KR20000070759A - 규산나트륨을 함유하는 투명액체 세정제 - Google Patents
규산나트륨을 함유하는 투명액체 세정제 Download PDFInfo
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- KR20000070759A KR20000070759A KR1019997007018A KR19997007018A KR20000070759A KR 20000070759 A KR20000070759 A KR 20000070759A KR 1019997007018 A KR1019997007018 A KR 1019997007018A KR 19997007018 A KR19997007018 A KR 19997007018A KR 20000070759 A KR20000070759 A KR 20000070759A
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- South Korea
- Prior art keywords
- weight
- parts
- sodium silicate
- surfactant
- water
- Prior art date
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- 239000007788 liquid Substances 0.000 title claims abstract description 63
- 239000003599 detergent Substances 0.000 title claims abstract description 62
- 239000011734 sodium Substances 0.000 title description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 title description 4
- 229910052708 sodium Inorganic materials 0.000 title description 4
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 71
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 71
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 71
- -1 alkyl ether sulfate Chemical class 0.000 claims abstract description 53
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 23
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 21
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 21
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 21
- 239000002244 precipitate Substances 0.000 claims abstract description 9
- 150000008378 aryl ethers Chemical class 0.000 claims abstract description 4
- 239000004094 surface-active agent Substances 0.000 claims description 54
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 27
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 24
- 239000000194 fatty acid Substances 0.000 claims description 24
- 229930195729 fatty acid Natural products 0.000 claims description 24
- 150000004665 fatty acids Chemical class 0.000 claims description 23
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 17
- 229910052751 metal Inorganic materials 0.000 claims description 17
- 239000002184 metal Substances 0.000 claims description 17
- 239000002738 chelating agent Substances 0.000 claims description 15
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 14
- 239000011737 fluorine Substances 0.000 claims description 14
- 229910052731 fluorine Inorganic materials 0.000 claims description 14
- 235000011187 glycerol Nutrition 0.000 claims description 14
- 235000015165 citric acid Nutrition 0.000 claims description 12
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 11
- 125000003118 aryl group Chemical group 0.000 claims description 11
- 239000001630 malic acid Substances 0.000 claims description 11
- 235000011090 malic acid Nutrition 0.000 claims description 11
- 239000012190 activator Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 description 39
- 239000004744 fabric Substances 0.000 description 27
- 239000000203 mixture Substances 0.000 description 26
- 238000004140 cleaning Methods 0.000 description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
- 239000012459 cleaning agent Substances 0.000 description 11
- 238000003756 stirring Methods 0.000 description 11
- 238000005406 washing Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- 238000005187 foaming Methods 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 150000005215 alkyl ethers Chemical class 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 6
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 235000012239 silicon dioxide Nutrition 0.000 description 5
- 239000008399 tap water Substances 0.000 description 5
- 235000020679 tap water Nutrition 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 239000003925 fat Substances 0.000 description 4
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 4
- 238000004062 sedimentation Methods 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 235000019482 Palm oil Nutrition 0.000 description 2
- 241000282320 Panthera leo Species 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- GSPKZYJPUDYKPI-UHFFFAOYSA-N diethoxy sulfate Chemical compound CCOOS(=O)(=O)OOCC GSPKZYJPUDYKPI-UHFFFAOYSA-N 0.000 description 2
