KR840004128A - 모노알릴아민 폴리머 생산을 위한 공정 - Google Patents

모노알릴아민 폴리머 생산을 위한 공정 Download PDF

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KR840004128A
KR840004128A KR1019830001269A KR830001269A KR840004128A KR 840004128 A KR840004128 A KR 840004128A KR 1019830001269 A KR1019830001269 A KR 1019830001269A KR 830001269 A KR830001269 A KR 830001269A KR 840004128 A KR840004128 A KR 840004128A
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group
nitrogen atom
azo
monoallylamine
inorganic acid
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KR1019830001269A
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KR890002931B1 (ko
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스스무 하라다
Original Assignee
가스가 게사지
닛또보오세끼가부시끼가이샤
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F22/02—Acids; Metal salts or ammonium salts thereof, e.g. maleic acid or itaconic acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F26/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F26/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a single or double bond to nitrogen

Abstract

내용 없음

Description

모노알릴아민 폴리머 생산을 위한 공정
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 폴리머의 양성자 핵자기 공명 스펙트럼을 나타낸다.

Claims (5)

  1. 그의 분자에 아조기 및 양이온성 질소원자를 갖는 기를 가진 라디칼 개시제의 존재하, 극성 용매 내에서 모노알릴아민의 무기산 염을 중합하는 것을 포함하는 모노알릴아민 폴리머의 제조공정.
  2. 제1항에 있어서, 상기 모노알릴아민의 무기산 염이 모노알릴아민의 염화수소, 황산염 또는 인산염인 공정.
  3. 제1항에 있어서, 상기 극성용매가 물, 무기산, 무기산수용액, 무기산 금속염의 수용액, 유기산, 유기산의 수용액 및 극성 유기 용매로 구성된 군으로부터 선택되는 공정.
  4. 제1항에 있어서, 그의 분자에 아조기 및 양이온성 질소원자를 가진 라디칼 개시제가 하기 일반식(Ⅰ)에 의해 표시된 아조 화합물의 무기 및 유기산 염인 공정.
    R1-N=N-R2(Ⅰ)
    여기서 하나 이상이, 바람직하기는 R1및 R2모두, 아미노알킬, 아미노아릴, 아미디닐알킬, 아미디닐아릴, 아미노알크아릴, 아미노아르알킬, 아미디닐 아르알킬, 아미디닐알킬아릴, 시아노아미노알킬 및 시아노 아미노알크아릴로 구성된 기중 선택된 양이온성 질소원자를 갖는 기이다. R1및 R2중 어느 하나만이 상기 양이온성 질소원자를 갖느 족일때, 다른 하나는 알킬, 아릴, 알크아릴, 시아노알킬, 시아노아릴, 시아노알크아릴 및 시아노아르알킬이다. 임의로 R1및 R2가 함께 선택되면, 하기 일반식(Ⅱ)에 의해 표시되는 단일 알킬렌기 이어도 좋다.
    (Ⅱ)
    (여기서 R은 알킬렌, 알킬알킬렌 및 아르알킬렌이고, 공유결합(a) 및 (b)는 각각 아조기의 질소원자와 연결되어 아조기 포함 고리를 형상하며, X는 양이온성 질소원자를 갖는 기이다)
  5. 제4항에 있어서, 상기 일반식(Ⅰ)에 나타낸 라디칼 개시제가 아조기에 인접한 2급 및 3급 탄소를가진 화합물인 공정.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019830001269A 1982-05-19 1983-03-29 모노알린아민 폴리머 제조방법 KR890002931B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US379,983 1982-05-19
US06/379,983 US4504640A (en) 1982-05-19 1982-05-19 Process for producing monoallylamine polymer
US379.983 1982-05-19

Publications (2)

Publication Number Publication Date
KR840004128A true KR840004128A (ko) 1984-10-06
KR890002931B1 KR890002931B1 (ko) 1989-08-12

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KR1019830001269A KR890002931B1 (ko) 1982-05-19 1983-03-29 모노알린아민 폴리머 제조방법

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US (1) US4504640A (ko)
EP (1) EP0095233B1 (ko)
JP (1) JPS58201811A (ko)
KR (1) KR890002931B1 (ko)
AU (1) AU539800B2 (ko)
CA (1) CA1233945A (ko)
DE (1) DE3363895D1 (ko)

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Publication number Publication date
EP0095233B1 (en) 1986-06-04
EP0095233A3 (en) 1984-03-21
EP0095233A2 (en) 1983-11-30
JPS58201811A (ja) 1983-11-24
CA1233945A (en) 1988-03-08
AU1292983A (en) 1983-11-24
KR890002931B1 (ko) 1989-08-12
JPH0214364B2 (ko) 1990-04-06
US4504640A (en) 1985-03-12
AU539800B2 (en) 1984-10-18
DE3363895D1 (en) 1986-07-10

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