patents

메타크롤레인 합성용 촉매 Download PDF

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KR840005981A
KR840005981A KR1019830004165A KR830004165A KR840005981A KR 840005981 A KR840005981 A KR 840005981A KR 1019830004165 A KR1019830004165 A KR 1019830004165A KR 830004165 A KR830004165 A KR 830004165A KR 840005981 A KR840005981 A KR 840005981A
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outer diameter
element selected
hollow cylinder
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KR890000517B1 (ko
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노보루(외3) 사이또
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이시가와 사부로
닛뽕쇼꾸바이가가꾸고오교가부시끼가이샤
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    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
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    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
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    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
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    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

메타 크롤레인 합성용 촉매
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
첨부된 도면은 본 발명의 촉매를 나타내는 투시도이다.

Claims (2)

  1. 하기 일반식 MoaWbBieFedAeBfCgDhO의 제성을 가지며, 외직경이 3.0~10.0㎜, 내직경이 외직경의 0.1~0.7배 및 길이가 외직경의 0.5~2.0배인 속이 빈 실리더형으로 성형됨을 특징으로 하는, 이소부틸렌 또는 3차 부탄올의 증기상 산화에 의한 메타크롤레인 합성용 촉매.
    (상기식에서 A는 니켈 및 코발트 중에서 선택된 하나 이상의 원소를 나타내고, B는 알칼리금속, 알칼리토금속 및 탈륨중에서 선택된 하나 이상의 원소를 나타내며, C는 인, 텔루리움, 안티몬, 주석, 세륨, 납, 니오븀, 망간 및 아연중에서 선택된 하나 이상의 원소를 나타내고, D는 실리콘, 알루미늄, 지르코늄 및 티타늄 중에서 선택된 하나 이상의 원소를 나타내며, a,b,c,d,e,f,g,h는 x는 각각 Mo,W,Bi, Fe,A,B,C,D 및 O의 원자비를 나타내고, 이때 a는 12이며, b는 0~10, c는 0.1~10, d는 0.1~20, e는 2~20, f는 0~10, g는 0~4, h는 0~30, 및 x는 각 원소의 원자균형에 의해 결정된 수이다.)
  2. 제1항에 있어서, D가 속이 빈 실린더의 외직경이고 d가 속이 빈 실린더의 내직경일때,가 1.0~4.0㎜인 촉매.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019830004165A 1982-09-06 1983-09-05 메타크롤레인 합성용 촉매 KR890000517B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP57153819A JPS5946132A (ja) 1982-09-06 1982-09-06 メタクロレイン合成用触媒
JP153819 1982-09-06
JP153819/82 1982-09-06

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KR840005981A true KR840005981A (ko) 1984-11-21
KR890000517B1 KR890000517B1 (ko) 1989-03-20

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US (1) US4511671A (ko)
EP (1) EP0102641B1 (ko)
JP (1) JPS5946132A (ko)
KR (1) KR890000517B1 (ko)
DE (1) DE3380685D1 (ko)

