KR102397588B1 - 고체 입자상 비닐 방향족 폴리머 조성물의 제조 방법 - Google Patents
고체 입자상 비닐 방향족 폴리머 조성물의 제조 방법 Download PDFInfo
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- KR102397588B1 KR102397588B1 KR1020167020686A KR20167020686A KR102397588B1 KR 102397588 B1 KR102397588 B1 KR 102397588B1 KR 1020167020686 A KR1020167020686 A KR 1020167020686A KR 20167020686 A KR20167020686 A KR 20167020686A KR 102397588 B1 KR102397588 B1 KR 102397588B1
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- styrene
- weight
- suspension
- derivative
- polymerization
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- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 20
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 18
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- MGIDEDVBLNEGDG-UHFFFAOYSA-N 1-methoxy-1-(2-methylbutan-2-ylperoxy)cyclohexane Chemical compound CCC(C)(C)OOC1(OC)CCCCC1 MGIDEDVBLNEGDG-UHFFFAOYSA-N 0.000 description 10
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- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 8
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- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 5
- FIYMNUNPPYABMU-UHFFFAOYSA-N 2-benzyl-5-chloro-1h-indole Chemical compound C=1C2=CC(Cl)=CC=C2NC=1CC1=CC=CC=C1 FIYMNUNPPYABMU-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
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- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 4
- 229910000397 disodium phosphate Inorganic materials 0.000 description 4
- 235000019800 disodium phosphate Nutrition 0.000 description 4
- WRUGWIBCXHJTDG-UHFFFAOYSA-L magnesium sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Mg+2].[O-]S([O-])(=O)=O WRUGWIBCXHJTDG-UHFFFAOYSA-L 0.000 description 4
- 229940061634 magnesium sulfate heptahydrate Drugs 0.000 description 4
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 4
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- 238000007796 conventional method Methods 0.000 description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 3
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- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
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- BRQMAAFGEXNUOL-LLVKDONJSA-N [(2R)-2-ethylhexyl] (2-methylpropan-2-yl)oxy carbonate Chemical compound CCCC[C@@H](CC)COC(=O)OOC(C)(C)C BRQMAAFGEXNUOL-LLVKDONJSA-N 0.000 description 2
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- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
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- XZTWHWHGBBCSMX-UHFFFAOYSA-J dimagnesium;phosphonato phosphate Chemical group [Mg+2].[Mg+2].[O-]P([O-])(=O)OP([O-])([O-])=O XZTWHWHGBBCSMX-UHFFFAOYSA-J 0.000 description 1
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/18—Binary blends of expanding agents
- C08J2203/182—Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
- C08J2325/06—Polystyrene
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
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| EP13199815 | 2013-12-30 | ||
| EP13199815.5 | 2013-12-30 | ||
| PCT/EP2014/079438 WO2015101621A1 (en) | 2013-12-30 | 2014-12-30 | Process for the preparation of solid particulate vinyl aromatic polymer compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20160105973A KR20160105973A (ko) | 2016-09-08 |
| KR102397588B1 true KR102397588B1 (ko) | 2022-05-12 |
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| JP (1) | JP6672166B2 (enExample) |
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| WO (1) | WO2015101621A1 (enExample) |
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| CN109312108A (zh) * | 2016-05-11 | 2019-02-05 | 欧文斯科宁知识产权资产有限公司 | 包含低水平溴化阻燃剂的聚合物泡沫及其制备方法 |
| CN109180881A (zh) * | 2018-09-07 | 2019-01-11 | 山东日兴新材料股份有限公司 | 一种高效阻燃聚苯乙烯的制备方法 |
| FR3105228B1 (fr) * | 2019-12-18 | 2021-11-26 | Arkema France | Composition comprenant un hemiperoxyacetal, son procédé de polymérisation, son utilisation et matériau de composition obtenu après polymérisation de la composition |
| CN114940719B (zh) * | 2022-05-12 | 2023-11-24 | 洪湖市一泰科技有限公司 | 阻燃性聚苯乙烯及其制备方法 |
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| DE602203C (de) | 1933-05-16 | 1934-09-03 | Gustaf Bernhard Nygren | Vorrichtung zum Umstimmen von Saiteninstrumenten, insbesondere von Akkordzithern |