- 238000004851 dishwashing Methods 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000002540 palm oil Substances 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- SSTHBHCRNGPPAI-UHFFFAOYSA-N 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-n,n-bis(2-hydroxyethyl)octane-1-sulfonamide Chemical compound OCCN(CCO)S(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F SSTHBHCRNGPPAI-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 125000006539 C12 alkyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229930191764 Sparin Natural products 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- LLSDKQJKOVVTOJ-UHFFFAOYSA-L calcium chloride dihydrate Chemical compound O.O.[Cl-].[Cl-].[Ca+2] LLSDKQJKOVVTOJ-UHFFFAOYSA-L 0.000 description 1
- 229940052299 calcium chloride dihydrate Drugs 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000013066 combination product Substances 0.000 description 1
- 229940127555 combination product Drugs 0.000 description 1
- 239000002577 cryoprotective agent Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- ZJXZSIYSNXKHEA-UHFFFAOYSA-N ethyl dihydrogen phosphate Chemical compound CCOP(O)(O)=O ZJXZSIYSNXKHEA-UHFFFAOYSA-N 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052806 inorganic carbonate Inorganic materials 0.000 description 1
- 229910052909 inorganic silicate Inorganic materials 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 201000008383 nephritis Diseases 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- RRRXPPIDPYTNJG-UHFFFAOYSA-N perfluorooctanesulfonamide Chemical compound NS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F RRRXPPIDPYTNJG-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical group FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
성 분 | 세정제 (중량 %) | |||||
A | B | C | D | E | ||
규산나트륨수용액 | 20.0 | 25.0 | 30.0 | 35.0 | 40.0 | |
혼합계면활성제용액 | 78.0 | 73.0 | 68.0 | 63 | 58.0 | |
지방산알칸올아미드 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | |
세정제전체중의비율 | 에틸렌디아민테트라아세트산4나트륨염 | 1.2 | 1.5 | 1.8 | 2.1 | 2.4 |
DL- 말산 | 0.12 | 0.15 | 0.18 | 0.21 | 0.4 | |
시트르산 | - | - | - | - | - | |
2 호 규산나트륨 | 6.6 | 8.25 | 9.9 | 11.5 | 13.2 | |
3 호 규산나트륨 | - | - | - | - | - | |
글리세린 | 1.6 | 2.0 | 2.4 | 2.8 | 3.2 | |
폴리옥시에틸렌알킬에테르 계면활성제 | 12.48 | 11.68 | 10.88 | 10.08 | 9.28 | |
알킬에테르황산염계면활성제 | 21.84 | 20.44 | 19.04 | 17.64 | 16.24 | |
불소계 계면활성제 | - | - | - | - | - | |
지방산알칸올아미드 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | |
물(합계) | 54.16 | 53.98 | 53.80 | 53.62 | 53.44 | |
p H 값 | 11.54 | 11.61 | 11.67 | 11.72 | 12.07 | |
1000 배 희석 pH 값 | 7.65 | 7.75 | 8.33 | 8.36 | 8.50 |
성 분 | 세정제 (중량 %) | ||||
F | G | H | I | ||
규산나트륨수용액 | 15.0 | 20.0 | 25.0 | 30.0 | |
혼합계면활성제용액 | 83.0 | 78.0 | 73.0 | 68.0 | |
지방산알칸올아미드 | 2.0 | 2.0 | 2.0 | 2.0 | |
세정제전체중의비율 | 에틸렌디아민테트라아세트산4나트륨염 | 0.9 | 1.2 | 1.5 | 1.8 |
DL- 말산 | - | - | - | - | |
시트르산 | 0.09 | 0.12 | 0.15 | 0.18 | |
2 호 규산나트륨 | - | - | - | - | |
3 호 규산나트륨 | 4.95 | 6.6 | 8.25 | 9.9 | |
글리세린 | 1.2 | 1.6 | 2.0 | 2.4 | |
폴리옥시에틸렌알킬에테르 계면활성제 | 13.28 | 12.48 | 11.68 | 10.88 | |
알킬에테르황산염계면활성제 | 23.157 | 21.762 | 20.367 | 18.972 | |
불소계 계면활성제 | 0.083 | 0.078 | 0.073 | 0.068 | |
지방산알칸올아미드 | 2.0 | 2.0 | 2.0 | 2.0 | |
물(합계) | 54.34 | 54.16 | 53.98 | 53.80 | |
p H 값 | 11.57 | 11.68 | 11.74 | 11.81 | |
1000 배 희석 pH 값 | 7.36 | 7.75 | 7.88 | 8.42 |
평가항목 | 세 정 제 | ||||
A | B | C | D | E | |
투명성 | △ | O | O | O | O |
백탁감 | O | O | O | O | O |
안정성 | O | O | O | O | O |
점도(cP) | 235.5 | 215.0 | 220.0 | 190.0 | 165.0 |
평가항목 | 세 정 제 | |||
F | G | H | I | |
투명성 | O | O | O | O |
백탁감 | O | O | O | O |
안정성 | O | O | O | O |
점도(cP) | 240.0 | 225.0 | 210.0 | 160.0 |
옷깃 때받이 천N0. | 패널리스트1 | 패널리스트2 | 패널리스트3 |
123456789101112131415 | +2+1+2+1+1+2+2+2+1+1+2+1+2+2+2 | +2+1+2+1+1+2+2+2+1+1+2+2+2+2+2 | +2+1+2+1+1+2+2+2+2+1+2+2+2+1+2 |
계 | +24 | +25 | +25 |
옷깃 때받이 천N0. | 패널리스트1 | 패널리스트2 | 패널리스트3 |
123456789101112131415 | +2+2+1+2+2+1+2+1+2+2+1+2+2+2+2 | +2+2+2+2+2+2+1+2+1+2+2+2+2+1+2 | +2+2+2+2+2+2+1+2+1+2+2+2+2+1+2 |
계 | +26 | +27 | +27 |
옷깃 때받이 천N0. | 패널리스트1 | 패널리스트2 | 패널리스트3 |
123456789101112131415 | +2+2+2+2+2+2+2+2+2+2+2+2+1+2+2 | +2+2+2+2+2+2+2+2+2+2+2+2+2+2+2 | +2+2+2+2+2+2+2+2+2+2+2+2+2+2+2 |
계 | +29 | +30 | +30 |
옷깃 때받이 천N0. | 패널리스트1 | 패널리스트2 | 패널리스트3 |
123456789101112131415 | +2+2+2+2+2+2+2+2+2+2+2+2+2+2+2 | +2+2+2+2+2+2+2+2+2+2+2+2+2+2+2 | +2+2+2+2+2+2+2+2+2+2+2+2+2+2+2 |
계 | +30 | +30 | +30 |
Claims (7)
- 액체 규산나트륨, 알킬에테르 황산염계 음이온 계면활성제, 및 폴리옥시에틸렌알킬 또는 아릴에테르계 비이온 계면활성제를 수중에 함유하고, 석출물을 발생시키지 않으며, 온도변화에 의해 백탁되는 일이 없는 투명액체 세정제.
