KR102387183B1 - 투명 압출 코팅 공정을 위한 저휘발성 관형 저밀도 에틸렌계 폴리머의 제조 방법 - Google Patents

투명 압출 코팅 공정을 위한 저휘발성 관형 저밀도 에틸렌계 폴리머의 제조 방법 Download PDF

Info

Publication number
KR102387183B1
KR102387183B1 KR1020187031696A KR20187031696A KR102387183B1 KR 102387183 B1 KR102387183 B1 KR 102387183B1 KR 1020187031696 A KR1020187031696 A KR 1020187031696A KR 20187031696 A KR20187031696 A KR 20187031696A KR 102387183 B1 KR102387183 B1 KR 102387183B1
Authority
KR
South Korea
Prior art keywords
solvent
ethylene
less
cta
initiator
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020187031696A
Other languages
English (en)
Korean (ko)
Other versions
KR20180136968A (ko
Inventor
코넬리스 에프제이 덴 도엘더
스테판 힌리치스
에바-마리아 쿱스치
오토 제이. 벌비
라제시 피. 팔드카르
버나드 에이. 페흐르
카멜로 데클렛 페레즈
Original Assignee
다우 글로벌 테크놀로지스 엘엘씨
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 다우 글로벌 테크놀로지스 엘엘씨 filed Critical 다우 글로벌 테크놀로지스 엘엘씨
Publication of KR20180136968A publication Critical patent/KR20180136968A/ko
Application granted granted Critical
Publication of KR102387183B1 publication Critical patent/KR102387183B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/01Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/28Oxygen or compounds releasing free oxygen
    • C08F4/32Organic compounds
    • C08F4/38Mixtures of peroxy-compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00Post-polymerisation treatments
    • C08F6/001Removal of residual monomers by physical means
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/04Homopolymers or copolymers of ethene
    • C09D123/06Polyethylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/06Polyethene
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020187031696A 2016-04-22 2017-04-21 투명 압출 코팅 공정을 위한 저휘발성 관형 저밀도 에틸렌계 폴리머의 제조 방법 Active KR102387183B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662326511P 2016-04-22 2016-04-22
US62/326,511 2016-04-22
PCT/US2017/028864 WO2017184990A1 (en) 2016-04-22 2017-04-21 Method for producing low volatile tubular low density ethylene-based polymers for clean extrusion coating processing

Publications (2)

Publication Number Publication Date
KR20180136968A KR20180136968A (ko) 2018-12-26
KR102387183B1 true KR102387183B1 (ko) 2022-04-18

Family

ID=58668998

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020187031696A Active KR102387183B1 (ko) 2016-04-22 2017-04-21 투명 압출 코팅 공정을 위한 저휘발성 관형 저밀도 에틸렌계 폴리머의 제조 방법

Country Status (8)

Country Link
US (1) US10815321B2 (https=)
EP (1) EP3445789B1 (https=)
JP (1) JP6946331B2 (https=)
KR (1) KR102387183B1 (https=)
CN (1) CN109071686B (https=)
BR (1) BR112018069870B1 (https=)
ES (1) ES2803232T3 (https=)
WO (1) WO2017184990A1 (https=)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12077491B2 (en) * 2019-09-24 2024-09-03 Nova Chemicals (International) S.A. Steam generation in oxidative dehydrogenation
JP7789703B2 (ja) * 2020-06-15 2025-12-22 ダウ グローバル テクノロジーズ エルエルシー Ldpe重合中のエチレン揮発性物質を減少させるためのプロセス

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015100351A1 (en) * 2013-12-26 2015-07-02 Dow Global Technologies Llc Processes to improve reactor stability for the preparation of ethylene-based polymers using asymmetrical polyenes

