KR20250016446A - 시클로올레핀의 제조 방법 - Google Patents

시클로올레핀의 제조 방법 Download PDF

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Publication number
KR20250016446A
KR20250016446A KR1020257000049A KR20257000049A KR20250016446A KR 20250016446 A KR20250016446 A KR 20250016446A KR 1020257000049 A KR1020257000049 A KR 1020257000049A KR 20257000049 A KR20257000049 A KR 20257000049A KR 20250016446 A KR20250016446 A KR 20250016446A
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KR
South Korea
Prior art keywords
catalyst
zinc sulfate
reaction
aqueous solution
concentration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
KR1020257000049A
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English (en)
Korean (ko)
Inventor
아키요시 후쿠자와
사토미 이시하라
다카유키 시미즈
게이타 아시다
야스노부 나가노
Original Assignee
아사히 가세이 가부시키가이샤
아사히 가세이 가부시키가이샤
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Application filed by 아사히 가세이 가부시키가이샤, 아사히 가세이 가부시키가이샤 filed Critical 아사히 가세이 가부시키가이샤
Publication of KR20250016446A publication Critical patent/KR20250016446A/ko
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • C07C5/11—Partial hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/60—Platinum group metals with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/02—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/16—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with a six-membered ring
    • C07C13/20—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with a six-membered ring with a cyclohexene ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/10—Purification; Separation; Use of additives by extraction, i.e. purification or separation of liquid hydrocarbons with the aid of liquids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/56—Platinum group metals
    • C07C2523/60—Platinum group metals with zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020257000049A 2022-08-05 2023-07-26 시클로올레핀의 제조 방법 Pending KR20250016446A (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JPJP-P-2022-125754 2022-08-05
JPJP-P-2022-125785 2022-08-05
JP2022125754 2022-08-05
JP2022125785 2022-08-05
PCT/JP2023/027336 WO2024029418A1 (ja) 2022-08-05 2023-07-26 シクロオレフィンの製造方法

Publications (1)

Publication Number Publication Date
KR20250016446A true KR20250016446A (ko) 2025-02-03

Family

ID=89848986

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020257000049A Pending KR20250016446A (ko) 2022-08-05 2023-07-26 시클로올레핀의 제조 방법

Country Status (5)

Country Link
EP (1) EP4567017A1 (https=)
JP (1) JP7770575B2 (https=)
KR (1) KR20250016446A (https=)
CN (1) CN119654303A (https=)
WO (1) WO2024029418A1 (https=)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5147053B1 (https=) 1971-03-11 1976-12-13
JPS5254338U (https=) 1975-10-15 1977-04-19
JPH02115581A (ja) 1988-10-26 1990-04-27 Matsushita Electric Works Ltd 携帯用電動コンプレッサ
JPH02138012A (ja) 1988-11-16 1990-05-28 Daifuku Co Ltd 被搬送物移載システム
JP3125913U (ja) 2006-07-26 2006-10-05 八京實業股▲ふん▼有限公司 ドアや窓の取手ロックの構造

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6021126B2 (ja) * 1976-11-17 1985-05-25 東レ株式会社 シクロヘキセン類の製造法
JPS5929172B2 (ja) * 1980-04-15 1984-07-18 東レ株式会社 芳香族炭化水素の還元的付加反応法
JPS59186932A (ja) * 1983-04-06 1984-10-23 Asahi Chem Ind Co Ltd シクロオレフインを製造する方法
JPH07106991B2 (ja) * 1986-07-14 1995-11-15 旭化成工業株式会社 部分水素化方法
JP2634828B2 (ja) 1987-12-16 1997-07-30 旭化成工業株式会社 芳香族化合物の部分核水素化方法
JP2886563B2 (ja) 1989-08-07 1999-04-26 旭化成工業株式会社 ルテニウム触媒の活性回復方法
JPH04312537A (ja) * 1991-04-11 1992-11-04 Sagami Chem Res Center 環状オレフィンの製造方法
JP2892233B2 (ja) 1992-10-15 1999-05-17 旭化成工業株式会社 単環芳香族炭化水素の部分水素化方法
JPH07267882A (ja) * 1994-03-29 1995-10-17 Cosmo Sogo Kenkyusho:Kk シクロオレフィンの製造方法
JP3125913B2 (ja) 1995-06-01 2001-01-22 三菱化学株式会社 シクロオレフィンの製造方法
WO1997016249A1 (fr) 1995-11-01 1997-05-09 Asahi Kasei Kogyo Kabushiki Kaisha Procede de reactivation d'un catalyseur a base de ruthenium
JP4025407B2 (ja) 1997-04-02 2007-12-19 旭化成ケミカルズ株式会社 シクロオレフィンの製造方法
JPH11228457A (ja) * 1998-02-17 1999-08-24 Mitsubishi Chemical Corp シクロオレフィンの製造方法
JP4033980B2 (ja) 1998-09-09 2008-01-16 旭化成ケミカルズ株式会社 シクロオレフィンの製造方法
JP4397468B2 (ja) 1999-07-13 2010-01-13 旭化成ケミカルズ株式会社 シクロオレフィンの製造方法
JP4777891B2 (ja) 2004-07-09 2011-09-21 旭化成ケミカルズ株式会社 シクロオレフィン製造用触媒及び製造方法
US7947859B2 (en) 2005-08-26 2011-05-24 Asahi Kasei Chemicals Corporation Process for production of cycloolefin
JP5254338B2 (ja) 2008-07-30 2013-08-07 旭化成ケミカルズ株式会社 シクロオレフィンの製造方法及び製造装置
CN102264471A (zh) * 2008-12-22 2011-11-30 旭化成化学株式会社 环烯烃制造用钌催化剂的制备方法、环烯烃的制造方法以及制造装置
ITMI20121724A1 (it) * 2012-10-12 2014-04-13 Versalis Spa Catalizzatore a base di rutenio e suo impiego nell'idrogenazione selettiva di composti aromatici o poliinsaturi
CN105056971A (zh) 2015-08-07 2015-11-18 郑州大学 一种苯选择加氢制环己烯用Ru-Zn催化剂的原位再生方法
CN105130734B (zh) * 2015-08-07 2017-05-24 郑州大学 一种苯选择加氢制环己烯用Ru‑Zn催化剂的活性选择性的调变方法
JP7694056B2 (ja) 2021-02-17 2025-06-18 積水ハウス株式会社 設計支援システムおよび設計支援プログラム
JP2022125785A (ja) 2021-02-17 2022-08-29 日立建機株式会社 ホイールローダ

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5147053B1 (https=) 1971-03-11 1976-12-13
JPS5254338U (https=) 1975-10-15 1977-04-19
JPH02115581A (ja) 1988-10-26 1990-04-27 Matsushita Electric Works Ltd 携帯用電動コンプレッサ
JPH02138012A (ja) 1988-11-16 1990-05-28 Daifuku Co Ltd 被搬送物移載システム
JP3125913U (ja) 2006-07-26 2006-10-05 八京實業股▲ふん▼有限公司 ドアや窓の取手ロックの構造

Also Published As

Publication number Publication date
EP4567017A1 (en) 2025-06-11
JPWO2024029418A1 (https=) 2024-02-08
WO2024029418A1 (ja) 2024-02-08
JP7770575B2 (ja) 2025-11-14
CN119654303A (zh) 2025-03-18

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PA0105 International application

Patent event date: 20250102

Patent event code: PA01051R01D

Comment text: International Patent Application

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