KR20130094790A - 열가소성 조성물, 그의 제조 방법 및 그로부터 제조된 물품 - Google Patents
열가소성 조성물, 그의 제조 방법 및 그로부터 제조된 물품 Download PDFInfo
- Publication number
- KR20130094790A KR20130094790A KR1020137003224A KR20137003224A KR20130094790A KR 20130094790 A KR20130094790 A KR 20130094790A KR 1020137003224 A KR1020137003224 A KR 1020137003224A KR 20137003224 A KR20137003224 A KR 20137003224A KR 20130094790 A KR20130094790 A KR 20130094790A
- Authority
- KR
- South Korea
- Prior art keywords
- thermoplastic
- acrylate
- thermoplastic composition
- core
- shell
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 186
- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 147
- 239000000203 mixture Substances 0.000 title claims abstract description 132
- 238000000034 method Methods 0.000 title claims abstract description 61
- 239000002245 particle Substances 0.000 claims abstract description 72
- 229920000642 polymer Polymers 0.000 claims abstract description 58
- 239000000178 monomer Substances 0.000 claims description 34
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 28
- 238000004519 manufacturing process Methods 0.000 claims description 27
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 26
- -1 polyoxymethylene Polymers 0.000 claims description 26
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 24
- 230000009477 glass transition Effects 0.000 claims description 23
- 238000004132 cross linking Methods 0.000 claims description 21
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 19
- 238000000465 moulding Methods 0.000 claims description 15
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 claims description 14
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 13
- GCTPMLUUWLLESL-UHFFFAOYSA-N benzyl prop-2-enoate Chemical compound C=CC(=O)OCC1=CC=CC=C1 GCTPMLUUWLLESL-UHFFFAOYSA-N 0.000 claims description 13
- 229920001577 copolymer Polymers 0.000 claims description 13
- 238000002844 melting Methods 0.000 claims description 13
- 230000008018 melting Effects 0.000 claims description 13
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 claims description 13
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims description 12
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 12
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 12
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims description 12
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 12
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical group CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 12
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 12
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 claims description 12
- KCAMXZBMXVIIQN-UHFFFAOYSA-N octan-3-yl 2-methylprop-2-enoate Chemical compound CCCCCC(CC)OC(=O)C(C)=C KCAMXZBMXVIIQN-UHFFFAOYSA-N 0.000 claims description 12
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 12
- 239000004743 Polypropylene Substances 0.000 claims description 11
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 10
- 125000000524 functional group Chemical group 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 9
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 9
- 229920006324 polyoxymethylene Polymers 0.000 claims description 9
- 239000004734 Polyphenylene sulfide Substances 0.000 claims description 8
- 229920000069 polyphenylene sulfide Polymers 0.000 claims description 8
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 6
- 229930040373 Paraformaldehyde Natural products 0.000 claims description 6
- 239000005062 Polybutadiene Substances 0.000 claims description 6
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical group C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 6
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 6
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 6
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 6
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 6