- 제 1 항에 있어서, 액체 규산나트륨을 4.5 내지 13.2 중량 % 의 비율로 함유하는 투명액체 세정제.
- 액체 규산나트륨, 금속 킬레이트제, 말산 또는 시트르산, 글리세린, 알킬에테르 황산염계 음이온 계면활성제, 폴리옥시 에틸렌알킬 또는 아릴계 비이온 계면활성제, 지방산알칸올아미드 및 물을 함유하고, 석출물을 발생시키지 않으며, 온도변화에 의해 백탁되는 일이 없는 투명액체 세정제.
- 제 3 항에 있어서, 액체 규산나트륨을 4.5 내지 13.2 중량 % 의 비율로 함유하는 투명액체 세정제.
- 제 3 항에 있어서, 불소계 계면활성제를 더 함유하는 투명액체 세정제.
- (a) 액체 규산나트륨 1 내지 40 중량부, 물 30 내지 85 중량부, 금속킬레이트제 5 내지 15 중량부, 말산 또는 시트르산 0.1 내지 3.0 중량부 및 글리세린 0.15 내지 15 중량부를 함유하는 규산나트륨 용액을 10 내지 35 중량 %의 비율로, (b) 알킬에테르 황산염계 음이온 계면활성제 5 내지 50 중량부, 폴리옥시에틸렌알킬 또는 아릴계 비이온 계면활성제 5 내지 30 중량부 및 물 20 내지 65 중량부를 함유하는 계면활성제 용액 또는 (c) 알킬에테르황산염계 음이온 계면활성제 5 내지 50 중량부, 폴리옥시에틸렌알킬 또는 아릴계 비이온 계면활성제 5 내지 30 중량부, 불소계 계면활성제 0.01 내지 0.1 중량부 및 물 20 내지 65 중량부를 함유하는 계면활성제 용액을 89.5 내지 59 중량 % 의 비율로, (d) 지방산 알칸올아미드를 0.5 내지 6 중량 % 의 비율로 함유하는 투명액체 세정제.
