FR2370514A1 - Production de l'anhydride maleique et catalyseurs utiles a cette fin - Google Patents
Production de l'anhydride maleique et catalyseurs utiles a cette finInfo
- Publication number
- FR2370514A1 FR2370514A1 FR7733942A FR7733942A FR2370514A1 FR 2370514 A1 FR2370514 A1 FR 2370514A1 FR 7733942 A FR7733942 A FR 7733942A FR 7733942 A FR7733942 A FR 7733942A FR 2370514 A1 FR2370514 A1 FR 2370514A1
- Authority
- FR
- France
- Prior art keywords
- production
- maleic anhydride
- catalyst
- vanadium
- useful catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/54—Preparation of carboxylic acid anhydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
- B01J27/198—Vanadium
- B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Furan Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
L'invention concerne l'industrie de la chimie organique. Elle a pour objet un catalyseur pour la production de l'anhydride maléique par oxydation d'un hydrocarbure qui comprend un oxyde mixte de phosphore/vanadium contenant comme promoteur du tungstène, de l'antimoine, du niobium et/ou du molybdène, le rapport atomique du vanadium au phosphore étant de 0,5 :1 à 2 :1 et le rapport atomique d'ensemble du molybdène, du tungstène, de l'antimoine et/ou du niobium ou vanadium étant de 0,025 : 1 à 1 : 1 tandis que la surface spécifique de catalyseur est d'au moins 10 m** 2/g. Ce catalyseur est préféré pour la production de l'anhydride maléique au départ du n-butane.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB46966/76A GB1591307A (en) | 1976-11-11 | 1976-11-11 | Production of maleic anhydride and catalysts therefor |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2370514A1 true FR2370514A1 (fr) | 1978-06-09 |
FR2370514B1 FR2370514B1 (fr) | 1984-02-10 |
Family
ID=10443247
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7733942A Granted FR2370514A1 (fr) | 1976-11-11 | 1977-11-10 | Production de l'anhydride maleique et catalyseurs utiles a cette fin |
Country Status (8)
Country | Link |
---|---|
US (1) | US4147661A (fr) |
JP (1) | JPS5361588A (fr) |
BE (1) | BE860512A (fr) |
DE (1) | DE2750327A1 (fr) |
FR (1) | FR2370514A1 (fr) |
GB (1) | GB1591307A (fr) |
IT (1) | IT1089056B (fr) |
ZA (1) | ZA776580B (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0056528A2 (fr) * | 1981-01-02 | 1982-07-28 | Monsanto Company | Intermédiaire de catalyseur, catalyseur préparé avec celui-ci et méthode de préparation de l'anhydride maléique |
Families Citing this family (51)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4209423A (en) * | 1977-05-23 | 1980-06-24 | Imperial Chemical Industries Limited | Production of acid anhydrides and catalysts therefor |
US4292202A (en) * | 1979-12-19 | 1981-09-29 | Atlantic Richfield Company | Preparation of a vanadium(IV)bis(metaphosphate) hydrocarbon oxidation catalyst containing a group VIB metal promoter |
US4292201A (en) * | 1979-12-19 | 1981-09-29 | Atlantic Richfield Company | Preparation of vanadium(IV)bis(metaphosphate) hydrocarbon oxidation catalyst containing an actinide or lanthanide series metal |
DE3010710A1 (de) * | 1980-03-20 | 1981-09-24 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur herstellung von katalysatoren fuer die gasphaseoxidation von gesaettigten und/oder ungesaettigten c(pfeil abwaerts)4(pfeil abwaerts)-kohlenwasserstoffen zu maleinsaeureanhydrid |