- 229920002857 polybutadiene Polymers 0.000 claims description 6
- 239000004417 polycarbonate Substances 0.000 claims description 6
- 229920006380 polyphenylene oxide Polymers 0.000 claims description 6
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical group OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 claims description 5
- 239000004952 Polyamide Substances 0.000 claims description 5
- 150000008064 anhydrides Chemical group 0.000 claims description 5
- 238000004898 kneading Methods 0.000 claims description 5
- 229920002647 polyamide Polymers 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 4
- 229920000515 polycarbonate Polymers 0.000 claims description 4
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 claims description 4
- IKYAJDOSWUATPI-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propane-1-thiol Chemical compound CO[Si](C)(OC)CCCS IKYAJDOSWUATPI-UHFFFAOYSA-N 0.000 claims description 3
- 239000004696 Poly ether ether ketone Substances 0.000 claims description 3
- 229930182556 Polyacetal Natural products 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 125000003368 amide group Chemical group 0.000 claims description 3
- JUPQTSLXMOCDHR-UHFFFAOYSA-N benzene-1,4-diol;bis(4-fluorophenyl)methanone Chemical compound OC1=CC=C(O)C=C1.C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 JUPQTSLXMOCDHR-UHFFFAOYSA-N 0.000 claims description 3
- AOJOEFVRHOZDFN-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CC=C1 AOJOEFVRHOZDFN-UHFFFAOYSA-N 0.000 claims description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
- WQTNGCZMPUCIEX-UHFFFAOYSA-N dimethoxy-methyl-prop-2-enylsilane Chemical compound CO[Si](C)(OC)CC=C WQTNGCZMPUCIEX-UHFFFAOYSA-N 0.000 claims description 3
- 125000003700 epoxy group Chemical group 0.000 claims description 3
- ZLNAFSPCNATQPQ-UHFFFAOYSA-N ethenyl-dimethoxy-methylsilane Chemical group CO[Si](C)(OC)C=C ZLNAFSPCNATQPQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004811 fluoropolymer Substances 0.000 claims description 3
- 229920002313 fluoropolymer Polymers 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 229920001643 poly(ether ketone) Polymers 0.000 claims description 3
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 3
- 229920002492 poly(sulfone) Polymers 0.000 claims description 3
- 229920001230 polyarylate Polymers 0.000 claims description 3
- 229920006260 polyaryletherketone Polymers 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 229920002530 polyetherether ketone Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 239000004626 polylactic acid Substances 0.000 claims description 3
- 229920000193 polymethacrylate Polymers 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- 229920006259 thermoplastic polyimide Polymers 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 2
- VKEQBMCRQDSRET-UHFFFAOYSA-N Methylone Chemical compound CNC(C)C(=O)C1=CC=C2OCOC2=C1 VKEQBMCRQDSRET-UHFFFAOYSA-N 0.000 claims description 2
- 150000001408 amides Chemical class 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 239000004816 latex Substances 0.000 claims 1
- 229920000126 latex Polymers 0.000 claims 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 7
- 229920001971 elastomer Polymers 0.000 description 15
- 238000007906 compression Methods 0.000 description 10
- 230000006835 compression Effects 0.000 description 10
- 238000009472 formulation Methods 0.000 description 8
- 239000000155 melt Substances 0.000 description 8
- 239000005060 rubber Substances 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- 239000003963 antioxidant agent Substances 0.000 description 6
- 238000001125 extrusion Methods 0.000 description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 5