| DE2264224C3 (de) | 1972-12-30 | 1981-11-19 | Röhm GmbH, 6100 Darmstadt | Herstellung eines vernetzten Polystyrol-Emulsionspolymerisats und seine Verwendung zum Trüben von Kunststoffen auf Methacrylatbasis |
| US4173688A (en) | 1973-07-23 | 1979-11-06 | Sekisui Kagaku Kogyo Kabushiki Kaisha | Process for preparing styrenic polymer foams |
| DE2734607A1 (de) | 1977-08-01 | 1979-02-15 | Basf Ag | Verfahren zur herstellung von kugelfoermigen, expandierbaren styrolpolymerisaten |
| US4271281A (en) | 1980-05-29 | 1981-06-02 | American Hoechst Corporation | Process for preparing styrenic polymer particles |
| FR2540126A1 (fr) | 1983-01-28 | 1984-08-03 | Rhone Poulenc Spec Chim | Latex stables et amphoteres de copolymeres a base de dienes conjugues |
| DE4029298A1 (de) | 1990-09-15 | 1992-03-19 | Huels Chemische Werke Ag | Verfahren zur koernungssteuerung bei der herstellung von expandierbaren styrolpolymerisaten durch suspensionspolymerisation |
| US5126120A (en) | 1990-10-02 | 1992-06-30 | Uop | Crystalline microporous zinc phosphate compositions |
| DE4220225A1 (de) | 1992-06-20 | 1993-12-23 | Basf Ag | Verfahren zur Herstellung von perlförmigen expandierbaren Styrolpolymerisaten |
| JPH08109279A (ja) * | 1994-10-12 | 1996-04-30 | Hitachi Chem Co Ltd | 発泡性スチレン系重合体粒子、その製造法及び発泡成形品 |
| DE19640793A1 (de) | 1996-10-02 | 1998-04-16 | Basf Ag | Verfahren und Vorrichtung zur Herstellung von Homo- und Copolymeren in Emulsionspolymerisationstechnik |
| ES2151270T3 (es) | 1997-05-14 | 2000-12-16 | Basf Ag | Procedimiento para la obtencion de polimeros de estireno expandibles que contienen particulas de grafito. |
| DE19742910A1 (de) | 1997-09-29 | 1999-04-01 | Basf Ag | Verfahren zur Herstellung von expandierbaren Styrolpolymerisaten |
| DE69921448T2 (de) | 1999-03-29 | 2005-10-13 | Chang, Young Bae, Anyang | Verfahren zur Herstellung von aufschäumbaren Styrolharzpartikeln |
| DE60225203T2 (de) | 2001-03-29 | 2009-02-19 | Agfa Graphics N.V. | Verfahren zur Herstellung von Polymerpartikeln mit enger Teilchengrössen-Verteilung |
| EP1247820B1 (en) | 2001-03-29 | 2008-02-27 | Agfa Graphics N.V. | Method of preparing polymer particles having narrow particle size distribution |
| US6455219B1 (en) * | 2001-06-22 | 2002-09-24 | Xerox Corporation | Semicontinuous emulsion polymerization process for making silica-containing latex for toners |
| DE10150405A1 (de) | 2001-10-11 | 2003-04-17 | Basf Ag | Verfahren zur Herstellung von expandierbaren Styrolpolymerisaten |
| DE102004028768A1 (de) | 2004-06-16 | 2005-12-29 | Basf Ag | Styrolpolymer-Partikelschaumstoffe mit verringerter Wärmeleitfähigkeit |
| WO2010066454A2 (en) | 2008-12-12 | 2010-06-17 | Jackon Gmbh | Process for the preparation of an expandable polymer composition in the form of beads |
| EP2356173B1 (en) | 2008-12-12 | 2018-06-13 | Jackon GmbH | Process for the preparation of an expandable polymer composition in the form of beads |
| JP5840355B2 (ja) * | 2009-10-22 | 2016-01-06 | 旭化成ケミカルズ株式会社 | アクリル系樹脂、及び成形体 |
| KR20120117980A (ko) * | 2009-12-10 | 2012-10-25 | 아크조 노벨 케미칼즈 인터내셔널 비.브이. | 스티렌 중합 방법 |
| EP2728646B1 (en) * | 2011-07-01 | 2016-05-18 | Zeon Corporation | Membrane poreuse pour batteries secondaires, procédé de sa fabrication et utilisation de celle-ci |
| WO2013092466A1 (de) | 2011-12-21 | 2013-06-27 | Basf Se | Hochtemperaturperoxid-haltige styrolpolymerisatperlen für die saatpolymerisation |
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- 2014-12-30 PL PL14827240T patent/PL3090004T3/pl unknown
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- 2014-12-30 KR KR1020167020686A patent/KR102397588B1/ko active Active
- 2014-12-30 TW TW103146357A patent/TWI654224B/zh active
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- 2014-12-30 JP JP2016561081A patent/JP6672166B2/ja not_active Expired - Fee Related
Also Published As
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| EP3090004A1 (en) | 2016-11-09 |
| CN105873961B (zh) | 2018-10-19 |
| PL3090004T3 (pl) | 2019-04-30 |
| JP6672166B2 (ja) | 2020-03-25 |
| TWI654224B (zh) | 2019-03-21 |
| WO2015101621A1 (en) | 2015-07-09 |
| US20160326333A1 (en) | 2016-11-10 |
| KR20160105973A (ko) | 2016-09-08 |
| CN105873961A (zh) | 2016-08-17 |
| TW201533100A (zh) | 2015-09-01 |
| JP2017501294A (ja) | 2017-01-12 |
| US9976006B2 (en) | 2018-05-22 |
| EP3090004B1 (en) | 2018-11-28 |
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