US4328126A (en) * | 1980-04-11 | 1982-05-04 | Standard Oil Company (Indiana) | Catalyst for the production of maleic anhydride by the oxidation of butane |
US4283288A (en) * | 1980-05-14 | 1981-08-11 | Standard Oil Company (Indiana) | Oxidation of butane to maleic anhydride |
US4315864A (en) * | 1980-10-22 | 1982-02-16 | Standard Oil Company (Ohio) | Preparation of maleic anhydride |
US4293498A (en) * | 1980-10-22 | 1981-10-06 | Standard Oil Co. | Preparation of maleic anhydride |
US4396536A (en) * | 1980-10-22 | 1983-08-02 | The Standard Oil Company | Preparation of vanadium phosphorous catalysts using olefinic oxygenated media |
US4360453A (en) * | 1980-11-28 | 1982-11-23 | The Standard Oil Company | Preparation of vanadium phosphorus catalysts |
US4400522A (en) * | 1980-11-28 | 1983-08-23 | Standard Oil Company | Preparation of maleic anhydride |
US4412940A (en) * | 1980-12-18 | 1983-11-01 | Monsanto Company | Method for preparing maleic anhydride catalyst |
US4424141A (en) | 1981-01-05 | 1984-01-03 | The Standard Oil Co. | Process for producing an oxide complex catalyst containing molybdenum and one of bismuth and tellurium |
US4443555A (en) * | 1981-06-08 | 1984-04-17 | The Standard Oil Company | Method for the preparation of high activity phosphomolybdic acid based catalysts |
US4444906A (en) * | 1981-06-08 | 1984-04-24 | The Standard Oil Company | Method for the preparation of high activity phosphomolybdic acid based catalysts |
US4365069A (en) * | 1981-07-24 | 1982-12-21 | The Standard Oil Company | Use of improved mixed vanadium phosphorus oxide catalyst in oxidation processes |
US4396535A (en) * | 1981-11-12 | 1983-08-02 | The Standard Oil Company | Preparation of mixed vanadium phosphorus oxide catalysts and their use in oxidative processes |
US4465846A (en) * | 1981-11-12 | 1984-08-14 | The Standard Oil Company | Preparation of maleic anhydride |
US4418003A (en) * | 1982-05-26 | 1983-11-29 | Standard Oil Company (Indiana) | Catalysts for the production of maleic anhydride |
US4416802A (en) * | 1982-05-26 | 1983-11-22 | Standard Oil Co. (Indiana) | Catalysts for the production of maleic anhydride by the oxidation of butane |
US4416803A (en) * | 1982-05-26 | 1983-11-22 | Standard Oil Company (Indiana) | Process for the manufacture of catalysts useful for the oxidation of butane to malelic anhydride |
US4510259A (en) * | 1982-05-26 | 1985-04-09 | Standard Oil Company (Indiana) | Catalysts for the production of maleic anhydride by the oxidation of butane |
US4434244A (en) | 1982-06-07 | 1984-02-28 | Standard Oil Company (Indiana) | Maleic anhydride catalyst recycle |
US4710484A (en) * | 1982-06-25 | 1987-12-01 | The Standard Oil Company | Method for preparing a supported mixed-metal oxide oxidation catalyst |
US4518523A (en) * | 1983-03-04 | 1985-05-21 | The Standard Oil Company | Method for adding make-up fluid bed oxidation catalysts for fluid bed oxidation catalysts containing the mixed oxides of vanadium and phosphorus |
US4510258A (en) * | 1983-08-17 | 1985-04-09 | The Lummus Company | Catalysts containing mixed oxides of vanadium and phosphorus |
US4515904A (en) * | 1983-09-30 | 1985-05-07 | Standard Oil Company (Indiana) | Catalysts for the production of maleic anhydride by the oxidation of butane |
US4699895A (en) * | 1983-09-30 | 1987-10-13 | Standard Oil Company (Indiana) | Process for the manufacture of catalysts for the production of maleic anhydride |