- 241000612182 Rexea solandri Species 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 238000001746 injection moulding Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- 229920002292 Nylon 6 Polymers 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 238000000071 blow moulding Methods 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229920002943 EPDM rubber Polymers 0.000 description 3
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 239000011258 core-shell material Substances 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- 238000001175 rotational moulding Methods 0.000 description 3
- 229920006342 thermoplastic vulcanizate Polymers 0.000 description 3
- HSOOIVBINKDISP-UHFFFAOYSA-N 1-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(CCC)OC(=O)C(C)=C HSOOIVBINKDISP-UHFFFAOYSA-N 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000010102 injection blow moulding Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000010420 shell particle Substances 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- HGDULKQRXBSKHL-UHFFFAOYSA-N 1,1-bis(2-methylprop-2-enoyloxy)propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(CC)(OC(=O)C(C)=C)OC(=O)C(C)=C HGDULKQRXBSKHL-UHFFFAOYSA-N 0.000 description 1
- LNZBSVNIMBHSAG-UHFFFAOYSA-N 1-(1,3-benzodioxol-5-yl)-2-(methylamino)hexan-1-one Chemical compound CCCCC(NC)C(=O)c1ccc2OCOc2c1 LNZBSVNIMBHSAG-UHFFFAOYSA-N 0.000 description 1
- WPMYUUITDBHVQZ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- 229920003692 Grilamid® L Polymers 0.000 description 1
- 229920006060 Grivory® Polymers 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- 229920004142 LEXAN™ Polymers 0.000 description 1
- 239000004418 Lexan Substances 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 229920006097 Ultramide® Polymers 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229920000891 common polymer Polymers 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000007771 core particle Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 238000010101 extrusion blow moulding Methods 0.000 description 1
- 210000003195 fascia Anatomy 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 229920005555 halobutyl Polymers 0.000 description 1
- 125000004968 halobutyl group Chemical group 0.000 description 1
- 238000007542 hardness measurement Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000001841 imino group Chemical group [H]N=* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000010103 injection stretch blow moulding Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000005641 methacryl group Chemical group 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US36235210P | 2010-07-08 | 2010-07-08 | |
| US61/362,352 | 2010-07-08 | ||
| PCT/US2011/042987 WO2012006297A1 (en) | 2010-07-08 | 2011-07-06 | Thermoplastic composition, method of producing the same, and articles made therefrom |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20130094790A true KR20130094790A (ko) | 2013-08-26 |
Family
ID=44504176
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020137003224A Ceased KR20130094790A (ko) | 2010-07-08 | 2011-07-06 | 열가소성 조성물, 그의 제조 방법 및 그로부터 제조된 물품 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8779051B2 (https=) |
| EP (1) | EP2591054B1 (https=) |
| JP (1) | JP2013531115A (https=) |
| KR (1) | KR20130094790A (https=) |
| CN (1) | CN103097457A (https=) |
| BR (1) | BR112013000373A2 (https=) |
| TW (1) | TWI504434B (https=) |
| WO (1) | WO2012006297A1 (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20200070655A (ko) * | 2018-12-10 | 2020-06-18 | 엘지엠엠에이 주식회사 | 생분해성 필름 조성물 |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI445755B (zh) * | 2012-06-27 | 2014-07-21 | Ind Tech Res Inst | 阻燃性熱可塑性澱粉材料、生質複材及其製備方法 |
| EP2945994B1 (en) | 2013-01-18 | 2018-07-11 | Basf Se | Acrylic dispersion-based coating compositions |
| CN103146164B (zh) * | 2013-04-07 | 2016-03-30 | 苏州聚复高分子材料有限公司 | 用于快速成型的纳米增韧聚乳酸材料及其制备方法 |
| TWI542605B (zh) * | 2013-08-02 | 2016-07-21 | Lg化學股份有限公司 | 樹脂 |
| CN104086967B (zh) * | 2014-06-27 | 2016-06-22 | 张雨生 | 一种塑料制品材料 |