Families Citing this family (58)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0699335B2 (ja) * 1984-02-01 1994-12-07 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造法
JPH0662463B2 (ja) * 1984-02-03 1994-08-17 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造法
JPS6122040A (ja) * 1984-07-10 1986-01-30 Mitsubishi Rayon Co Ltd メタクロレイン及びメタクリル酸の製造法
JPH0625085B2 (ja) * 1984-07-24 1994-04-06 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造法
JPH0625084B2 (ja) * 1984-07-23 1994-04-06 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造法
US4783545A (en) * 1985-12-20 1988-11-08 The Standard Oil Company Method for ammoxidation of paraffins and catalyst system therefor
US4788173A (en) * 1985-12-20 1988-11-29 The Standard Oil Company Catalytic mixtures for ammoxidation of paraffins
JPS63122642A (ja) * 1986-11-11 1988-05-26 Mitsubishi Rayon Co Ltd メタクロレイン及びメタクリル酸の製造法
US5208371A (en) * 1986-11-11 1993-05-04 Mitsubishi Rayon Co., Ltd. Process for production of methacrolein and methacrylic acid
EP0279374B1 (en) * 1987-02-17 1992-01-02 Nippon Shokubai Kagaku Kogyo Co., Ltd Catalyst for oxidation of olefin or tertiary alcohol and process for production thereof
DE3827639A1 (de) * 1988-08-16 1990-02-22 Basf Ag Katalysator fuer die oxidation und ammonoxidation von (alpha),ss-ungesaettigten kohlenwasserstoffen
DE3930534A1 (de) * 1989-09-13 1991-03-21 Degussa Verfahren zur herstellung von acrolein durch katalytische gasphasenoxidation von propen
DE3930533C1 (ko) * 1989-09-13 1991-05-08 Degussa Ag, 6000 Frankfurt, De
KR950006522B1 (ko) * 1989-12-06 1995-06-16 가부시끼가이샤 닛뽕쇼꾸바이 메타크롤레인 및 메타크릴산의 제조방법
DE4018512A1 (de) * 1990-06-09 1991-12-12 Wacker Chemie Gmbh Zylindrisch geformter katalysator und dessen verwendung bei der oxichlorierung von ethylen
DE69101032T2 (de) * 1990-07-03 1994-08-11 Kuraray Co Katalysator und Verfahren zur Herstellung von ungesättigten Estern.
KR950004031B1 (ko) * 1991-02-27 1995-04-22 미쓰이도오아쓰가가꾸 가부시끼가이샤 메타크롤레인의 제조방법 및 메타크롤레인의 제조에 사용하는 촉매의 제조방법
JPH05154205A (ja) * 1991-06-07 1993-06-22 San Fuiirudo:Kk 治療具
BE1005723A5 (fr) * 1992-03-25 1993-12-28 Univ Catholique Louvain Systeme catalytique pour l'oxydation selective de compose organique et procede de preparation d'un tel systeme.
IT1256156B (it) * 1992-10-06 1995-11-29 Montecatini Tecnologie Srl Catalizzatore in granuli particolarmente per la deidrogenazione ossidativa di metanolo a formaldeide
US5861353A (en) * 1992-10-06 1999-01-19 Montecatini Tecnologie S.R.L. Catalyst in granular form for 1,2-dichloroethane synthesis
CN1046499C (zh) * 1994-06-22 1999-11-17 旭化成工业株式会社 制备异丁烯醛的方法
KR960021143A (ko) * 1994-12-05 1996-07-18 황선두 메타크로레인 제조용 촉매
KR100569632B1 (ko) 1999-05-13 2006-04-10 가부시키가이샤 닛폰 쇼쿠바이 불포화 알데히드 및 불포화 카르복실산을 제조하기 위한촉매 및 이 촉매를 사용하여 불포화 알데히드 및 불포화카르복실산을 제조하기 위한 방법
ES2226288T3 (es) * 1999-05-21 2005-03-16 Evc Technology Ag Catalizador y procedimiento de oxicloracion que lo usa.
JP4185217B2 (ja) * 1999-05-25 2008-11-26 株式会社日本触媒 複合酸化物触媒、並びに（メタ）アクロレインおよび（メタ）アクリル酸の製造方法
JP3943311B2 (ja) 2000-05-19 2007-07-11 株式会社日本触媒 不飽和アルデヒドおよび不飽和カルボン酸の製造方法
DE10063162A1 (de) * 2000-12-18 2002-06-20 Basf Ag Verfahren zur Herstellung einer Mo, Bi, Fe sowie Ni und/oder Co enthaltenden Multimetalloxidativmasse
JP3892244B2 (ja) * 2001-03-21 2007-03-14 株式会社日本触媒 不飽和アルデヒドおよび不飽和カルボン酸製造用触媒の製造方法
US7045657B2 (en) * 2002-04-03 2006-05-16 Nippon Shokubai Co., Ltd. Catalytic gas phase oxidation process
US20040043900A1 (en) * 2002-08-12 2004-03-04 Combs Glenn A. Heterogeneous gaseous chemical reactor catalyst
US6946422B2 (en) * 2002-12-12 2005-09-20 Saudi Basic Industries Corporation Preparation of mixed metal oxide catalysts for catalytic oxidation of olefins to unsaturated aldehydes
US7501377B2 (en) * 2003-03-31 2009-03-10 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US7232788B2 (en) * 2003-03-31 2007-06-19 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US20040192973A1 (en) * 2003-03-31 2004-09-30 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US20040225138A1 (en) * 2003-05-07 2004-11-11 Mcallister Paul Michael Reactor system and process for the manufacture of ethylene oxide
JP2007531612A (ja) * 2003-05-07 2007-11-08 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー エチレンオキシドを製造するための反応器系及び方法
BRPI0410090A (pt) * 2003-05-07 2006-05-16 Shell Int Research catalisadores contendo prata, a fabricação de tais catalisadores contendo prata e o seu uso
US20040224841A1 (en) * 2003-05-07 2004-11-11 Marek Matusz Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof
US7229945B2 (en) * 2003-12-19 2007-06-12 Saudi Basic Industrics Corporation Process of making mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
TW200600190A (en) * 2004-04-01 2006-01-01 Shell Int Research Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation
TW200613056A (en) * 2004-04-01 2006-05-01 Shell Int Research A process for preparing a silver catalyst, the catalyst, and a use of the catalyst for olefin oxidation
TW200602123A (en) * 2004-04-01 2006-01-16 Shell Int Research Process for preparing a catalyst, the catalyst, and a use of the catalyst
JP2005334932A (ja) * 2004-05-26 2005-12-08 Mitsubishi Chemicals Corp 円筒錠の打錠方法
AU2005289799A1 (en) * 2004-09-24 2006-04-06 Shell Internationale Research Maatschappij B.V. A process for selecting shaped particles, a process for installing a system, a process for reacting a gaseous feedstock in such a system, a computer program product, and a computer system
DE102005023955A1 (de) * 2005-05-20 2006-11-23 Basf Ag Inertmaterial für den Einsatz in exothermen Reaktionen
US7732367B2 (en) * 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649112B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US7851397B2 (en) * 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649111B2 (en) * 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
JP4650354B2 (ja) 2006-06-28 2011-03-16 住友化学株式会社 不飽和アルデヒド及び／又は不飽和カルボン酸製造用触媒の再生方法、並びに不飽和アルデヒド及び／又は不飽和カルボン酸の製造方法
US7799946B2 (en) * 2007-02-14 2010-09-21 Saudi Basic Industries Corporation Process for separating methacrolein from methacrylic acid in a gas phase product from the partial oxidation of isobutene
CN101385978B (zh) * 2007-09-12 2011-04-20 上海华谊丙烯酸有限公司 一种合成甲基丙烯醛的催化剂及其制备方法
WO2012063771A1 (ja) * 2010-11-10 2012-05-18 日本化薬株式会社 メタクロレインおよびメタクリル酸製造用触媒、ならびにその製造方法
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
JP5892826B2 (ja) 2012-03-27 2016-03-23 住友化学株式会社 メタクリル酸の製造方法
US10525448B2 (en) 2015-07-22 2020-01-07 Basf Corporation High geometric surface area catalysts for vinyl acetate monomer production