US4652543A (en) * | 1983-09-30 | 1987-03-24 | Standard Oil Company (Indiana) | Catalysts useful for the manufacture of maleic anhydride having a characteristic X-ray diffraction pattern |
US4632916A (en) * | 1985-07-15 | 1986-12-30 | E. I. Du Pont De Nemours And Company | Fumed silica modified catalyst |
US4699985A (en) * | 1985-07-15 | 1987-10-13 | E. I. Du Pont De Nemours And Company | Process for oxidation of N-butane to maleic anhydride |
US5158923A (en) * | 1990-05-21 | 1992-10-27 | Scientific Design Company, Inc. | Phosphorous/vanadium oxidation catalyst |
US5070060A (en) * | 1990-05-21 | 1991-12-03 | Scientific Design Company, Inc. | Phosphorous/vanadium oxidation catalyst |
US5262548A (en) * | 1990-05-21 | 1993-11-16 | Scientific Design Company, Inc. | Phosphorous/vanadium oxidation catalyst |
US5280003A (en) * | 1992-08-24 | 1994-01-18 | Scientific Design Company, Inc. | Static condition process for the preparation of phosphorous/vanadium oxidation catalyst |
US5364824A (en) * | 1992-12-08 | 1994-11-15 | Huntsman Specialty Chemicals Corporation | Catalysis for the production of maleic anhydride containing vanadium-phosphorus oxide with selected promoter elements |
US5296436A (en) * | 1993-01-08 | 1994-03-22 | Scientific Design Company, Inc. | Phosphorous/vanadium oxidation catalyst |
US5348927A (en) * | 1993-03-01 | 1994-09-20 | Scientific Design Company, Inc. | Treatment for virgin phosphorous/vanadium oxidation catalysts |
US5543532A (en) * | 1994-03-31 | 1996-08-06 | E. I. Du Pont De Nemours And Company | Catalyst and method for vapor phase oxidation of alkane hydrocarbons |
US5510308A (en) * | 1994-10-19 | 1996-04-23 | E. I. Du Pont De Nemours And Company | Cation and vanadium substituted heteropolyacid catalysts for vapor phase oxidation |
US5945368A (en) * | 1995-10-02 | 1999-08-31 | Huntsman Petrochemical Corporation | Molybdenum-modified vanadium-phosphorus oxide catalysts for the production of maleic anhydride |
DE69702728T2 (de) | 1996-04-01 | 2001-02-01 | Nippon Shokubai Co. Ltd., Osaka | Vanadium-Phosphoroxid, Verfahren zu dessen Herstellung, aus dem Oxid hergestellter Katalysator für die Dampfphasenoxidation und Verfahren für die Dampfphasenteiloxidation von Kohlenwasserstoffen |
US6107234A (en) * | 1999-01-29 | 2000-08-22 | Scientific Design Company, Inc. | Phosphorus/vanadium maleic anhydride catalyst preparation |
EP1110603A1 (fr) * | 1999-12-22 | 2001-06-27 | Haldor Topsoe A/S | Procédé de synthèse de catalyseurs de type VPO |
DE10211449A1 (de) * | 2002-03-15 | 2003-09-25 | Basf Ag | Katalysator-Precursor für die Herstellung von Maleinsäureanhydrid und Verfahren zu dessen Herstellung |
US7576233B2 (en) | 2002-06-04 | 2009-08-18 | Tessenderlo Chemie S.A. | Method for the preparation of halogenated benzonitriles |
DE10335454A1 (de) * | 2003-08-02 | 2005-02-24 | Reilly Industries, Inc., Indianapolis | Verfahren zur Herstellung von Cyanopyridinen und dafür geeignete Katalysatoren |
EP1514598A1 (fr) * | 2003-09-15 | 2005-03-16 | Lonza S.p.A. | Catalyseur à base d'oxydes mélangés de vanadium et de phosphore dopé au niobium |
US8658557B2 (en) * | 2011-10-25 | 2014-02-25 | Ineos Usa Llc | Catalyst for n-butane oxidation to maleic anhydride |
US9675966B2 (en) | 2015-07-16 | 2017-06-13 | Ineos Europe Ag | Catalyst for n-butane oxidation to maleic anhydride |
DE102019100983A1 (de) | 2019-01-16 | 2020-07-16 | Clariant International Ltd | Verfahren zur herstellung eines vpo-katalysators |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2162051A1 (fr) * | 1971-12-01 | 1973-07-13 | Basf Ag | |