| JP6443659B2 (ja) * | 2014-09-25 | 2018-12-26 | 日油株式会社 | 熱可塑性エラストマー |
| JP6443660B2 (ja) * | 2014-09-25 | 2018-12-26 | 日油株式会社 | 熱可塑性エラストマー |
| TWI667279B (zh) | 2014-10-21 | 2019-08-01 | 美商羅門哈斯公司 | 聚合物之摻合物、其所製造之膜或片、由膜或片或管所製造之物品及製備膜或片之方法 |
| US10253123B2 (en) | 2014-12-17 | 2019-04-09 | Rohm And Haas Company | Impact modifier, a process to produce the same and a polymer composition comprising the same |
| US10414863B2 (en) * | 2014-12-18 | 2019-09-17 | Victrex Manufacturing Limited | Polymeric materials |
| WO2016106055A1 (en) | 2014-12-22 | 2016-06-30 | Rohm And Haas Company | An impact modifier and a polymer composition comprising the same |
| CN104987651A (zh) * | 2015-06-30 | 2015-10-21 | 苏州博利迈新材料科技有限公司 | 一种汽车保险杠用聚甲醛塑料粒子的制备方法 |
| JP2017095577A (ja) * | 2015-11-24 | 2017-06-01 | 株式会社リコー | 活性エネルギー線硬化型組成物、活性エネルギー線硬化型インク、組成物収容容器、像の形成方法及び形成装置、2次元又は3次元の像、並びに成形加工品 |
| MX2017015856A (es) | 2015-12-11 | 2018-11-09 | Ticona Llc | Composicion reticulable de sulfuro de poliarileno. |
| JP6896731B2 (ja) | 2015-12-11 | 2021-06-30 | ティコナ・エルエルシー | ポリアリーレンスルフィド組成物 |
| WO2017161534A1 (en) | 2016-03-24 | 2017-09-28 | Ticona Llc | Composite structure |
| JP2017200760A (ja) * | 2016-05-02 | 2017-11-09 | ダウ グローバル テクノロジーズ エルエルシー | 弾性下層を有するサーマル印刷可能な紙物品 |
| KR102006725B1 (ko) * | 2016-06-14 | 2019-08-02 | 주식회사 엘지화학 | 아크릴계 가공조제 및 이를 포함하는 염화비닐계 수지 조성물 |
| US10450491B2 (en) | 2016-08-08 | 2019-10-22 | Ticona Llc | Thermally conductive polymer composition for a heat sink |
| US11667781B2 (en) * | 2017-06-20 | 2023-06-06 | Dow Global Technologies, Llc | Polyvinyl chloride compositions containing impact modifiers and calcium carbonate |
| CN111032699B (zh) * | 2017-07-21 | 2022-08-02 | 罗门哈斯公司 | 聚(甲基丙烯酸甲酯)树脂组合物 |
| CN108794958B (zh) * | 2018-06-20 | 2020-04-14 | 新泰华(惠州)制鞋科技有限公司 | 一种舒适鞋子中底及女鞋 |
| CN109111706B (zh) * | 2018-07-09 | 2020-11-03 | 福建师范大学 | 一种功能化皮芯结构的3d打印线材的制备方法 |
| KR102854410B1 (ko) * | 2019-11-19 | 2025-09-05 | 디아이씨 가부시끼가이샤 | 2축 연신 적층 필름, 적층체 및 그들의 제조 방법 |
| CN113583396B (zh) * | 2021-07-07 | 2022-08-19 | 金发科技股份有限公司 | 一种耐循环注塑的pbt组合物及其制备方法和制品 |
| WO2024003637A1 (en) * | 2022-06-29 | 2024-01-04 | 3M Innovative Properties Company | Curable adhesive and articles for bonding pavement and concrete |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3796771A (en) * | 1970-09-10 | 1974-03-12 | Rohm & Haas | Acrylic modifiers for polycarbonamides |
| US4306040A (en) * | 1980-11-03 | 1981-12-15 | Monsanto Company | Multiphase core//shell polymers |
| US4584344A (en) * | 1980-11-03 | 1986-04-22 | Monsanto Company | Tough thermoplastic nylon compositions |
| JPS6036561A (ja) * | 1983-07-09 | 1985-02-25 | バイエル・アクチエンゲゼルシヤフト | 熱可塑性成形組成物 |
| DE3339000A1 (de) * | 1983-07-09 | 1985-01-17 | Bayer Ag, 5090 Leverkusen | Thermoplastische polyamid-formmassen mit hoher zaehigkeit |
| US4495324A (en) * | 1983-10-24 | 1985-01-22 | Allied Corporation | Glass reinforced polyamide composition containing acrylic core/shell polymer |
| CA1332992C (en) * | 1986-08-27 | 1994-11-08 | Susan Marie Liwak | Impact-strength modifiers for thermoplastic polymers |
| JPH04312238A (ja) * | 1991-04-10 | 1992-11-04 | Hitachi Chem Co Ltd | 制振性樹脂組成物およびこれを用いた制振性積層体 |
| JPH051200A (ja) * | 1991-04-19 | 1993-01-08 | Hitachi Chem Co Ltd | 熱可塑性エラストマー組成物及び成形品 |
| TW199902B (https=) * | 1991-07-25 | 1993-02-11 | Rohm & Haas | |
| JPH11292940A (ja) * | 1998-04-10 | 1999-10-26 | Kuraray Co Ltd | 多層構造重合体粒子並びにその製造方法及び用途 |
| JP2000186204A (ja) * | 1998-12-22 | 2000-07-04 | Kuraray Co Ltd | ポリアミド樹脂組成物 |
| US7195820B2 (en) * | 2003-12-09 | 2007-03-27 | Arkema Inc. | Core-shell polymers having hydrophilic shells for improved shell coverage and anti-blocking properties |
| JP4619902B2 (ja) * | 2005-08-30 | 2011-01-26 | 株式会社クラレ | 二次加工用光学物品及びその二次加工光学物品 |
| CN101501134B (zh) * | 2006-09-13 | 2012-02-22 | 胜技高分子株式会社 | 激光熔敷用树脂组合物及成型品 |
| US7807751B2 (en) * | 2008-02-25 | 2010-10-05 | Sabic Innovative Plastics Ip B.V. | Core-shell particle, method, and composition |
| JP5352201B2 (ja) | 2008-11-17 | 2013-11-27 | 三菱エンジニアリングプラスチックス株式会社 | 難燃性ポリアミド樹脂組成物及びこれを用いた成形品 |
| JP5724181B2 (ja) * | 2010-01-21 | 2015-05-27 | 株式会社カネカ | 熱可塑性エラストマー組成物 |
-
2011
- 2011-07-06 CN CN2011800433214A patent/CN103097457A/zh active Pending
- 2011-07-06 WO PCT/US2011/042987 patent/WO2012006297A1/en not_active Ceased
- 2011-07-06 US US13/808,951 patent/US8779051B2/en active Active
- 2011-07-06 KR KR1020137003224A patent/KR20130094790A/ko not_active Ceased
- 2011-07-06 JP JP2013518793A patent/JP2013531115A/ja active Pending
- 2011-07-06 BR BR112013000373-1A patent/BR112013000373A2/pt not_active Application Discontinuation
- 2011-07-06 EP EP11743682.4A patent/EP2591054B1/en active Active
- 2011-07-07 TW TW100124028A patent/TWI504434B/zh not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20200070655A (ko) * | 2018-12-10 | 2020-06-18 | 엘지엠엠에이 주식회사 | 생분해성 필름 조성물 |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201210685A (en) | 2012-03-16 |
| US8779051B2 (en) | 2014-07-15 |
| EP2591054A1 (en) | 2013-05-15 |
| CN103097457A (zh) | 2013-05-08 |
| US20130116382A1 (en) | 2013-05-09 |
| JP2013531115A (ja) | 2013-08-01 |
| EP2591054B1 (en) | 2016-11-23 |
| WO2012006297A1 (en) | 2012-01-12 |
| TWI504434B (zh) | 2015-10-21 |
| BR112013000373A2 (pt) | 2021-03-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2591054B1 (en) | Thermoplastic composition, method of producing the same, and articles made therefrom | |
| EP1846503B1 (en) | Thermoplastic vulcanisate blend | |
| US7074857B2 (en) | Curable thermoplastic elastomeric blend, method of manufacture, and use thereof | |
| CN114106547B (zh) | 一种聚碳酸酯组合物及其制备方法和应用 | |
| JP4624111B2 (ja) | 改良されたゴムペレット化工程を用いた熱可塑性エラストマー組成物の製造方法 | |
| CA2605271C (en) | Thermoplastic elastomer blend, method of manufacture and use thereof | |
| JP2018044115A (ja) | 熱可塑性エラストマー組成物 | |
| US20060247380A1 (en) | Thermoplastic elastomer blend, method of manufacture and use thereof | |
| US8013067B2 (en) | Curable thermoplastic elastomeric blend, method of manufacture, and use thereof | |
| JP2018044113A (ja) | 熱可塑性エラストマー組成物 | |
| US20070185265A1 (en) | Impact-modified blends | |
| EP1406937B1 (en) | Heat and oil resistant thermoplastic elastomer | |
| US6710131B2 (en) | Melt processible thermoplastic polyolefin blends for car bumpers and other articles and a process for the preparation thereof | |
| JP2018044114A (ja) | 熱可塑性エラストマー組成物 | |
| JP4798482B2 (ja) | 耐熱性ならびに耐薬品性に優れた熱可塑性エラストマー、その製造方法及びその用途 | |
| KR100700685B1 (ko) | 저광택 고충격 특성을 지니는 내열아크릴로니트릴-부타디엔-스티렌 수지 조성물 | |
| CN114854191B (zh) | 热塑性弹性体材料及其制备方法和应用 | |
| JP4127090B2 (ja) | 熱可塑性エラストマー組成物およびその製造方法 | |
| JP3066220B2 (ja) | シリコーンゴム組成物 | |
| JPH0873725A (ja) | ポリカーボネート樹脂組成物 | |
| KR20020039294A (ko) | 열가소성 폴리우레탄과 나일론 또는 글리콜 변형테레프탈레이트 공중합 수지의 혼련으로 이루어진열가소성 수지 조성물 | |
| CN119039775A (zh) | 一种尼龙复合材料及其制备方法与应用 | |
| JPH07138448A (ja) | 艶消し性に優れた熱可塑性樹脂組成物 | |
| KR20170089516A (ko) | 열안정성이 우수한 창호재용 수지 조성물 | |
| JPH0730237B2 (ja) | ノルボルネン系ポリマ−組成物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0105 | International application |
Patent event date: 20130207 Patent event code: PA01051R01D Comment text: International Patent Application |
|
| PG1501 | Laying open of application | ||
| A201 | Request for examination | ||
| PA0201 | Request for examination |
Patent event code: PA02012R01D Patent event date: 20160407 Comment text: Request for Examination of Application |
|
| E902 | Notification of reason for refusal | ||
| PE0902 | Notice of grounds for rejection |
Comment text: Notification of reason for refusal Patent event date: 20170316 Patent event code: PE09021S01D |
|
| E601 | Decision to refuse application | ||
| PE0601 | Decision on rejection of patent |
Patent event date: 20170726 Comment text: Decision to Refuse Application Patent event code: PE06012S01D Patent event date: 20170316 Comment text: Notification of reason for refusal Patent event code: PE06011S01I |