- 제 6 항에 있어서, 액체 규산나트륨을 4.5 내지 13.2 중량 % 의 비율로 함유하는 투명액체 세정제.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP34945997A JP3262523B2 (ja) | 1997-12-18 | 1997-12-18 | ケイ酸ナトリウムを含有する透明液体洗浄剤 |
JP9-349459 | 1997-12-18 |
Publications (2)
Publication Number | Publication Date |
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KR20000070759A true KR20000070759A (ko) | 2000-11-25 |
KR100352933B1 KR100352933B1 (ko) | 2002-09-16 |
Family
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Application Number | Title | Priority Date | Filing Date |
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KR1019997007018A KR100352933B1 (ko) | 1997-12-18 | 1998-12-17 | 규산나트륨을 함유하는 투명액체 세정제 |
Country Status (11)
Country | Link |
---|---|
US (1) | US6391842B1 (ko) |
EP (1) | EP0969081B1 (ko) |
JP (1) | JP3262523B2 (ko) |
KR (1) | KR100352933B1 (ko) |
CN (1) | CN1204239C (ko) |
AT (1) | ATE252630T1 (ko) |
CA (1) | CA2281784C (ko) |
DE (1) | DE69819137T2 (ko) |
ES (1) | ES2207018T3 (ko) |
TW (1) | TW482821B (ko) |
WO (1) | WO1999031210A1 (ko) |
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US9650299B2 (en) | 2013-06-28 | 2017-05-16 | Halliburton Energy Services, Inc. | Methods of using downhole compositions including an ion-sequestering compound |
CN106281773B (zh) * | 2016-08-15 | 2019-01-15 | 广州澳希亚实业有限公司 | 一种不添加聚合物流变改性剂的透明洗手液及其制备方法 |
KR101952912B1 (ko) * | 2017-05-30 | 2019-02-27 | 소원기 | 액체 세제 조성물 |
Family Cites Families (11)
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JPS5139249B2 (ko) | 1972-02-26 | 1976-10-27 | ||
JPS5858397B2 (ja) | 1975-12-29 | 1983-12-24 | ダスキンフランチヤイズ カブシキガイシヤ | エキタイセンジヨウザイソセイブツ |
JPS5948080B2 (ja) | 1980-07-04 | 1984-11-24 | 花王株式会社 | 液体クレンザ−組成物 |
GB8308263D0 (en) | 1983-03-25 | 1983-05-05 | Unilever Plc | Aqueous liquid detergent composition |
DE4216405A1 (de) | 1992-05-18 | 1993-11-25 | Henkel Kgaa | Pumpfähige alkalische Reinigerkonzentrate |
JPH083594A (ja) | 1994-06-18 | 1996-01-09 | Masahiro Mihashi | 洗滌剤 |
JP3655339B2 (ja) | 1995-02-16 | 2005-06-02 | ライオン株式会社 | 液体ビルダー組成物 |
JPH08283972A (ja) | 1995-04-13 | 1996-10-29 | Dai Ichi Kogyo Seiyaku Co Ltd | 水系洗浄液用添加剤及びこれを用いた金属の変色並びに溶出を抑制する方法 |
US5759980A (en) * | 1997-03-04 | 1998-06-02 | Blue Coral, Inc. | Car wash |
US5858951A (en) | 1997-05-05 | 1999-01-12 | Church & Dwight Co., Inc. | Clear, homogeneous and temperature-stable liquid laundry detergent product containing blend of anionic and nonionic surfactants |
US5863878A (en) * | 1997-08-05 | 1999-01-26 | Church & Dwight Co., Inc. | Clear, homogeneous and temperature-stable liquid laundry detergent product containing blend of anionic, nonionic and amphoteric surfactants |
-
1997
- 1997-12-18 JP JP34945997A patent/JP3262523B2/ja not_active Expired - Lifetime
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1998
- 1998-12-17 WO PCT/JP1998/005724 patent/WO1999031210A1/ja active IP Right Grant
- 1998-12-17 DE DE69819137T patent/DE69819137T2/de not_active Expired - Lifetime
- 1998-12-17 CN CNB988026082A patent/CN1204239C/zh not_active Expired - Fee Related
- 1998-12-17 US US09/367,738 patent/US6391842B1/en not_active Expired - Fee Related
- 1998-12-17 KR KR1019997007018A patent/KR100352933B1/ko not_active IP Right Cessation
- 1998-12-17 AT AT98961400T patent/ATE252630T1/de not_active IP Right Cessation
- 1998-12-17 TW TW087121087A patent/TW482821B/zh not_active IP Right Cessation
- 1998-12-17 ES ES98961400T patent/ES2207018T3/es not_active Expired - Lifetime
- 1998-12-17 EP EP98961400A patent/EP0969081B1/en not_active Expired - Lifetime
- 1998-12-17 CA CA002281784A patent/CA2281784C/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
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EP0969081B1 (en) | 2003-10-22 |
JPH11181473A (ja) | 1999-07-06 |
KR100352933B1 (ko) | 2002-09-16 |
JP3262523B2 (ja) | 2002-03-04 |
WO1999031210A1 (fr) | 1999-06-24 |
CN1248284A (zh) | 2000-03-22 |
DE69819137T2 (de) | 2004-06-03 |
TW482821B (en) | 2002-04-11 |
ES2207018T3 (es) | 2004-05-16 |
DE69819137D1 (de) | 2003-11-27 |
EP0969081A1 (en) | 2000-01-05 |
US6391842B1 (en) | 2002-05-21 |
EP0969081A4 (en) | 2001-02-28 |
CA2281784A1 (en) | 1999-06-24 |
ATE252630T1 (de) | 2003-11-15 |
CN1204239C (zh) | 2005-06-01 |
CA2281784C (en) | 2006-01-17 |
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