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL110624C (https=) 1955-11-30
GB1047191A (https=) 1963-02-15 1900-01-01
DE3227746A1 (de) 1982-07-24 1984-01-26 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von polymerisaten des ethylens
AR001122A1 (es) 1995-03-06 1997-09-24 Akzo Nobel Nv Procedimiento de polímerizacion que utiliza una composición de peróxidos (co)polímero funcionalizadoobtenido por el proceso y uso de una composición de peróxidos
US6844408B2 (en) 2000-03-16 2005-01-18 Basell Polyolefine Gmbh Preparation of polyethylene
EP1311556B1 (en) 2000-08-15 2004-10-27 Akzo Nobel N.V. Use of trioxepans in the production of high-solid acrylic, styrenic and low-density polyethylene type resins
US20060167193A1 (en) 2003-03-06 2006-07-27 Basell Polyolefine Gmbh Regulation of the continuous ethylene polymerization process in a high-pressure reactor
DE10351262A1 (de) * 2003-10-31 2005-06-02 Basell Polyolefine Gmbh Verfahren zur kontinuierlichen Herstellung von Ethylenhomo- oder Copolymeren
EP1555292B1 (en) 2004-01-13 2015-12-23 Borealis Technology Oy Extrusion coating polyethylene
JP2008533223A (ja) * 2005-03-09 2008-08-21 サウディ ベーシック インダストリーズ コーポレイション 管型反応装置内でエチレンコポリマーを調製する方法
EP1777238B1 (en) 2005-10-18 2007-05-02 Borealis Technology Oy Polyethylene blend component and blends containing the same
CA2541180A1 (en) 2006-03-23 2007-09-23 Nova Chemicals Corporation Extrusion coating composition
JP5415289B2 (ja) 2007-03-09 2014-02-12 ダウ グローバル テクノロジーズ エルエルシー 低密度ポリエチレンポリマーを生成するためのフリーラジカル開始剤系および高圧フリーラジカル重合法
MX2011003550A (es) * 2008-10-07 2011-08-17 Dow Global Technologies Llc Resinas de polietileno de baja densidad, alta presion con propiedades opticas mejoradas producidas a traves del uso de agentes de transferencia de cadena altamente activos.
WO2011008197A1 (en) 2009-07-14 2011-01-20 Exxonmobil Chemical Patents Inc. High pressure radical polymerization process
US9238700B2 (en) 2010-12-22 2016-01-19 Basell Polyolefine Gmbh Process for the preparation of ethylene copolymers in the presence of free-radical polymerization initiator by copolymerizing ethylene, a bi- or multifunctional comonomer and optionally further comonomers
BR112013022111B1 (pt) 2011-03-03 2020-03-10 Basell Polyolefine Gmbh Processo para preparar homopolímero ou copolímero de etileno na presença de iniciador de polimerização de radical livre e pelo menos um agente de transferência de cadeia em reator tubular, homopolímero ou copolímero de etileno obtenível por tal processo, seu uso e processo para revestimento por extrusão de substrato
WO2013178242A1 (en) 2012-05-31 2013-12-05 Borealis Ag Low density polyethylene for extrusion coating
JP6138927B2 (ja) 2012-05-31 2017-05-31 ボレアリス・アクチェンゲゼルシャフトBorealis Ag 押出コーティング用エチレンポリマー
US9394389B2 (en) 2012-11-20 2016-07-19 Dow Global Technologies Llc Low density ethylene-based polymers with high melt strength
EP3214123B1 (en) 2013-05-22 2021-03-31 Dow Global Technologies LLC Low density ethylene-based polymer compositions with high melt strength and mid-high density control
WO2015166297A1 (en) 2014-04-30 2015-11-05 Exxonmobil Chemical Patents Inc. Process for manufacturing ethylene polymers and copolymers
KR102577959B1 (ko) * 2015-06-25 2023-09-14 다우 글로벌 테크놀로지스 엘엘씨 낮은 헥산 추출물을 갖는 에틸렌계 폴리머

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015100351A1 (en) * 2013-12-26 2015-07-02 Dow Global Technologies Llc Processes to improve reactor stability for the preparation of ethylene-based polymers using asymmetrical polyenes

Also Published As

Publication number Publication date
JP2019515059A (ja) 2019-06-06
WO2017184990A1 (en) 2017-10-26
BR112018069870B1 (pt) 2022-10-11
JP6946331B2 (ja) 2021-10-06
EP3445789B1 (en) 2020-05-13
EP3445789A1 (en) 2019-02-27
US20190135956A1 (en) 2019-05-09
CN109071686B (zh) 2021-11-02
US10815321B2 (en) 2020-10-27
ES2803232T3 (es) 2021-01-25
BR112018069870A2 (pt) 2019-01-29
CN109071686A (zh) 2018-12-21
KR20180136968A (ko) 2018-12-26

Similar Documents

Publication Publication Date Title
KR101945575B1 (ko) 더 낮은 분자량의 추출물을 갖는 저밀도 에틸렌-계 중합체
JP7071323B2 (ja) 抽出分量と溶融弾性との改善された均衡を有する管状低密度エチレン系ポリマー
JP6141288B2 (ja) 低密度エチレン系ポリマー調製のための新しいエチレンの分配を有する重合プロセス
JP2018518573A (ja) 分子量分布の柔軟な調節を用いた高圧フリーラジカル重合プロセス
KR102331518B1 (ko) 자유 라디칼 에틸렌 공중합체의 고압 제조 방법
KR102387183B1 (ko) 투명 압출 코팅 공정을 위한 저휘발성 관형 저밀도 에틸렌계 폴리머의 제조 방법
CN111065659A (zh) 用于制备乙烯共聚物的高压聚合方法
EP3313902B1 (en) A process for producing an ethylene-based polymer
CN110770259B (zh) 用于生产基于乙烯的聚合物的高压自由基聚合
CN114555655B (zh) 具有支化的基于乙烯的聚合物组合物
CN119731291A (zh) 低级烯烃制造用石脑油及其制造方法、低级烯烃制造用石脑油的判定方法、低级烯烃组合物及其制造方法、以及聚烯烃系聚合物
KR102658251B1 (ko) 말단 불포화 및 내부 불포화의 새로운 분포를 갖는 에틸렌계 중합체
WO2025216983A1 (en) Process for the production of polyethylenes
US20210261702A1 (en) Ethylene-Based Polymers with Improved Melt Strength and Thermal Stability

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

R18-X000 Changes to party contact information recorded

St.27 status event code: A-3-3-R10-R18-oth-X000

A201 Request for examination
PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-OTH-PR1001 (AS PROVIDED BY THE NATIONAL OFFICE)

Year of fee payment: 5