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3907712A (en) * 1970-05-26 1975-09-23 Nippon Catalytic Chem Ind Catalyst composition for the preparation of unsaturated carbonyl compounds
IT946068B (it) * 1971-11-17 1973-05-21 Sir Soc Italiana Resine Spa Perfezionamenti nei procedimenti per la produzione di catalizzatori adatti alla convwersione di metanolo in formaldeide
US4171454A (en) * 1972-07-13 1979-10-16 The Standard Oil Company Oxidation process utilizing amphora catalysts
US4111984A (en) * 1973-06-11 1978-09-05 Mitsubishi Rayon Co., Ltd. Process for producing unsaturated aldehydes, and unsaturated fatty acids
JPS5230278B2 (ko) * 1973-12-11 1977-08-06
JPS5823370B2 (ja) * 1974-01-29 1983-05-14 日本化薬株式会社 メタクロレイン ノ セイゾウホウホウ
US4001317A (en) * 1974-07-22 1977-01-04 Standard Oil Company Process for the oxidation of olefins using catalysts containing various promoter elements
JPS5163112A (en) * 1974-11-27 1976-06-01 Nippon Kayaku Kk Metakuroreinno seizoho
GB1490683A (en) * 1975-03-12 1977-11-02 Mitsubishi Rayon Co Process and a catalyst for producing unsaturated aldehydes unsaturated carboxylic acids or conjugated diene
US4086158A (en) * 1976-09-24 1978-04-25 Gulf Research & Development Company Process for upgrading solids-containing liquid hydrocarbon oils
US4217309A (en) * 1978-06-12 1980-08-12 Ube Industries, Ltd. Process for producing methacrolein
NL183170C (nl) * 1978-09-05 1988-08-16 Halcon Res & Dev Katalysator voor oxydatie van isobuteen en/of tertiaire butylalcohol.
IT1193931B (it) * 1980-04-02 1988-08-31 Alusuisse Italia Spa Catalizzatore per la produzione di anidride maleica
JPS56141842A (en) * 1980-04-07 1981-11-05 Kanegafuchi Chem Ind Co Ltd Catalyst formed in novel cylindrical shape
US4414134A (en) * 1981-01-05 1983-11-08 The Standard Oil Co. Impregnating catalysts

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JPS5946132A (ja) 1984-03-15
EP0102641A3 (en) 1986-06-18
US4511671A (en) 1985-04-16
KR890000517B1 (ko) 1989-03-20
DE3380685D1 (en) 1989-11-16
JPS6236740B2 (ko) 1987-08-08
EP0102641A2 (en) 1984-03-14
EP0102641B1 (en) 1989-10-11

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