KR102118501B1 - 글리세롤로부터 아크롤레인의 제조 방법 - Google Patents

글리세롤로부터 아크롤레인의 제조 방법 Download PDF

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Publication number
KR102118501B1
KR102118501B1 KR1020157013980A KR20157013980A KR102118501B1 KR 102118501 B1 KR102118501 B1 KR 102118501B1 KR 1020157013980 A KR1020157013980 A KR 1020157013980A KR 20157013980 A KR20157013980 A KR 20157013980A KR 102118501 B1 KR102118501 B1 KR 102118501B1
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KR
South Korea
Prior art keywords
glycerol
catalyst
bed
acrolein
dehydration reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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KR1020157013980A
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English (en)
Korean (ko)
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KR20150092128A (ko
Inventor
라자 즈나이귀아
쟝-마크 밀레
스테판 로리단트
패트릭 레이
Original Assignee
아디쎄오 프랑스 에스에이에스
쌩뜨레 나티오날 데 라 르세르쉬 생띠끄 (씨. 엔. 알. 에스)
위니베르시테 끌로드 베르나르 리옹 Ⅰ
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Application filed by 아디쎄오 프랑스 에스에이에스, 쌩뜨레 나티오날 데 라 르세르쉬 생띠끄 (씨. 엔. 알. 에스), 위니베르시테 끌로드 베르나르 리옹 Ⅰ filed Critical 아디쎄오 프랑스 에스에이에스
Publication of KR20150092128A publication Critical patent/KR20150092128A/ko
Application granted granted Critical
Publication of KR102118501B1 publication Critical patent/KR102118501B1/ko
Expired - Fee Related legal-status Critical Current
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/132—Halogens; Compounds thereof with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/135—Halogens; Compounds thereof with titanium, zirconium, hafnium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/182—Phosphorus; Compounds thereof with silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
    • C07C319/12—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols by reactions not involving the formation of mercapto groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C07C319/18—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by addition of thiols to unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/10—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C323/18—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/86—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C47/22—Acryaldehyde; Methacryaldehyde

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
KR1020157013980A 2012-10-30 2013-10-29 글리세롤로부터 아크롤레인의 제조 방법 Expired - Fee Related KR102118501B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR12/60358 2012-10-30
FR1260358A FR2997398B1 (fr) 2012-10-30 2012-10-30 Procede de preparation de l’acroleine a partir de glycerol
PCT/FR2013/052582 WO2014068241A1 (fr) 2012-10-30 2013-10-29 Procédé de préparation de l'acroléine à partir de glycérol

Publications (2)

Publication Number Publication Date
KR20150092128A KR20150092128A (ko) 2015-08-12
KR102118501B1 true KR102118501B1 (ko) 2020-06-03

Family

ID=47666283

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020157013980A Expired - Fee Related KR102118501B1 (ko) 2012-10-30 2013-10-29 글리세롤로부터 아크롤레인의 제조 방법

Country Status (13)

Country Link
US (1) US9187395B2 (https=)
EP (1) EP2914569B1 (https=)
JP (1) JP6189965B2 (https=)
KR (1) KR102118501B1 (https=)
CN (1) CN104918908B (https=)
AR (1) AR093255A1 (https=)
BR (1) BR112015009711B1 (https=)
ES (1) ES2644604T3 (https=)
FR (1) FR2997398B1 (https=)
IN (1) IN2015DN03774A (https=)
MY (1) MY169928A (https=)
RU (1) RU2644767C2 (https=)
WO (1) WO2014068241A1 (https=)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102210508B1 (ko) * 2015-12-23 2021-02-01 주식회사 엘지화학 글리세린 탈수 반응용 촉매의 제조 방법 및 아크롤레인의 제조 방법

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007137785A (ja) * 2005-11-15 2007-06-07 Nippon Shokubai Co Ltd 多価アルコールの脱水方法
US20080214384A1 (en) * 2007-01-29 2008-09-04 Hubert Redlingshofer Process for regenerating a catalyst
JP2010538050A (ja) * 2007-09-06 2010-12-09 アルケマ フランス グリセロールの反応性蒸発方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2897058B1 (fr) * 2006-02-07 2008-04-18 Arkema Sa Procede de preparation d'acroleine
WO2009127889A1 (en) * 2008-04-16 2009-10-22 Arkema France Process for manufacturing acrolein from glycerol
FR2939791B1 (fr) * 2008-12-16 2011-01-14 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine brute
WO2011033689A1 (en) * 2009-09-18 2011-03-24 Nippon Kayaku Kabushiki Kaisha Catalyst and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin
FR2961507B1 (fr) 2010-06-17 2016-03-04 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine
CN101879456A (zh) * 2010-06-29 2010-11-10 江苏大学 甘油选择性脱水制备丙烯醛的工艺及其催化剂的制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007137785A (ja) * 2005-11-15 2007-06-07 Nippon Shokubai Co Ltd 多価アルコールの脱水方法
US20080214384A1 (en) * 2007-01-29 2008-09-04 Hubert Redlingshofer Process for regenerating a catalyst
JP2010538050A (ja) * 2007-09-06 2010-12-09 アルケマ フランス グリセロールの反応性蒸発方法

Also Published As

Publication number Publication date
US20150239815A1 (en) 2015-08-27
FR2997398A1 (fr) 2014-05-02
JP6189965B2 (ja) 2017-08-30
CN104918908B (zh) 2017-09-01
ES2644604T3 (es) 2017-11-29
US9187395B2 (en) 2015-11-17
JP2016500695A (ja) 2016-01-14
EP2914569A1 (fr) 2015-09-09
BR112015009711B1 (pt) 2021-02-02
MY169928A (en) 2019-06-17
RU2644767C2 (ru) 2018-02-14
AR093255A1 (es) 2015-05-27
FR2997398B1 (fr) 2014-11-21
EP2914569B1 (fr) 2017-08-30
RU2015120089A (ru) 2016-12-20
IN2015DN03774A (https=) 2015-10-02
KR20150092128A (ko) 2015-08-12
WO2014068241A1 (fr) 2014-05-08
CN104918908A (zh) 2015-09-16

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