FR2189493A1 (fr) * | 1972-06-19 | 1974-01-25 | Chevron Res | |
FR2286825A1 (fr) * | 1973-02-07 | 1976-04-30 | Monsanto Co | Procede de preparation de catalyseurs a base de phosphore-vanadium-oxygene et nouveaux produits ainsi obtenus pour la preparation d'anhydride maleique |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1425301A (fr) * | 1964-09-15 | 1966-01-24 | Aquitaine Petrole | Catalyseur perfectionné pour l'oxydation d'hydrocarbures |
FR1470581A (fr) * | 1965-03-05 | 1967-02-24 | Basf Ag | Catalyseur pour la préparation de l'anhydride maléique |
CA990305A (en) * | 1970-08-26 | 1976-06-01 | The Standard Oil Company | Manufacture of maleic anhydride from butane |
DD106631A1 (fr) * | 1971-12-06 | 1974-06-20 | ||
US3888886A (en) * | 1972-06-08 | 1975-06-10 | Mobil Oil Corp | Oxidation of alkanes to maleic anhydride using promoted vanadium-phosphorus catalyst |
US3864280A (en) * | 1972-06-19 | 1975-02-04 | Chevron Res | Catalyst for a n-butane oxidation to maleic anhydride |
US3875220A (en) * | 1973-10-11 | 1975-04-01 | Standard Oil Co Ohio | Process for the preparation of methacrylic acid from methacrolein |
US4070379A (en) * | 1973-11-23 | 1978-01-24 | Produits Chimiques Ugine Kuhlmann | Process for the manufacture of maleic anhydride |
GB1496331A (en) * | 1975-09-08 | 1977-12-30 | Bp Chem Int Ltd | Catalyst composition |
US4045478A (en) * | 1975-02-28 | 1977-08-30 | Ube Industries, Ltd. | Method for the preparation of methacrylic acid |
US4052417A (en) * | 1975-11-06 | 1977-10-04 | Celanese Corporation | Vapor phase oxidation of butane producing maleic anhydride and acetic acid |
-
1976
- 1976-11-11 GB GB46966/76A patent/GB1591307A/en not_active Expired
-
1977
- 1977-11-04 ZA ZA00776580A patent/ZA776580B/xx unknown
- 1977-11-04 US US05/848,719 patent/US4147661A/en not_active Expired - Lifetime
- 1977-11-04 BE BE182372A patent/BE860512A/fr not_active IP Right Cessation
- 1977-11-10 FR FR7733942A patent/FR2370514A1/fr active Granted
- 1977-11-10 DE DE19772750327 patent/DE2750327A1/de active Granted
- 1977-11-10 IT IT29557/77A patent/IT1089056B/it active
- 1977-11-11 JP JP13558077A patent/JPS5361588A/ja active Granted
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2162051A1 (fr) * | 1971-12-01 | 1973-07-13 | Basf Ag | |
FR2189493A1 (fr) * | 1972-06-19 | 1974-01-25 | Chevron Res | |
FR2286825A1 (fr) * | 1973-02-07 | 1976-04-30 | Monsanto Co | Procede de preparation de catalyseurs a base de phosphore-vanadium-oxygene et nouveaux produits ainsi obtenus pour la preparation d'anhydride maleique |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0056528A2 (fr) * | 1981-01-02 | 1982-07-28 | Monsanto Company | Intermédiaire de catalyseur, catalyseur préparé avec celui-ci et méthode de préparation de l'anhydride maléique |
EP0056528A3 (fr) * | 1981-01-02 | 1983-01-05 | Monsanto Company | Intermédiaire de catalyseur, catalyseur préparé avec celui-ci et méthode de préparation de l'anhydride maléique |
Also Published As
Publication number | Publication date |
---|---|
IT1089056B (it) | 1985-06-10 |
US4147661A (en) | 1979-04-03 |
DE2750327C2 (fr) | 1989-07-27 |
FR2370514B1 (fr) | 1984-02-10 |
DE2750327A1 (de) | 1978-05-18 |
ZA776580B (en) | 1979-06-27 |
JPS6125420B2 (fr) | 1986-06-16 |
BE860512A (fr) | 1978-05-05 |
JPS5361588A (en) | 1978-06-02 |
GB1591307A (en) | 1981-06-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |